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The structural, vibrational, energetic and electronic properties of hydrogen at the stoichiometric RuO2(110) termination are studied using density functional theory. The oxide surface is found to stabilize both molecular and dissociated H2.…

Materials Science · Physics 2007-05-23 Qiang Sun , Karsten Reuter , Matthias Scheffler

Knowledge of the behavior of hydrogen in metal hydrides is the key for understanding their electronic properties. So far, no experimental methods exist to access these properties beyond 100 GPa, where high-Tc superconductivity emerges.…

The relaxed geometries and electronic properties of the hydrogenated phases of the Si(111)-7$\times$7 surface are studied using first-principles molecular dynamics. A monohydride phase, with one H per dangling bond adsorbed on the bare…

Condensed Matter · Physics 2009-10-28 D. R. Alfonso , C. Noguez , D. A. Drabold , S. E. Ulloa

The atomic structures of clean and hydrogen-adsorbed Pd(001) are investigated by low energy electron diffraction (LEED) I/V analysis. Clean Pd(001) shows little surface relaxation in sharp contrast to previous reports. Adsorbing 1 monolayer…

Other Condensed Matter · Physics 2007-05-23 S. H. Kim , J. Barthel , H. L. Meyerheim , J. Kirschner , Jikeun Seo , J. -S. Kim

We present extensive molecular dynamics (MD) simulations investigating numerous candidate crystal structures for hydrogen in conditions around the present experimental frontier (400GPa). Spontaneous phase transitions in the simulations…

Materials Science · Physics 2015-11-18 Ioan B. Magdau , Graeme J. Ackland

The hydrogen atom theory is developed for the de Sitter and anti de Sitter spaces on the basis of the Klein-Gordon-Fock wave equation in static coordinates. In both models, after separation of the variables, the problem is reduced to the…

Mathematical Physics · Physics 2014-12-30 O. V. Veko , K. V. Kazmerchuk , E. M. Ovsiyuk , V. M. Red'kov , A. M. Ishkhanyan

Within the subgap of amorphous oxide semiconductors like amorphous indium gallium zinc oxide (a-IGZO) are donor-like and acceptor-like states that control the operational physics of optically transparent thin-film transistors (TFTs).…

Materials Science · Physics 2022-03-01 George W. Mattson , Kyle T. Vogt , John F. Wager , Matt W. Graham

We have carried out a series of helium atom scattering measurements in order to characterise the adsorption properties of hydrogen on antimony(111). Molecular hydrogen does not adsorb at temperatures above 110 K in contrast to…

Materials Science · Physics 2017-05-25 Patrick Kraus , Christian Gösweiner , Anton Tamtögl , Florian Apolloner , Wolfgang E. Ernst

By performing density functional theory-based calculations, we investigate how hydrogen atom interacts with the surfaces of monolayer PbI2 and how one and two side hydrogenation modify its structural, electronic, and magnetic properties.…

Mesoscale and Nanoscale Physics · Physics 2016-07-22 C. Bacaksiz , H. Sahin

Density Functional Theory calculations are used to investigate the role of substrate-induced cooperative effects on the adsorption of water on a partially oxidized transition metal surface, O(2x2)/Ru(0001). Focussing particularly on the…

Materials Science · Physics 2015-05-19 Pepa Cabrera-Sanfelix , M. V. Fernández-Serra , A. Arnau , D. Sánchez-Portal

In this paper we report the effect of hydrogen on the structural properties of AISI-H13 steel nitrogen-implanted samples in low oxygen partial pressure atmosphere. The samples were implanted in a high vacuum chamber by using a broad ion…

Materials Science · Physics 2017-12-06 L. F. Zagonel , C. A. Figueroa , F. Alvarez

We report differences in adsorption and reaction energetics for ethylene on Si(001) with respect to different dangling bond configurations induced by hydrogen precoverage as obtained via density functional theory calculations. This can help…

Chemical Physics · Physics 2016-12-06 Josua Pecher , Gerson Mette , Michael Dürr , Ralf Tonner

The structures and energetics of organic molecules adsorbed onto clean and H-passivated Si(001)-(2$\times$1) surfaces have been calculated using density functional theory. For benzene adsorbed on the clean Si surface the tight-bridge…

Materials Science · Physics 2009-11-13 Karen Johnston , Risto M. Nieminen

Motivated by the long-debated question about the internal stability of the electron, the force densities acting on the charge density of the 1s electron in the H atom are investigated. The problem is mapped onto the canonical formalism for…

Atomic Physics · Physics 2016-06-22 F. J. Himpsel

Recently, the hydrogen adsorption and diffusion on the CeO2 (111) surface have been a vividly discussed topic because of its outstanding catalytic activity and selectivity in hydrogenation reactions. However, for the strongly reduced CeO2…

Materials Science · Physics 2019-05-01 Xiaoke Li , Joachim Paier , Joachim Sauer

Static and dynamic changes induced by adsorption of atomic hydrogen on the NiAl(110) lattice at 130 K have been examined as a function of adsorbate coverage. Adsorbed hydrogen exists in three distinct phases. At low coverages the hydrogen…

Materials Science · Physics 2009-11-07 Aubrey T. Hanbicki , P. J. Rous , E. W. Plummer

The behaviors of hydrogen (H) in MAX phase material Ti3SiC2 have been investigated using first-principles method. We show that a single H atom prefers to stay 1.01 {\AA} down of the Si vacancy with solution energy of about -4.07 eV,…

Materials Science · Physics 2013-08-06 Yi-Guo Xu , Xue-Dong Ou , Xi-Ming Rong

We propose a method to simulate a-Si and a-Si:H using an ab initio approach based on the Harris functional and thermally amorphisized periodically continued cells with at least 64 atoms, and calculate their radial distribution functions.…

Materials Science · Physics 2009-10-31 Ariel A. Valladares , Fernando Alvarez , Zhihua Liu , Juergen Stitcht , John Harris

The hydrogen dynamics on a graphene sheet is studied in the presence of carbon vacancies. We analyze the motion of atomic H by means of molecular dynamics (MD) simulations, using a tight-binding Hamiltonian fitted to density-functional…

Chemical Physics · Physics 2022-09-29 Carlos P. Herrero , Jose A. Verges , Rafael Ramirez

The efficiency of silicon solar cells gradually decreases in various environments, with humidity being a key factor contributing to this decline through moisture-induced degradation (MID) involving multiple mechanisms including encapsulant…

Materials Science · Physics 2026-03-13 Bo Li , Feifei Zhang , Yu Pang , Jinyu Hu , Huiyan Zhao , Guocai Liu , Chao He , Xingtao An