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Using density-functional theory and a tight-binding approach we investigate the physical origin of distinct favourable geometries of adsorbed hydrogen atoms in various graphyne structures, and the relation with electronic properties. In…

Materials Science · Physics 2014-02-07 Hunpyo Lee , Jahyun Koo , Massimo Capone , Yongkyung Kwon , Hoonkyung Lee

Amorphous hydrogenated silicon (a-Si:H) is an important material for surface defect passivation of photovoltaic silicon (Si) wafers in order to reduce their recombination losses. The material is however unstable with regards to hydrogen (H)…

A pi-conjugated {C}3h-oligomer involving three dithienylethylene branches bridged at the meta positions of a central benzenic core has been synthesized and deposited either on the Si(100) surface or on the HOPG surface. On the silicon…

We use scanning tunneling microscopy (STM) and Auger electron spectroscopy to study the behavior of adsorbed phosphine (PH$_{3}$) on Si(001), as a function of annealing temperature, paying particular attention to the formation of the Si-P…

Materials Science · Physics 2007-05-23 N. J. Curson , S. R. Schofield , M. Y. Simmons , L. Oberbeck , J. L. O'Brien , R. G. Clark

The dipole force components in nano-sized metal hydrides are quantitatively determined with curvature and x-ray diffraction measurements. Ab-initio density functional theory is used to calculate the dipole components and the symmetry of the…

Mesoscale and Nanoscale Physics · Physics 2016-05-30 Gunnar K. Pálsson , Moritz Wälde , Martin Amft , Yuanyuan Wu , Martina Ahlberg , Max Wolff , Astrid Pundt , Björgvin Hjörvarsson

We present a 2D lattice model of water to study the effects of ion hydration on the properties of water. We map the water molecules as lattice particles consisting of a single Oxygen at the center of a site and two Hydrogen atoms on each…

Soft Condensed Matter · Physics 2015-11-12 S. Dutta , Yongjin Lee , Y. S. Jho

We report results of a theoretical study on an adsorbate induced surface reconstruction. Hydrogen adsorption on a W(100) surface causes a switching transition in the symmetry of the displacements of the W atoms within the ordered c(2x2)…

Condensed Matter · Physics 2009-10-22 Kari Kankaala , Tapio Ala-Nissila , See-Chen Ying

The absorption energy of atomic hydrogen at rotated graphene bilayers is studied using ab initio methods based on the density functional theory including van der Waals interactions. We find that, due to the surface corrugation induced by…

Mesoscale and Nanoscale Physics · Physics 2017-10-06 Ivan Brihuega , Felix Yndurain

In order to clarify the physics of the gating of solids by ionic liquids (ILs) we have gated lightly doped $p$-Si, which is so well studied that it can be called the "hydrogen atom of solid state physics" and can be used as a test bed for…

Mesoscale and Nanoscale Physics · Physics 2015-08-26 J. Nelson , K. V. Reich , M. Sammon , B. I. Shklovskii , A. M. Goldman

We have performed time-dependent density functional theory simulations for the neutralization process of a hydrogen ion injected at 100eV onto the (110) surface of tungsten material. We have also proposed a method for evaluating the…

Chemical Physics · Physics 2024-07-04 Yuto Toda , Arimichi Takayama , Atsushi M. Ito

The influence of nitrogen incorporation on the energy distribution of interface states in the (100)Si/HfO2 system and their passivation by hydrogen have been studied. The results are compared to those of nominally N-free samples. The…

Materials Science · Physics 2014-06-26 Y. G. Fedorenko , L. Truong , V. V. Afanas'ev , A. Stesmans , Z. Zhang , S. A. Campbell

The creation of magnetism on non-magnetic semiconductor surfaces is of importance for the realization of spintronics devices. Especially, the coupling of electron spins within quantum nanostructures can be utilized for nanomagnetism…

Mesoscale and Nanoscale Physics · Physics 2018-11-21 Xiao-Yan Ren , Chun-Yao Niu , Seho Yi , Shunfang Li , Jun-Hyung Cho

Using helium-3 atom scattering, we have studied the adsorption kinetics, the structure and the diffusional dynamics of atomic hydrogen on the surface of a graphene monolayer on Ni(111). Diffraction measurements reveal a 4$^\circ$ rotated…

Mesoscale and Nanoscale Physics · Physics 2022-12-15 Emanuel Bahn , Anton Tamtögl , John Ellis , William Allison , Peter Fouquet

Hydrogen as a fuel can be stored safely with high volumetric density in metals. It can, however, also be detrimental to metals causing embrittlement. Understanding fundamental behavior of hydrogen at atomic scale is key to improve the…

Materials Science · Physics 2020-02-05 Sytze de Graaf , Jamo Momand , Christoph Mitterbauer , Sorin Lazar , Bart J. Kooi

Density functional theory has been used to study the adsorption of molecular H2 on a graphene layer. Different adsorption sites on top of atoms, bonds and the center of carbon hexagons have been considered and compared. We conclude that the…

Chemical Physics · Physics 2009-11-06 J. S. Arellano , L. M. Molina , A. Rubio , J. A. Alonso

We determine the ground-state structure of a double vacancy in a hydrogen monolayer on the Pd(111) surface. We represent the double vacancy as a triple vacancy containing one additional hydrogen atom. The potential-energy surface for a…

Materials Science · Physics 2009-11-13 Sungho Kim , Seong-Gon Kim , S. C. Erwin

Hydrogen activation is a key elementary step in catalytic hydrogenation. In heterogeneous catalysis, it usually proceeds through dissociative adsorption on metal nanoparticles followed by surface diffusion or spillover, whereas homogeneous…

Chemical adsorption of atomic hydrogen on a negatively charged single layer graphene sheet has been analyzed with ab-initio Density Functional Theory calculations. We have simulated both finite clusters and infinite periodic systems to…

Materials Science · Physics 2015-05-18 J. A. Verges , P. L. de Andres

Si deposition on H terminated Si(100)-2x1 and 3x1 surfaces at temperatures 300-530 K is studied by scanning tunneling microscopy. Hydrogen apparently hinders Si adatom diffusion and enhances surface roughening. The post-growth annealing…

Materials Science · Physics 2009-11-10 Jeong-Young Ji , T. -C. Shen

Hydrogen bond is often assumed to be a purely electrostatic interaction between a electron-deficient hydrogen atom and a region of high electron density. Here, for the first time, we directly image hydrogen bond in real space by…

Chemical Physics · Physics 2013-02-28 Xiu Chen , Shuyi Liu , Lacheng Liu , Xiaoqing Liu , Yingxing Cai , Nianhua Liu , Li Wang