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We explore the feasibility of coherent control of excitonic dynamics in light harvesting complexes, analyzing the limits imposed by the open nature of these quantum systems. We establish feasible targets for phase and phase/amplitude…

Referring to a Fano-type model qualitative analogy we develop a comprehensive basic mechanism for the laser control of the non-Markovian bath response in strongly coupled Open Quantum Systems (OQS). A converged Hierarchy Equations Of Motion…

The time evolution in open quantum systems, such as a molecular aggregate in contact with a thermal bath, still poses a complex and challenging problem. The influence of the thermal noise can be treated using a plethora of schemes, several…

Chemical Physics · Physics 2019-07-24 Hasan Rahman , Ulrich Kleinekathoefer

Our understanding of magnetic reconnection (MR) under chromospheric conditions remains limited. Recent observations have demonstrated the important role of ion-neutral interactions in the dynamics of the chromosphere. Furthermore, the…

Solar and Stellar Astrophysics · Physics 2023-04-19 Q. M. Wargnier , J. Martinez-Sykora , V. H. Hansteen , B. De Pontieu

Numerically "exact" methods addressing the dynamics of coupled electron--phonon systems have been intensively developed. Nevertheless, the corresponding results for the electron mobility $\mu_\mathrm{dc}$ are scarce, even for the…

Strongly Correlated Electrons · Physics 2023-09-12 Veljko Janković

The light-harvesting is a problem of long interest. It becomes active again in recent years stimulated by suggestions of quantum effects in energy transport. Recent experiments found evidence that BChla 1 and BChla 6 are the first to be…

Biological Physics · Physics 2015-06-04 B. Cui , X. X. Yi , C. H. Oh

Correlated many-fermion systems emerge in a broad range of phenomena in warm dense matter, plasmonics, and ultracold atoms. Quantum hydrodynamics (QHD) complements common first-principles methods for many-fermion systems and enables…

Plasma Physics · Physics 2022-02-17 Zh. A. Moldabekov , T. Dornheim , G. Gregori , F. Graziani , M. Bonitz , A. Cangi

The Born--Oppenheimer approximation is the standard tool for the study of molecular systems. It is founded on the observation that the energy scale of the electron dynamics in a molecule is larger than that of the nuclei. A very similar…

High Energy Physics - Phenomenology · Physics 2018-01-31 Nora Brambilla , Gastão Krein , Jaume Tarrús Castellà , Antonio Vairo

Quantum mechanical phenomena, such as electronic coherence and entanglement, play a key role in achieving the unrivalled efficiencies of light-energy conversion in natural photosynthetic light-harvesting complexes, and triggered the growing…

Quantum Physics · Physics 2011-02-02 Richard Hildner , Daan Brinks , Niek F. van Hulst

The theory of hierarchical equations of motion (HEOM) is one of the standard methods to give exact evaluations of the dynamics as coupled to harmonic oscillator environments. However, the theory is numerically demanding due to its…

Chemical Physics · Physics 2022-05-31 Tatsushi Ikeda , Akira Nakayama

We present an efficient quantum algorithm for beyond-Born-Oppenheimer molecular energy computations. Our approach combines the quantum full configuration interaction method with the nuclear orbital plus molecular orbital (NOMO) method. We…

Quantum Physics · Physics 2016-02-24 Libor Veis , Jakub Višňák , Hiroaki Nishizawa , Hiromi Nakai , Jiří Pittner

A generalized master equation (GME) governing quantum evolution of modular exciton density (MED) is derived for large scale light harvesting systems composed of weakly interacting modules of multiple chromophores. The GME-MED offers a…

Quantum Physics · Physics 2013-11-12 Seogjoo Jang , Stephan Hoyer , Graham Fleming , K. Birgitta Whaley

Obtaining the exciton dynamics of large photosynthetic complexes by using mixed quantum mechanics/molecular mechanics (QM/MM) is computationally demanding. We propose a machine learning technique, multi-layer perceptrons, as a tool to…

Chemical Physics · Physics 2016-06-01 Florian Häse , Stéphanie Valleau , Edward Pyzer-Knapp , Alán Aspuru-Guzik

The multi-mode anharmonic Brownian motion model provides a universal framework for simulating molecular vibrations in condensed phases. When vibrational energy surpasses thermal excitation, quantum effects become significant, necessitating…

Chemical Physics · Physics 2026-03-18 Ryotaro Hoshino , Yoshitaka Tanimura

Quantum entanglement generation is generally known to be impossible by any classical means. According to Poisson statistics, coherent photons are not considered quantum particles due to the bunching phenomenon. Recently, a coherence…

Quantum Physics · Physics 2023-03-23 B. S. Ham

Simulations of biophysical systems inevitably include steps that correspond to time integrations of ordinary differential equations. These equations are often related to enzyme action in the synthesis and destruction of molecular species,…

Biological Physics · Physics 2009-03-31 Roberto Chignola , Alessio Del Fabbro , Edoardo Milotti

Quantum computing offers promising new avenues for tackling the long-standing challenge of simulating the quantum dynamics of complex chemical systems, particularly open quantum systems coupled to external baths. However, simulating such…

Quantum Physics · Physics 2025-02-20 Xiaohan Dan , Eitan Geva , Victor S. Batista

Photosynthetic organisms use networks of chromophores to absorb sunlight and deliver the energy to reaction centres, where charge separation triggers a cascade of chemical steps to store the energy. We present a detailed model of the…

The fractional quantum Hall (FQH) effect arises from strong electron correlations in a quantising magnetic field, and features exotic emergent phenomena such as electron fractionalisation. Using the diagrammatic Monte Carlo approach with…

Strongly Correlated Electrons · Physics 2026-03-16 Ben Currie , Evgeny Kozik

We present a theoretical framework to investigate quantum thermodynamic processes under non-Markovian system-bath interactions on the basis of the hierarchical equations of motion (HEOM) approach, which is convenient to carry out…

Quantum Physics · Physics 2019-05-01 Akihito Kato , Yoshitaka Tanimura
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