English

Equilibrium route to colloidal gellation: mixtures of hard sphere-like colloids

Soft Condensed Matter 2009-11-13 v1

Abstract

The binodals and the non-ergodicity lines of a binary mixture of hard sphere-like particles with large size ratio are computed for studying the interplay between dynamic arrest and phase separation in depletion-driven colloidal mixtures. Contrarily to the case of hard core plus short range effective attraction, physical gellation without competition with the fluid-phase separation can occur in such mixtures. This behavior due to the oscillations in the depletion potential should concern all simple mixtures with non-ideal depletant, justifying further studies of their dynamic properties.

Keywords

Cite

@article{arxiv.0811.2707,
  title  = {Equilibrium route to colloidal gellation: mixtures of hard sphere-like colloids},
  author = {Ph. Germain and S. Amokrane},
  journal= {arXiv preprint arXiv:0811.2707},
  year   = {2009}
}