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We have studied four complex organic molecules (COMs), methyl formate ($CH_3OCHO$), dimethyl ether ($CH_3OCH_3$), formamide ($NH_2CHO$), and ethyl cyanide ($C_2H_5CN$), towards a large sample of 39 high-mass star-forming regions…

Astrophysics of Galaxies · Physics 2020-09-09 A. Coletta , F. Fontani , V. M. Rivilla , C. Mininni , L. Colzi , Á. Sánchez-Monge , M. T. Beltrán

The complex organic molecules (COMs) detected in star-forming regions are the precursors of the prebiotic molecules that can lead to the emergence of life. By studying COMs in more evolved protoplanetary disks we can gain a better…

Earth and Planetary Astrophysics · Physics 2022-03-08 Nashanty G. C. Brunken , Alice S. Booth , Margot Leemker , Pooneh Nazari , Nienke van der Marel , Ewine F. van Dishoeck

A 3 $\times$ 3 map of the Galactic Center was made at 9$\arcmin$ resolution and 10$\arcmin$ spacing in the CH $^2\Pi_{1/2}$, J=1/2, F=1-1 transition at 3335 MHz. The CH emission shows a velocity extent that is nearly that of the CO(1-0)…

Astrophysics · Physics 2009-11-13 Loris Magnani , Susan Zelenik , T. M. Dame , B. Engebreth

Measuring isotopic ratios is a sensitive technique used to obtain information on stellar nucleosynthesis and chemical evolution. We present measurements of the carbon and sulphur abundances in the interstellar medium of the central region…

While the abundance of elemental deuterium is relatively low (D/H ~ a few 1E-5), orders of magnitude higher D/H abundance ratios have been found for many interstellar molecules, enhanced by deuterium fractionation. In cold molecular clouds…

Astrophysics of Galaxies · Physics 2023-07-05 Arshia M. Jacob , Karl M. Menten , Friedrich Wyrowski , Olli Sipilä

Dense gas is important for galaxy evolution and star formation. Optically-thin dense-gas tracers, such as isotopologues of HCN, HCO+, etc., are very helpful to diagnose excitation conditions of dense molecular gas. However, previous studies…

Astrophysics of Galaxies · Physics 2022-08-03 Fei Li , Zhi-Yu Zhang , Junzhi Wang , Feng Gao , Shanghuo Li , Jing Zhou , Yichen Sun , Ziyi Guo , Shu Liu

C-fractionation has been studied from a theoretical point of view with different models of time-dependent chemistry, including both isotope-selective photodissociation and low-temperature isotopic exchange reactions. Recent chemical models…

Astrophysics of Galaxies · Physics 2020-10-05 L. Colzi , O. Sipilä , E. Roueff , P. Caselli , F. Fontani

Isomerism in complex organic molecules provides key insights into the formation mechanisms and physical conditions of the interstellar medium (ISM). Among the C$_2$H$_5$NO isomers, only acetamide and trans-N-methylformamide (trans-NMF) have…

We report an extensive rotational spectroscopic analysis of singly deuterated methyl mercaptan (CH$_{2}$DSH) using both millimeter and far-infrared synchrotron spectra to achieve a global torsional analysis of the three lowest torsional…

The detection of complex organic molecules (COMs) toward cold sources such as pre-stellar cores (with T<10 K), has challenged our understanding of the formation processes of COMs in the interstellar medium. Recent modelling on COM chemistry…

The nitrogen isotope ratio 14N/15N is a powerful tool to trace Galactic stellar nucleosynthesis and constraining Galactic chemical evolution. Previous observations have found lower 14N/15N ratios in the Galactic center and higher values in…

Astrophysics of Galaxies · Physics 2024-06-17 J. L. Chen , J. S. Zhang , C. Henkel , Y. T. Yan , H. Z. Yu , Y. X. Wang , Y. P. Zou , J. Y. Zhao , X. Y. Wang

Aims. The purpose of this study is to investigate the distributions of the isomeric molecules HCN and HNC and estimate their abundance ratio in the protostellar core Cha-MMS1 located in Chamaeleon {\sc i}. Methods. The core was mapped in…

Astrophysics · Physics 2009-11-11 P. P. Tennekes , J. Harju , M. Juvela , L. V. Toth

In studying the interstellar medium (ISM) and Galactic cosmic rays (CRs), uncertainty of the interstellar gas density has always been an issue. To overcome this difficulty, we used a component decomposition of the 21-cm HI line emission and…

High Energy Astrophysical Phenomena · Physics 2022-08-31 T. Mizuno , K. Hayashi , J. Metzger , I. V. Moskalenko , E. Orlando , A. W. Strong , H. Yamamoto

We have carried out model calculations of the photoionized intergalactic medium (IGM) to determine the effects on the predicted ionic column densities due to uncertainties in the published dielectronic recombination (DR) rate coefficients.…

Astrophysics · Physics 2016-09-07 Daniel Wolf Savin

We present a clear detection of CH2 in absorption towards the molecular cloud complexes Sagittarius B2 and W49 N using the ISO Long Wavelength Spectrometer. These observations represent the first detection of its low excitation rotational…

Astrophysics · Physics 2009-11-10 E. T. Polehampton , K. M. Menten , S. Bruenken , G. Winnewisser , J. -P. Baluteau

We present the first extragalactic detections of several CH rotational transitions in the far-infrared (FIR) in four nearby galaxies: NGC 1068, Arp 220, M 82 and NGC 253 using the \textit{Herschel Space Observatory}. The CH lines in all…

We present a detailed analysis of acetylene (C$_2$H$_2$) and its isotopologues in the Orion IRc2 region, focusing on the determination of $^{12}$C/$^{13}$C isotopic ratios using high-resolution infrared spectra from SOFIA. By employing a…

Astrophysics of Galaxies · Physics 2025-08-27 Minkyu Lee , Jubin Park , Sehoon Oh , Myung-Ki Cheoun , Se Young Park

The interstellar medium (ISM) in starburst galaxies contains plenty of chemical elements synthesised by core-collapse supernova explosions. By measuring the abundances of these metals, we can study the chemical enrichment within galaxies…

Astrophysics of Galaxies · Physics 2024-06-12 K. Fukushima , S. B. Kobayashi , K. Matsushita

Methanol is a seed species of complex organic molecules that is of fundamental importance in astrochemistry. Although various isotopologues of CH$_3$OH have been detected in the interstellar medium (ISM), CH$_{3}$$^{17}$OH is only…

Astrophysics of Galaxies · Physics 2025-10-10 Yoshimasa Watanabe , Takahiro Oyama , Akemi Tamanai , Shaoshan Zeng , Nami Sakai

(Modified) We measure the distribution of carbon in the intergalactic medium as a function of redshift z and overdensity delta. Using a hydrodynamical simulation to link the H I absorption to the density and temperature of the absorbing…

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