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We present a detailed study of the kinetic cluster growth process during gelation of weakly attractive colloidal particles by means of experiments on critical Casimir attractive colloidal systems, simulations and analytical theory. In the…

Soft Condensed Matter · Physics 2021-02-04 Joep Rouwhorst , Peter Schall , Christopher Ness , Theo Blijdenstein , Alessio Zaccone

We study the formation and growth of equilibrium clusters in a suspension of weakly-charged colloidal particles and small non-adsorbing polymers. The effective potential is characterised by a short-range attraction and a long-range…

Soft Condensed Matter · Physics 2009-11-11 Rodrigo Sanchez , Paul Bartlett

We study a model in which particles interact with short-ranged attractive and long-ranged repulsive interactions, in an attempt to model the equilibrium cluster phase recently discovered in sterically stabilized colloidal systems in the…

Soft Condensed Matter · Physics 2009-11-10 Francesco Sciortino , Stefano Mossa , Emanuela Zaccarelli , Piero Tartaglia

We present further evidence that gelation is an arrested phase separation in attractive colloid-polymer mixtures, based on a method combining confocal microscopy experiments with numerical simulations recently established in {\bf Nature…

Soft Condensed Matter · Physics 2009-11-13 Emanuela Zaccarelli , Peter J. Lu , Fabio Ciulla , David. A. Weitz , Francesco Sciortino

We systematically study the relationship between equilibrium and non-equilibrium phase diagrams of a system of short-ranged attractive colloids. Using Monte Carlo and Brownian dynamics simulations we find a window of enhanced…

Soft Condensed Matter · Physics 2009-11-13 Andrea Fortini , Eduardo Sanz , Marjolein Dijkstra

Dispersed colloidal particles within a suspension can aggregate and spontaneously self-organize into a robust, percolating structure known as a gel. These network-like structures are prevalent in nature and play a critical role in many…

Soft Condensed Matter · Physics 2025-04-29 David Richard , Mehdi Bouzid

By means of molecular dynamics, we study a model system for colloidal suspensions where the interaction is based on a competition between attraction and repulsion. At low temperatures the relaxation time $\tau$ first increases as a power…

Soft Condensed Matter · Physics 2009-11-10 A. de Candia , E. Del Gado , A. Fierro , N. Sator , A. Coniglio

We study gelation in suspensions of model colloidal particles with short-ranged attractive and long-ranged repulsive interactions by means of three-dimensional fluorescence confocal microscopy. At low packing fractions, particles form…

Soft Condensed Matter · Physics 2009-11-10 Andrew I. Campbell , Valerie J. Anderson , Jeroen S. van Duijneveldt , Paul Bartlett

Competing interactions stabilize exotic mesoscopic structures, yet the microscopic mechanisms by which they influence non-equilibrium processes leading to disordered states remain largely unexplored, despite their critical role in…

Soft Condensed Matter · Physics 2025-05-13 Joeri Opdam , Michio Tateno , Hajime Tanaka

We evaluate thermodynamic, geometric and dynamic properties of a short-ranged square well binary mixture to provide a coherent picture of this simple, but rich, model for colloidal interactions. In particular, we compare the location, in…

Soft Condensed Matter · Physics 2007-05-23 E. Zaccarelli , F. Sciortino , S. V. Buldyrev , P. Tartaglia

We examine the structure and dynamics of small isolated $N$-particle clusters interacting via short-ranged Morse potentials. "Ideally preprared ensembles" obtained via exact enumeration studies of sticky hard sphere packings serve as…

Soft Condensed Matter · Physics 2015-06-22 Robert S. Hoy

Computer simulations were used to study the gel transition occurring in colloidal systems with short range attractions. A colloid-polymer mixture was modelled and the results were compared with mode coupling theory expectations and with the…

Soft Condensed Matter · Physics 2009-11-07 Antonio M. Puertas , Matthias Fuchs , Michael E. Cates

The growing interest in the non-equilibrium assembly of colloidal particles in active liquids is driven by the motivation to create novel structures endowed with tunable properties unattainable within the confines of equilibrium systems.…

Soft Condensed Matter · Physics 2024-03-06 Pragya Kushwaha , Sayan Maity , Anjaly S. Menon , Raghunath Chelakkot , Vijayakumar Chikkadi

The binodals and the non-ergodicity lines of a binary mixture of hard sphere-like particles with large size ratio are computed for studying the interplay between dynamic arrest and phase separation in depletion-driven colloidal mixtures.…

Soft Condensed Matter · Physics 2009-11-13 Ph. Germain , S. Amokrane

In this Rapid Communication we demonstrate the applicability of an augmented Gibbs ensemble Monte Carlo approach for the phase behavior determination of model colloidal systems with short-ranged depletion attraction and long-ranged…

Soft Condensed Matter · Physics 2007-05-23 P. Charbonneau , D. R. Reichman

Transitions in structural heterogeneity of colloidal depletion gels formed through short-range attractive interactions are correlated with their dynamical arrest. The system is a density and refractive index matched suspension of 0.20…

Soft Condensed Matter · Physics 2009-11-11 C. J. Dibble , M. Kogan , M. J. Solomon

We numerically investigate the competition between phase separation and dynamical arrest in a colloidal system interacting via a short ranged attractive potential. Equilibrium fluid configurations are quenched at two different temperatures…

Soft Condensed Matter · Physics 2007-05-23 G. Foffi , C. De Michele , F. Sciortino , P. Tartaglia

The aggregation of attractive colloids has been extensively studied from both theoretical and experimental perspectives as the fraction of solid particles is changed, and the range, type and strength of attractive or repulsive forces…

Soft Condensed Matter · Physics 2019-11-07 Safa Jamali , Robert C. Armstrong , Gareth H. McKinley

The phase behavior of colloid-polymer mixtures, and of solutions of globular proteins, is often interpreted in terms of a simple model of hard spheres with short-ranged attraction. While such a model yields a qualitative understanding of…

Soft Condensed Matter · Physics 2009-10-31 M. G. Noro , N. Kern , D. Frenkel

Using computer simulations, we study the dynamic arrest in a schematic model of colloid-polymer mixtures combining short-ranged attractions with long-ranged repulsions. The arrested gel is a dilute rigid network of colloidal particles…

Soft Condensed Matter · Physics 2018-08-17 David Richard , C. Patrick Royall , Thomas Speck
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