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We investigate a physical divergence of the third order polarization susceptibility representing a photoinduced current in biased crystalline insulators. This current grows quadratically with illumination time in the absence of momentum…

Mesoscale and Nanoscale Physics · Physics 2018-10-30 Benjamin M. Fregoso , Rodrigo A. Muniz , J. E. Sipe

This paper presents a study of dc photocurrents in biased insulators to the third order in the electric field. We find three photocurrents which are characterized by physical divergences of the third-order free-electron polarization…

Mesoscale and Nanoscale Physics · Physics 2019-08-07 Benjamin M. Fregoso

The bulk photovoltaic effect provides a fundamental pathway for direct light-to-current conversion in quantum materials. However, these nonlinear currents are often strictly constrained or forbidden by crystal symmetries, hindering their…

Mesoscale and Nanoscale Physics · Physics 2026-05-25 Zhuocheng Lu , Zhuang Qian , Zhichao Guo , Likun Shi , Shi Liu , Hua Wang , Kai Chang

Solid systems with strong correlations and interactions under light illumination have the potential for exhibiting interesting bulk photovoltaic behavior in the non-perturbative regime, which has remained largely unexplored in the past…

Strongly Correlated Electrons · Physics 2022-04-06 Sangeeta Rajpurohit , C. Das Pemmaraju , Tadashi Ogitsu , Liang Z Tan

Recently, atomically thin PdSe$_2$ semiconductors with rare pentagonal Se-Pd-Se monolayers were synthesized and were also found to possess superior properties such as ultrahigh air stability, and high carrier mobility, thus offering a new…

Materials Science · Physics 2021-09-21 Vijay Kumar Gudelli , Guang-Yu Guo

Bulk photovoltaic (BPVE) effect in crystals lacking inversion symmetry offers great potential for optoelectronic applications due to its unique properties such as above bandgap photovoltage and switchable photocurrent. Because of their…

Materials Science · Physics 2021-10-27 Amr Abdelsamie , Lu You , Le Wang , Shuzhou Li , Mingqiang Gu , Junling Wang

We investigate the bulk photovoltaic effect, which rectifies light into electric current, in a collective quantum state with correlation driven electronic ferroelectricity. We show via explicit real-time dynamical calculations that the…

Strongly Correlated Electrons · Physics 2021-09-21 Tatsuya Kaneko , Zhiyuan Sun , Yuta Murakami , Denis Golež , Andrew J. Millis

We calculate the shift current response, which has been identified as the dominant mechanism for the bulk photovoltaic effect, for the polar compounds LiAsS$_\text{2}$, LiAsSe$_\text{2}$, and NaAsSe$_\text{2}$. We find that the magnitudes…

Materials Science · Physics 2014-12-04 John A. Brehm , Steve M. Young , Fan Zheng , Andrew M. Rappe

We study the bulk photovoltaic effect (BPVE) in Dirac and Weyl semimetals under two-frequency light irradiation. We show that the BPVE emerges for centrosymmetric Dirac and Weyl semimetals in the presence of light fields with frequencies…

Mesoscale and Nanoscale Physics · Physics 2025-01-15 Yuya Ikeda , Sota Kitamura , Takahiro Morimoto

Recently, it has been shown how shift and ballistic currents in piezoelectric sillenite crystals Bi$_{12}$GeO$_{20}$ and Bi$_{12}$SiO$_{20}$ can be separated experimentally under the assumption that the shift component of the circular…

The bulk photovoltaic effect exhibited by the non-centrosymmetric system gains research interest due to the observed large open-circuit voltage. The ferroelectric systems exhibiting anomalous photovoltaic effect are mostly crystallized with…

Materials Science · Physics 2021-04-08 Subhajit Pal , S. Muthukrishnan , Banasree Sadhukhan , Sarath N. , D. Murali , Pattukkannu Murugavel

We present a straightforward and computationally cheap method to obtain the phonon-assisted photocurrent in large-scale devices from first-principles transport calculations. The photocurrent is calculated using nonequilibrium Green's…

Mesoscale and Nanoscale Physics · Physics 2018-08-01 Mattias Palsgaard , Troels Markussen , Tue Gunst , Mads Brandbyge , Kurt Stokbro

We theoretically study direct current generation in a quantum spin chain induced by spinon excitations by light irradiation. We consider a s=1/2 1D antiferromagnetic XXZ model with magnetoelectric coupling that describes multiferroics with…

Strongly Correlated Electrons · Physics 2026-05-21 Ryosuke Yamashita , Shintaro Takayoshi , Takahiro Morimoto

Steady current in metals induces a thermal gradient, a phenomenon known as the Peltier effect. The Peltier effect is one of the fundamental phenomena in the thermoelectric properties of materials and is also used in applications such as…

Mesoscale and Nanoscale Physics · Physics 2024-08-15 Hiroaki Ishizuka , Masahiro Sato

We employ first-principles calculations to investigate the ferroelectric properties and the bulk photovoltaic effect (BPVE) of antimony sulfur iodide (SbSI). The BPVE enables direct sunlight-to-electricity conversion in homogeneous…

Materials Science · Physics 2025-06-13 Giuseppe Cuono , Subhadeep Bandyopadhyay , Andrea Droghetti , Silvia Picozzi

Electron beam induced current (EBIC) is a powerful technique which measures the charge collection efficiency of photovoltaics with sub-micron spatial resolution. The exciting electron beam results in a high generation rate density of…

Materials Science · Physics 2014-10-17 Paul M. Haney , Heayoung P. Yoon , Prakash Koirala , Robert W. Collins , Nikolai B. Zhitenev

We theoretically study the current-voltage relation, $I-V$ characteristic, of the photovoltaics due to the shift current, i.e., the photocurrent generated ${\it without}$ the external dc electric field in noncentrosymmetric crystals through…

Mesoscale and Nanoscale Physics · Physics 2019-01-01 Takahiro Morimoto , Masao Nakamura , Masashi Kawasaki , Naoto Nagaosa

Magnetic fields break time-reversal symmetry (TRS) and reshape a material's spatial symmetry. Because the bulk photovoltaic effect (BPVE) is exquisitely sensitive to symmetry, it offers a natural arena for magnetic-field control. Here, we…

Mesoscale and Nanoscale Physics · Physics 2025-12-01 Yuncheng Mao , Claudio Attaccalite

Bulk photovoltaic effect, which arises from crystal symmetry-driven charge carrier separation, is an intriguing physical phenomenon that has attracted extensive interest in photovoltaic application due to its junction-free photovoltaic and…

Materials Science · Physics 2023-08-22 Xiaojuan Chen , Kang Xu , Tingxiao Qin , Yubin Wang , Yuzhong Chen , Haiyun Liu , Qihua Xiong

Bulk photovoltaic effect is a non-linear response in noncentrosymmetric materials that converts light into DC current. In this work, we investigate the optical linear and non-linear responses in a chalcopyrite semiconductor ZnGeP$_2$. We…

Materials Science · Physics 2024-10-15 Banasree Sadhukhan