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We investigate the optical response of a charge-transfer complex in a condensed phase driven by an external laser field. Our model includes an instantaneous short-range Coulomb interaction and a local optical vibrational mode described by…

Strongly Correlated Electrons · Physics 2021-08-25 Kiyoto Nakamura , Yoshitaka Tanimura

Studying the changed water dynamics in the hydration layers of biomolecules is an important step towards fuller understanding of their function and mechanisms, but has shown to be quite difficult. The measurement of the time-dependent…

Chemical Physics · Physics 2021-05-20 Esther Heid , Christian Schröder

To identify an analytical relation between the properties of polymers and their's monomer a Metal-Molecule-Metal (MMM) junction has been presented as an interesting and widely used object of research in which the molecule is a polymer which…

Mesoscale and Nanoscale Physics · Physics 2016-08-16 Mohammad Nakhaee , S Ahmad Ketabi

We assess how quantum-mechanical effects associated with high-frequency chromophore vibrations influence excitation energy transfer in biological light-harvesting complexes. We begin with a mixed quantum-classical theory that combines a…

Chemical Physics · Physics 2025-01-07 Johan E. Runeson , David E. Manolopoulos

In non-perturbative non-Markovian open quantum systems, reaching either low temperatures with the hierarchical equations of motion (HEOM) or high temperatures with the Thermalized Time Evolving Density Operator with Orthogonal Polynomials…

Quantum Physics · Physics 2025-03-05 Brieuc Le Dé , Amine Jaouadi , Etienne Mangaud , Alex W. Chin , Michèle Desouter-Lecomte

A consistent microscopic theory for the response of strongly-coupled superfluid fermionic systems is formulated. After defining the response as a two-point two-fermion correlation function in the basis of the Bogolyubov's quasiparticles,…

Nuclear Theory · Physics 2023-01-02 Elena Litvinova , Yinu Zhang

Chlorosomes are the largest and most efficient natural light-harvesting antenna systems. They contain thousands of pigment molecules - bacteriochlorophylls (BChls)- that are organized into supramolecular aggregates and form a very efficient…

Chemical Physics · Physics 2014-05-13 Takatoshi Fujita , Joonsuk Huh , Semion K. Saikin , Jennifer C. Brookes , Alan Aspuru-Guzik

H\"uckel molecular orbital (HMO) theory provides a semi-empirical treatment of the electronic structure in conjugated {\pi}-electronic systems. A scalable system-agnostic execution of HMO theory on a quantum computer is reported here based…

Quantum Physics · Physics 2024-05-22 Harshdeep Singh , Sonjoy Majumder , Sabyashachi Mishra

We present numerically exact results for the quantum coherent energy transfer in the Fenna-Matthews-Olson molecular aggregate under realistic physiological conditions, including vibrational fluctuations of the protein and the pigments for…

Mesoscale and Nanoscale Physics · Physics 2011-12-06 Peter Nalbach , Daniel Braun , Michael Thorwart

Excitation transfer through interacting systems plays an important role in many areas of physics, chemistry, and biology. The uncontrollable interaction of the transmission network with a noisy environment is usually assumed to deteriorate…

Quantum Physics · Physics 2009-09-12 Filippo Caruso , Alex W. Chin , Animesh Datta , Susana F. Huelga , Martin B. Plenio

In quantum computation, it is of paramount importance to locate the parameter space where maximal coherence can be preserved in the qubit system. In recent years environment-induced decoherence based the quantum Brownian motion (QBM) models…

Quantum Physics · Physics 2015-06-26 B. L. Hu

The understanding of particle entanglement is an important goal in the studies of correlated quantum matter. The widely-used method of scanning tunneling spectroscopy -- which measures the local density of states (LDOS) of a many-body…

Strongly Correlated Electrons · Physics 2022-11-30 Songyang Pu , Ajit C. Balram , Zlatko Papić

It is shown that energy transfer in a homogeneous fully connected quantum network is assisted by a decohering interaction with environmental spins. Analytic expressions for the transfer probabilities are obtained for the zero temperature…

Quantum Physics · Physics 2014-01-28 A. Marais , I. Sinayskiy , A. Kay , F. Petruccione , A. Ekert

By leveraging the Variational Quantum Eigensolver (VQE), the ``quantum equation of motion" (qEOM) method established itself as a promising tool for quantum chemistry on near term quantum computers, and has been used extensively to estimate…

Quantum Physics · Physics 2024-09-04 Daniele Morrone , N. Walter Talarico , Marco Cattaneo , Matteo A. C. Rossi

Quantum mechanics describes the unitary time evolution of closed systems. In practice, every quantum system interacts with the environment leading to an irreversible loss of coherence. The Spin-Boson model (SBM) is central to the…

Chemical Physics · Physics 2020-09-28 Nirmalendu Acharyya , Martin Richter , Benjamin P. Fingerhut

We review the path integral method wherein quantum systems are mapped with Feynman's path integrals onto a classical system of "ring-polymers" and then simulated with the Monte Carlo technique. Bose or Fermi statistics correspond to…

Condensed Matter · Physics 2010-07-27 J. Shumway , D. M. Ceperley

Development of particle in cell methods using finite element based methods (FEMs) have been a topic of renewed interest; this has largely been driven by (a) the ability of finite element methods to better model geometry, (b) better…

Computational Physics · Physics 2022-04-13 Scott O'Connor , Zane D. Crawford , O. H. Ramachandran , John Luginsland , B. Shanker

We combine the coherent modified Redfield theory (CMRT) with the equation of motion-phase matching approach (PMA) to calculate two-dimensional photon echo spectra for photoactive molecular complexes with an intermediate strength of the…

Chemical Physics · Physics 2015-10-28 Hong-Guang Duan , Arend G. Dijkstra , Peter Nalbach , Michael Thorwart

Experiments on collisions of isolated electrons guided along the edges in quantum Hall setups can mimic mixing of photons with the important distinction that electrons are charged fermions. In the so-called electronic Hong-Ou-Mandel (HOM)…

Mesoscale and Nanoscale Physics · Physics 2023-05-15 Elina Pavlovska , Peter G. Silvestrov , Patrik Recher , Girts Barinovs , Vyacheslavs Kashcheyevs

Mean-field molecular dynamics based on path integrals is used to approximate canonical quantum observables for particle systems consisting of nuclei and electrons. A computational bottleneck is the sampling from the Gibbs density of the…

Numerical Analysis · Mathematics 2023-11-30 Xin Huang , Petr Plechac , Mattias Sandberg , Anders Szepessy