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Distinguishing between enantiomers is crucial in the study of chiral molecules in chemistry and pharmacology. Many optical approaches rely on enantiospecific cyclic electric-dipole transitions induced by three microwave or laser beams.…

Quantum Physics · Physics 2025-12-11 Fen Zou , Yong Li , Peng Zhang

We study the excitation of asymmetric-top (including chiral) molecules by two-color femtosecond laser pulses. In the cases of non-chiral asymmetric-top molecules excited by an orthogonally polarized two-color pulse, we demonstrate,…

Optics · Physics 2021-09-16 Long Xu , Ilia Tutunnikov , Yehiam Prior , Ilya Sh. Averbukh

Chiral discrimination, a problem of vital importance, has recently become an emerging frontier in ultrafast physics, with remarkable progress achieved in multiphoton and strong-field regimes. Rydberg excitations, unavoidable in the…

We show that the electric dipole-dipole interaction between a pair of polar molecules undergoes an all-out transformation when superimposed by a far-off resonant optical field. The combined interaction potential becomes tunable by variation…

Atomic Physics · Physics 2015-05-30 Mikhail Lemeshko , Bretislav Friedrich

Two-photon optical transitions combined with long-range dipole-dipole interactions can be used for the coherent manipulation of collective metastable states composed of different atoms. We show that it is possible to induce optical…

Quantum Physics · Physics 2007-05-23 M. D. Lukin , P. R. Hemmer

We study exciton quantum transfer along a molecular chain whilst accounting for the effects of permanent dipoles that are induced by charge displacements in the molecular orbitals. These effects are typically neglected as they do not arise…

Chemical Physics · Physics 2025-01-14 Adam Burgess , Erik Gauger

We give a derivation for the indirect interaction between two magnetic dipoles induced by the quantized electromagnetic field. It turns out that the interaction between permanent dipoles directly returns to the classical form; the…

Quantum Physics · Physics 2018-01-19 Jiaxuan Wang , Hui Dong , Sheng-Wen Li

Many organic molecules possess large permanent dipole moments that differ depending on the electronic state. These permanent dipoles influence both intermolecular coupling and interactions with the optical fields, yet they are often…

Quantum Physics · Physics 2025-08-18 Matthew Freed , Dominic M. Rouse , Andrea Rocco , Jim Al-Khalili , Marian Florescu , Adam Burgess

Chiroptical effects using circularly polarized light produce signals that change sign when switching either molecular handedness (enantiosensitivity) or the light helicity (circular dichroism). Here, we break this…

We show that the position of the exceptional points (EPs) in the parameter space of a chiral molecule coupled to the photoionization continuum by a three-color field is enantiosensitive. Using a minimal model of a three-level system driven…

Quantum Physics · Physics 2023-07-11 Nicola Mayer , Nimrod Moiseyev , Olga Smirnova

We investigate two-color photon correlations in the light emitted by strongly coupled two-level emitters. Spectral filtering allows us to manipulate the collected light statistics and we show that the resonances induced by dipole-dipole…

Quantum Physics · Physics 2021-05-12 Elnaz Darsheshdar , Mathilde Hugbart , Romain Bachelard , Celso Jorge Villas-Boas

Many optically active systems possess spatially asymmetric electron orbitals. These generate permanent dipole moments, which can be stronger than the corresponding transition dipole moments, significantly affecting the system dynamics and…

Quantum Physics · Physics 2023-04-21 Adam Burgess , Marian Florescu , Dominic Michael Rouse

Inspired by a sea creature, we identify a robust chiral optical force that pushes the opposite enantiomers of a chiral molecule towards regions of orthogonal linear polarization in an optical field via electric dipole interactions. Our…

We show that photons may be redshifted or blueshifted when interacting with the field of an overcritical dipole, which incorporates the one-loop QED corrections coming from vacuum polarization. Using the effective metric, it follows that…

High Energy Astrophysical Phenomena · Physics 2016-10-19 Luca Bonetti , Santiago E. Perez Bergliaffa , Alessandro D. A. M. Spallicci

We make a general derivation for the magnetic dipole-dipole interaction based on the mediation of the quantized electro-magnetic field. Due to the interaction with the dipoles, the dynamics of the field is added by a dipole field, which…

Quantum Physics · Physics 2020-08-07 Fang-qi Hu , Qing Zhao , Sheng-Wen Li

The design of far-field radiation diagrams from combined electric and magnetic dipolar sources has recently found applications in nanophotonic metasurfaces that realize tailored reflection and refraction. Such dipolar sources also exhibit…

We present a combined theoretical and experimental work investigating the angle-resolved phases of the photoionization process driven by a two-color field consisting of an attosecond pulse train and an infrared pulse in an ensemble of…

Efficient excitation of a single two-level system usually requires that the driving field is at the same frequency as the atomic transition. However, the scattered laser light in solid-state implementations can dominate over the single…

Impulsive orientation of symmetric-top molecules excited by two-color femtosecond pulses is considered. In addition to the well-known transient orientation appearing immediately after the pulse and then reemerging periodically due to…

Optics · Physics 2021-07-22 Long Xu , Ilia Tutunnikov , Yehiam Prior , Ilya Sh. Averbukh

Two-photon excitation (TPE) proceeds via a "virtual" pathway, which depends on the accessibility of one or more intermediate states, and, in the case of non-centrosymmetric molecules, an additional "dipole" pathway involving the…

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