Related papers: Role of virial coefficients in chemical reaction
In order to describe a nonuniform equilibrium mixture with an interface between two coexisting phases it is necessary to consider contributions to the Helmholtz energy which depend on the gradients of for instance the density. Van der Waals…
Quantum Hall systems are recently shown to possess a quantity sensitive to the spatial geometry and topology of the system, dubbed the Hall viscosity $\eta_H$. Despite the extensive theoretical discussions on its properties, the question of…
We use the formalism of Geometrothermodynamics to describe chemical reactions in the context of equilibrium thermodynamics. Any chemical reaction in a closed system is shown to be described by a geodesic in a $2-$dimensional manifold that…
In this Research Note the Zwanzig's formulation of the Stokes-Einstein (SE) relation for simple atomistic fluids is re-examined. It is shown that the value of the coefficient in SE relation depends on the ratio of the transverse and…
Electron Transfer (ET) reactions are modeled by the dynamics of a quantum two-level system (representing the electronic state) coupled to a thermalized bath of classical harmonic oscillators (representing the nuclei degrees of freedom).…
We study non-linear phenomena in quantum dots. Non linearities are reflected in the I-V characteristic curve as bistabilities, instabilities and time dependent oscillations of the currents. The nature of the non-linear behavior depends upon…
Predicting how systems respond to external perturbations far from equilibrium remains a fundamental challenge across physics, chemistry, and biology. We present a unified response framework for stochastic Markov dynamics that integrates…
The nonlinear dynamics of viscous, flow in a compressible spatially homogeneous fluid with chemical reactions are studied. Time-dependent but exact solution of the Piseuille type is obtained. Proceeding from this solution, the influence of…
The spectroscopic factor has long played a central role in nuclear reaction theory. However, it is not an observable. Consequently it is of minimal use as a meeting point between theory and experiment. In this paper the nature of the…
We study the dynamical behavior of nonlinear coupling in a quantum wave equation of a logarithmic type. Using statistical mechanical arguments for a large class of many-body systems, this coupling is shown to be related to temperature which…
We calculate the nonequilibrium mean-field 'temperature' of a Brownian system in contact with a heat bath. We consider two different cases: an equilibrium bath in the presence of strong external forces and a nonequilibrium bath. By proving…
We calculate the equation of state of dense hydrogen within the chemical picture. Fluid variational theory is generalized for a multi-component system of molecules, atoms, electrons, and protons. Chemical equilibrium is supposed for the…
The density distributions and Soret coefficient in a nonequilibrium colloidal system with nonuniform temperature are studied by the overdamped Langevin equation for Brownian motion in an inhomogeneous strong friction medium. Based on the…
Earlier, the author found that for the biggest part of chemical reactions the law of conservation of energy must have the following form: dU=dQ+PdV+SUM. In the present paper this result is confirmed by other experiments.
We show that the quantum reflection coefficient of ultracold heavy atoms scattering off a dielectric surface can be tuned in a wide range by suitable choice of surface and environment temperatures. This effect results from a temperature…
Particle number fluctuations are considered within the van der Waals (VDW) equation, which contains both attractive (mean-field) and repulsive (eigenvolume) interactions. The VDW equation is used to calculate the scaled variance of particle…
Using equilibrium fluctuations to understand the response of a physical system to an externally imposed perturbation is the basis for linear response theory, which is widely used to interpret experiments and shed light on microscopic…
In this paper we show how using a relativistic kinetic equation the ensuing expression for the heat flux can be casted in the form required by Classical Irreversible Thermodynamics. Indeed, it is linearly related to the temperature and…
We show how using a special relativistic kinetic equation with a BGK- like collision operator the ensuing expression for the heat flux can be casted in the form required by Classical Irreversible Thermodynamics. Indeed, it is linearly…
We present the virial equation of state of low-density nuclear matter composed of neutrons, protons and alpha particles. The virial equation of state is model-independent, and therefore sets a benchmark for all nuclear equations of state at…