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The recent experimental fabrication of ultra stable glass films via vapour deposition [Science 315, 353 (2007)] and the observation of front-like response to the annealing of these films [Phys.Rev.Lett. 102, 065503 (2009)], have raised…

Soft Condensed Matter · Physics 2011-01-20 Sébastien Léonard , Peter Harrowell

Concentrated colloidal suspensions are a well-tested model system which has a glass transition. Colloids are suspensions of small solid particles in a liquid, and exhibit glassy behavior when the particle concentration is high; the…

Soft Condensed Matter · Physics 2010-10-01 Luca Cipelletti , Eric R. Weeks

Glassy solids may undergo a fluidization (yielding) transition upon deformation whereby the material starts to flow plastically. It has been a matter of debate whether this process is controlled by a specific time scale, from among…

Soft Condensed Matter · Physics 2020-06-25 Alessio Zaccone , Eugene M. Terentjev

The discovery of ultrastable glasses has raised novel challenges about glassy systems. Recent experiments studied the macroscopic devitrification of ultrastable glasses into liquids upon heating but lacked microscopic resolution. We use…

Statistical Mechanics · Physics 2023-04-13 Cecilia Herrero , Camille Scalliet , M. D. Ediger , Ludovic Berthier

Despite the use of glasses for thousands of years, the nature of the glass transition is still mysterious. On approaching the glass transition, the growth of dynamic heterogeneity has long been thought to play a key role in explaining the…

Soft Condensed Matter · Physics 2018-03-23 Lijin Wang , Ning Xu , W. H. Wang , Pengfei Guan

One of the central problems of the liquid-glass transition is whether there is a structural signature that can qualitatively distinguish different dynamic behaviors at different degrees of supercooling. Here, we propose a novel structural…

Soft Condensed Matter · Physics 2015-09-24 Yan-Wei Li , You-Liang Zhu , Zhao-Yan Sun

Amorphous solids, or glasses, are distinguished from crystalline solids by their lack of long-range structural order. At the level of two-body structural correlations, glassformers show no qualitative change upon vitrifying from a…

Soft Condensed Matter · Physics 2015-06-11 C. Patrick Royall , Stephen R. Williams

Glass films prepared by a process of physical vapor deposition have been shown to have thermodynamic and kinetic stability comparable to those of ordinary glasses aged for thousands of years. A central question in the study of…

Soft Condensed Matter · Physics 2016-11-23 Daniel Reid , Ivan Lyubimov , Mark Ediger , Juan de Pablo

Glass-forming materials are characterized by an intermittent motion at the microscopic scale. Particles spend most of their time rattling within the cages formed by their neighbors, and seldom jump to a different cage. In molecular glass…

Soft Condensed Matter · Physics 2014-12-03 Raffaele Pastore , Massimo Pica Ciamarra , Giuseppe Pesce , Antonio Sasso

If a liquid is cooled rapidly to form a glass, its structural relaxation becomes retarded, producing a drastic increase in viscosity. In two dimensions, strong long-wavelength fluctuations persist, even at low temperature, making it…

Soft Condensed Matter · Physics 2019-12-25 Hayato Shiba , Takeshi Kawasaki , Kang Kim

Glass-forming liquids have only a modest tendency to crystallize and hence their dynamics can be studied even below the melting temperature. The relaxation dynamics of most of these liquids shows at a temperature $T_c$, somewhat above the…

Soft Condensed Matter · Physics 2025-01-17 Francesco Rusciano , Raffaele Pastore , Francesco Greco , Walter Kob

Understanding the role that structure plays in the dynamical arrest observed in glassy systems remains an open challenge. Over the last decade, machine learning (ML) strategies have emerged as an important tool for probing this…

Soft Condensed Matter · Physics 2026-01-09 Rinske M. Alkemade , Frank Smallenburg , Laura Filion

Using large-scale molecular dynamics simulations for a system of $10^6$ particles, the response of a dense amorphous solid to the continuous expansion of its volume is investigated. We find that the spatially uniform glassy state becomes…

Statistical Mechanics · Physics 2016-10-12 Pinaki Chaudhuri , Jürgen Horbach

Complex behavior in glassforming liquids is associated with formation of a mosaic of different structures. Using bond order parameters together with topological characteristics of the bond network, we show that in the mosaic of crystalline…

Soft Condensed Matter · Physics 2013-09-24 Alexander Z. Patashinski , Mark A. Ratner , Bartosz A. Grzybowski , Rafal Orlik , Antoni C. Mitus

Glass is a microscopically disordered, solid form of matter that results when a fluid is cooled or compressed in such a fashion that it does not crystallise. Almost all types of materials are capable of glass formation -- polymers, metal…

Statistical Mechanics · Physics 2009-10-31 Srikanth Sastry

Recent theories predict that when a supercooled liquid approaches the glass transition, particle clusters with a special "amorphous order" nucleate within the liquid, which lead to static correlations dictating the dramatic slowdown of…

Soft Condensed Matter · Physics 2016-03-04 Bo Zhang , Xiang Cheng

Glasses are solid materials whose constituent atoms are arranged in a disordered manner. The transition from a liquid to a glass remains one of the most poorly understood phenomena in condensed matter physics, and still no fully microscopic…

Statistical Mechanics · Physics 2015-11-12 Liesbeth M. C. Janssen , David R. Reichman

Glass formation is one of the most interesting phenomena in the condensed matter field. Considerable effort has gone into understanding and predicting the glass formability. However, the previous prediction requires the glass first made…

Materials Science · Physics 2019-02-12 R. Dai , R. Ashcraft , A. K. Gangopadhyay , K. F. Kelton

As liquids approach the glass transition temperature, dynamical heterogeneity emerges as a crucial universal feature of their behavior. Dynamic facilitation, where local motion triggers further motion nearby, plays a major role in this…

We investigate the characteristic length scales associated with the glass transition phenomenon. By studying an atomic glass-forming liquid in negatively curved space, for which the local order is well identified and the amount of…

Statistical Mechanics · Physics 2010-02-10 François Sausset , Gilles Tarjus