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We develop the elastically collective nonlinear Langevin equation theory of bulk relaxation of glass-forming liquids to investigate molecular mobility under compression conditions. The applied pressure restricts more molecular motion and…

Soft Condensed Matter · Physics 2020-04-24 Anh D. Phan , Agnieszka Jedrzejowska , Marian Paluch , Katsunori Wakabayashi

State-of-the-art techniques for simulating deeply supercooled liquids require a high degree of size polydispersity to be effective. While these techniques have enabled great insight into the microscopic dynamics near the glass transition,…

Soft Condensed Matter · Physics 2023-08-10 Ilian Pihlajamaa , Corentin C. L. Laudicina , Liesbeth M. C. Janssen

The relaxation dynamics in two van der Waals bonded and one hydrogen-bonding molecular liquids is studied as a function of pressure and temperature by incoherent neutron scattering using simultaneous dielectric spectroscopy. The dynamics is…

Soft Condensed Matter · Physics 2018-09-10 Henriette Wase Hansen , Bernhard Frick , Simone Capaccioli , Alejandro Sanz , Kristine Niss

Building on the recently derived inhomogeneous mode-coupling theory, we extend the generalised mode-coupling theory of supercooled liquids to inhomogeneous environments. This provides a first-principles-based, systematic and rigorous way of…

Statistical Mechanics · Physics 2023-01-11 Corentin C. L. Laudicina , Chengjie Luo , Kunimasa Miyazaki , Liesbeth M. C. Janssen

Disordered systems like liquids, gels, glasses, or granular materials are not only ubiquitous in daily life and in industrial applications but they are also crucial for the mechanical stability of cells or the transport of chemical and…

Disordered Systems and Neural Networks · Physics 2019-04-30 Zhen Zhang , Walter Kob

The interplay between the structural relaxation and the rheological response of a binary LJ glass former is studied via MD simulations. In the quiescent state, the model is well known for its sluggish dynamics and a two step relaxation of…

Soft Condensed Matter · Physics 2015-05-14 Fathollah Varnik

We propose a mechanism for liquid formation in strongly correlated lattice systems. The mechanism is based on an interplay between long-range attraction and superexchange processes. As an example, we study dipolar bosons in one-dimensional…

By employing a simplified nonlinear memory function proposed recently by the present author, a universal equation for a collective-intermediate scattering function derived based on the time-convolutionless mode-coupling theory is…

Statistical Mechanics · Physics 2020-05-20 Michio Tokuyama

Glassy systems are ubiquitous in nature, and are characterized by slow relaxations to equilibrium without a typical timescale, aging and memory effects. Understanding these is a long-standing problem in physics. We study the aging of the…

Disordered Systems and Neural Networks · Physics 2009-11-30 Ariel Amir , Yuval Oreg , Yoseph Imry

We use molecular dynamics computer simulations to investigate the relaxation dynamics of a simple model for a colloidal gel at a low volume fraction. We find that due to the presence of the open spanning network this dynamics shows at low…

Soft Condensed Matter · Physics 2015-06-25 E. Del Gado , W. Kob

We numerically study the equilibrium relaxation dynamics of a two-dimensional Mari-Kurchan glass model. The tree-like structure of particle interactions forbids both non-trivial structural motifs and the emergence of a complex free-energy…

Disordered Systems and Neural Networks · Physics 2022-06-27 Yoshihiko Nishikawa , Atsushi Ikeda , Ludovic Berthier

The process of structural relaxation in disordered solids subjected to repeated tension-compression loading is studied using molecular dynamics simulations. The binary glass is prepared by rapid cooling well below the glass transition…

Soft Condensed Matter · Physics 2020-05-04 Pritam Kumar Jana , Nikolai V. Priezjev

We propose that the dynamics of supercooled liquids and the formation of glasses can be understood from the existence of a zero temperature dynamical critical point. To support our proposal, we derive from simple physical assumptions a…

Soft Condensed Matter · Physics 2009-11-10 Stephen Whitelam , Ludovic Berthier , Juan P. Garrahan

When analyzing the broadband absorption spectrum of liquid water (10^10 - 10^13 Hz), we find its relaxation-resonance features to be an indication of Frenkel's translation-oscillation motion of particles, which is fundamentally inherent to…

Soft Condensed Matter · Physics 2026-03-26 A. A. Volkov , V. G. Artemov , A. A. Volkov , N. N. Sysoev

Diverse material classes exhibit practically identical behavior when made viscous upon cooling toward the glass transition, suggesting a common theoretical basis. The first-principles scaling laws that have been proposed to describe the…

In the mode coupling theory of the liquid to glass transition the long time structural relaxation follows from equations solely determined by equilibrium structural parameters. The present extension of these structural relaxation equations…

Soft Condensed Matter · Physics 2017-02-08 M. Fuchs , Th. Voigtmann

As liquids approach the glass transition temperature, dynamical heterogeneity emerges as a crucial universal feature of their behavior. Dynamic facilitation, where local motion triggers further motion nearby, plays a major role in this…

The random first order transition theory of the dynamics of supercooled liquids is extended to treat aging phenomena in nonequilibrium structural glasses. A reformulation of the idea of ``entropic droplets'' in terms of libraries of local…

Soft Condensed Matter · Physics 2009-11-10 Vassiliy Lubchenko , Peter G. Wolynes

For several atomistic models of glass formers, at conditions below their glassy dynamics onset temperatures, ${T_\mathrm{o}}$, we use importance sampling of trajectory space to study the structure, statistics and dynamics of excitations…

Statistical Mechanics · Physics 2014-05-08 Aaron S. Keys , Lester O. Hedges , Juan P. Garrahan , Sharon C. Glotzer , David Chandler

The dynamics of membrane undulations inside a viscous solvent is governed by distinctive, anomalous, power laws. Inside a viscoelastic continuous medium these universal behaviors are modified by the specific bulk viscoelastic spectrum. Yet,…

Soft Condensed Matter · Physics 2018-02-20 Rony Granek , Haim Diamant