Related papers: Role of virial coefficients in chemical reaction
The aim of this paper is to prove the existence of weak solution for a quasi-static evolution of thermo-visco-elastic model with Norton-Hoff law of plasticity. The dependence on temperature occurs both in the elastic constitutive equations…
We use the so-called Liouville-von Neumann (LvN) approach to study the nonequilibrium quantum dynamics of time-dependent second order phase transitions. The LvN approach is a canonical method that unifies the functional Schr\"{o}dinger…
We study a large class of strongly interacting condensate-like materials, which can be characterized by a normalizable complex-valued function. A quantum wave equation with logarithmic nonlinearity is known to describe such systems, at…
A theory for the nonlinear energy response of a system subjected to a heat bath is developed when the temperature of the heat bath is modulated sinusoidally. The theory is applied to a model glass forming system, where the landscape is…
Non-equilibrium modifications of the nuclear equation of state are assessed in the framework of Extended Irreversible Thermodynamics. The expected size of the non-equilibrium corrections to quantities like the nuclear-matter…
The entropy production rate is a key quantity in irreversible thermodynamics. In this work, we concentrate on the realization of entropy production rate in chemical reaction systems in terms of the experimentally measurable reaction rate.…
The atmospheric reaction of H$_2$S with Cl has been reinvestigated to check if, as previously suggested, only explicit dynamical computations can lead to an accurate evaluation of the reaction rate because of strong recrossing effects and…
A nonequilibrium thermodynamic theory demonstrating an induction effect of a statistical nature is presented. We have shown that this thermodynamic induction can arise in a class of systems that have variable kinetic coefficients (VKC). In…
Earlier, the author found that for the biggest part of chemical reactions the law of conservation of energy must have the following form: dU=dQ+PdV+SUM In the present paper this result is confirmed by other experiments.
It has been supposed that the law of conservation of energy in chemical reactions has the following form: dU=dQ-PdV+SUM Earlier the author has shown that for the biggest part of reactions it must have the following form: dU=dQ+PdV+SUM In…
A striking feature of standard quantum mechanics is its analogy with classical fluid dynamics. In particular it is well known the Schr\"{o}dinger equation can be viewed as describing a classical compressible and non-viscous fluid, described…
We present a fluctuation relation for heat dissipation in a nonequilibrium system. A nonequilibrium work is known to obey the fluctuation theorem in any time interval $t$. A heat, which differs from a work by an energy change, is shown to…
The group classification of a class of variable coefficient reaction-diffusion equations with exponential nonlinearities is carried out up to both the equivalence generated by the corresponding generalized equivalence group and the general…
We derive relativistic viscous hydrodynamic equations invoking the generalized second law of thermodynamics for two different forms of the non-equilibrium single-particle distribution function. We find that the relaxation times in these two…
Reaction rates of chemical reactions under nonequilibrium conditions can be determined through the construction of the normally hyperbolic invariant manifold (NHIM) [and moving dividing surface (DS)] associated with the transition state…
The quintessential description of Kondo physics in equilibrium is obtained within a scaling picture that shows the buildup of Kondo screening at low temperature. For the non-equilibrium Kondo model with a voltage bias the key new feature…
Recently we have shown that a one-parameter scaling, $T_{coh}$, describes the physical behavior of several heavy fermions in a region of their phase diagram. In this paper we fully characterize this region, obtaining the uniform…
In relativistic Hamiltonians the two-nucleon interaction is expressed as a sum of $\tilde{v}_{ij}$, the interaction in the ${\bf P}_{ij}=0$ rest frame, and the ``boost interaction'' $\delta v({\bf P}_{ij})$ which depends upon the total…
It is argued that the van der Waals force exerted by the liquid and vapor/air on the molecules escaping from one phase into the other strongly affects the characteristics of evaporation. This is shown using two distinct descriptions of the…
Our current understanding of interstellar carbon fractionation hinges on the interpretation of astrochemical kinetic models. Yet, the various reactions included carry large uncertainties in their (estimated) rate coefficients, notably those…