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Related papers: Hartree method for molecular polaritons

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Exciton-polaritons are mixed light-matter excitations that result from the strong coupling regime between an active excitonic material and photonic resonances. Harnessing these hybrid excitations provides a rich playground to explore…

The regime of ultrastrong light-matter interaction has been investigated theoretically and experimentally, using zero-dimensional electromagnetic resonators coupled with an electronic transition between two confined states of a…

Interaction of dipolar polaritons can be efficiently tuned by means of a shape resonance in their excitonic component. Provided the resonance width is large, a squeezed population of strongly interacting polaritons may persist on the…

Quantum Gases · Physics 2020-04-01 Sergueï V. Andreev

Strong coupling between electronic excitations in materials and photon modes results in the formation of polaritons, which display larger nonlinearities than their photonic counterparts due to their material component. We theoretically…

Chemical Physics · Physics 2023-08-29 Sindhana Pannir-Sivajothi , Nathaniel P. Stern , Joel Yuen-Zhou

Strong-coupling between light and matter produces hybridized states (polaritons) whose delocalization and electromagnetic character allow for novel modifications in spectroscopy and chemical reactivity of molecular systems. Recent…

This study investigates the dynamic behavior of polaritons in an optical cavity containing one million molecules, emphasizing the influence of molecular rotation and level disorder on the coupling between molecules and photons. Through…

Optics · Physics 2024-02-22 Wei Liu , Jingqi Chen , Wenjie Dou

We study how polariton condensation modifies charge transport in organic materials. In typical organic materials, charge transport proceeds via incoherent hopping. We therefore provide an approach to determine how the rate and final state…

Quantum Gases · Physics 2022-11-10 M. Ahsan Zeb , Peter G. Kirton , Jonathan Keeling

A theoretical description of radiation-matter coupling for semiconductor-based photonic crystal slabs is presented, in which quantum wells are embedded within the waveguide core layer. A full quantum theory is developed, by quantizing both…

Soft Condensed Matter · Physics 2009-11-13 D. Gerace , L. C. Andreani

Engineering non-linear hybrid light-matter states in tailored optical lattices is a central research strategy for the simulation of complex Hamiltonians. Excitons in atomically thin crystals are an ideal active medium for such purposes,…

The recent progress in nanotechnology [1,2] and single-molecule spectroscopy [3-5] paves the way for cost-effective organic quantum optical technologies emergent with a promise to real-life devices operating at ambient conditions. In this…

Vibrational polaritons, hybrid light-matter states formed between molecular vibrations and infrared (IR) cavity modes, provide a novel approach for modifying chemical reaction pathways and energy transfer processes. For vibrational…

Chemical Physics · Physics 2025-05-16 Xinwei Ji , Tao E. Li

We investigate polariton-phonon hybrid excitations, which describe the collective excitations of emitter-photon polaritons and vibrational phonons, in a periodic array of vibrating two-level emitters interacting with waveguide photons. We…

Quantum Physics · Physics 2022-10-26 Han-Jie Zhu , Xiao-Ming Zhao , Jin-Kui Zhao , Lin Zhuang , Guo-Feng Zhang , Wu-Ming Liu

The development of reliable ab initio methods for light-matter strong coupling is necessary for a deeper understanding of molecular polaritons. The recently developed strong coupling quantum electrodynamics Hartree-Fock model (SC-QED-HF)…

Chemical Physics · Physics 2025-02-21 Matteo Castagnola , Rosario R. Riso , Yassir El Moutaoukal , Enrico Ronca , Henrik Koch

Strong coupling between vibrational transitions in molecules within a resonant optical microcavity leads to the formation of collective, delocalized vibrational polaritons. There are many potential applications of "polaritonic chemistry,"…

Chemical Physics · Physics 2021-11-05 Rong Duan , Joseph N. Mastron , Yin Song , Kevin J. Kubarych

Coupling excitons with quantized radiation has been shown to enable coherent ballistic transport at room temperature inside optical cavities. Previous theoretical works employ a simple description of the material, depicting it as a…

Quantum Physics · Physics 2026-05-14 Saeed Rahmanian Koshkaki , Arshath Manjalingal , Logan Blackham , Arkajit Mandal

As pioneering experiments have shown, strong vibrational coupling between molecular vibrations and light modes in an optical cavity can significantly alter molecular properties and even affect chemical reactivity. However, the current…

Chemical Physics · Physics 2024-07-26 Thomas Schnappinger , Markus Kowalewski

Exciton polaritons in two-dimensional semiconductors inside microcavities are powerful platforms to explore hybrid light-matter quantum systems. Here, we study a macroscopic coherent population of the lowest energy state of…

Mesoscale and Nanoscale Physics · Physics 2021-10-26 Aleksi Julku , Miguel. A. Bastarrachea-Magnani , Arturo Camacho-Guardian , Georg M. Bruun

Organic microcavities are photonic nanostructures that strongly confine the electromagnetic field, allowing exotic quantum regimes of light-matter interaction with disordered organic semiconductors. The unambiguous interpretation of the…

Quantum Physics · Physics 2017-06-07 Felipe Herrera , Frank C. Spano

Polaritons are unique hybrid light-matter states that offer an alternative way to manipulate chemical processes and change material properties. In this work we theoretically demonstrate that singlet fission dynamics can be accelerated under…

Chemical Physics · Physics 2021-10-06 Clàudia Climent , David Casanova , Johannes Feist , Francisco J. García-Vidal

The behavior of instantaneous and averaged vectors of the Poynting vector transverse component for the resulting field formed as a superposition of waves with different frequencies and different polarizations is considered. Results of…

Optics · Physics 2020-06-24 I. Mokhun , I. Bodyanchuk , K. Galushko , Y. Galushko , O. Val , Y. Viktorovskaya