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Surface-enhanced Raman scattering (SERS) is a critical tool for chemical sensing and spectroscopy, and a key question is how to optimally design nanostructures for maximizing SERS. We present fundamental limits on spatially-averaged SERS…

Optics · Physics 2025-02-17 Pengning Chao , Ian M. Hammond , Steven G. Johnson

Single-molecule surface enhanced Raman scattering (SM-SERS) is one of the vital applications of plasmonic nanoparticles. The SM-SERS sensitivity critically depends on plasmonic hot-spots created at the vicinity of such nanoparticles. In…

Plasmon-free surface-enhanced Raman scattering (SERS) substrates have attracted tremendous attention for their abundant sources, excellent chemical stability, superior biocompatibility, good signal uniformity, and unique selectivity to…

Optics · Physics 2021-06-10 Leilei Lan , Yimeng Gao , Xingce Fan , Mingze Li , Qi Hao , Teng Qiu

For distances less 10 nm, a total energy transfer occurs from a quantum emitter to a nearby metallic surface, producing evanescent surface waves that are plasmonic in nature. When investigating a metallic nanohole supported on an optically…

Optics · Physics 2019-07-16 Amir Djalalian-Assl

Raman Spectroscopy offers an in-situ, rapid, and non-destructive characterization tool for chemical analysis of diverse samples with no or minimal preparation. However, due to the inherent weak signal of conventional Raman spectroscopy,…

Trisoctahedral (TOH) shaped Au nanocrystals (NCs) have emerged as a new class of metal nanoparticles (MNP) due to its superior catalystic and SERS activities caused by the presence of high density atomic steps and dangling bonds on their…

Materials Science · Physics 2017-05-15 Achyut Maity , Arpan Maiti , Biswarup Satpati , Avinash Patsha , Sandip Dhara , Tapas Kumar Chini

Surface-enhanced Raman spectroscopy (SERS) demands reliable, high enhancement substrates in order to be used in different fields of application. Here, we introduce freestanding porous gold membranes (PAuM) as easy to produce, scalable,…

Plasmonic nanostructures have wide applications in photonics including pathogen detection and diagnosis via Surface-Enhanced Raman Spectroscopy (SERS). Despite major role plasmonics play in signal enhancement, electrostatics in SERS is yet…

Cell Behavior · Quantitative Biology 2025-01-22 Jia Dong , Jeong Hee Kim , Isaac Pincus , Sujan Manna , Jennifer M. Podgorski , Yanmin Zhu , Loza F. Tadesse

We report that rhomb-shaped metal nanoantenna arrays support multiple plasmonic resonances, making them favorable bio-sensing substrates. Besides the two localized plasmonic dipole modes associated with the two principle axes of the rhombi,…

Surface-enhanced Raman spectroscopy (SERS) is a powerful tool for vibrational spectroscopy as it provides several orders of magnitude higher sensitivity than inherently weak spontaneous Raman scattering by exciting localized surface plasmon…

Angle-resolved reflection and emission spectra of metal gratings consisting of sub-wavelength grooves and immersed into rhodamine B and rhodamine 19 solutions are presented. The measured reflection and emission dispersion diagrams reveal…

Optics · Physics 2015-05-20 Carola Geiger , Jochen Fick

Hotspots of surface-enhanced resonance Raman scattering (SERRS) are localized within 1 nm at gaps or crevices of plasmonic nanoparticle (NP) dimers. We demonstrate SERRS hotspots with volumes that are extended in one dimension tens of…

The paper demonstrates possibility of giant enhancement of Surface Enhanced Hyper Raman Scattering on the base of qualitative consideration of electromagnetic field near some models of rough metal surfaces and of some features of the dipole…

Optics · Physics 2011-07-19 A. M. Polubotko

In this work, we introduce the platform of plasmonic Doppler grating (PDG) to experimentally investigate the enhancement effect of plasmonic gratings in the input and output beams of nonlinear surface-enhanced coherent anti-Stokes Raman…

Plasmonic gratings and nano-particle arrays in a metal-insulator-metal structures are fabricated on an erbium doped silicon nitride layer. This material system enables simple fabrication of the structure, since the active nitride layer can…

Optics · Physics 2015-05-14 Yiyang Gong , Selcuk Yerci , Rui Li , Luca Dal Negro , Jelena Vuckovic

We show that topology optimization (TO) of metallic resonators can lead to $\sim 10^2\times$ improvement in surface-enhanced Raman scattering (SERS) efficiency compared to traditional resonant structures such as bowtie antennas. TO inverse…

The review is devoted to explanation of SERS in terms of the dipole and quadrupole light-molecule interactions arising in surface fields strongly varying in space in the region of the strongly irregular surface roughness. The main SERS…

Chemical Physics · Physics 2013-10-01 A. M. Polubotko

Percolation of gold films of ~15 nm thickness was controlled to achieve the largest openings during Au deposition. Gold was evaporated on 300-nm-thick films of nanostructured porous and columnar SiO2, TiO2 and MgF2 which were deposited by…

Nanogaps are ubiquitous across science, confining molecules and thus changing chemistries which influence many areas such as catalysis, corrosion, photochemistry, and sensing. However in ambient conditions, it is unclear how water solvates…

This article reviews the new developments in Tip-enhanced Raman scattering (TERS). The fundamental mechanisms underlying the Raman enhancement are discussed, including the role of the plasmonic character of the metallic tips, the nature of…

Chemical Physics · Physics 2008-04-01 Catalin C. Neacsu , Samuel Berweger , Markus B. Raschke