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We present a numerical method for grand canonical density functional theory (DFT) tailored to solid-state systems, employing Gaussian-type orbitals as the primary basis. Our approach directly minimizes the grand canonical free energy using…

Chemical Physics · Physics 2025-10-09 Anton Z. Ni , Adam Rettig , Joonho Lee

A fast algorithm (linear in the degrees of freedom) for the solution of linear variable-coefficient rational-order fractional integral and differential equations is described. The approach is related to the ultraspherical method for…

Numerical Analysis · Mathematics 2017-12-04 Nicholas Hale , Sheehan Olver

A spectral method is developed for the direct solution of linear ordinary differential equations with variable coefficients. The method leads to matrices which are almost banded, and a numerical solver is presented that takes O(m^2n)…

Numerical Analysis · Mathematics 2012-08-16 Sheehan Olver , Alex Townsend

We present a real-time second-order Green's function (GF) method for computing excited states in molecules and nanostructures, with a computational scaling of $O(N_{\rm e}^3$), where $N_{\rm e}$ is the number of electrons. The cubic scaling…

Chemical Physics · Physics 2024-01-29 Leopoldo Mejía , Jia Yin , David R. Reichman , Roi Baer , Chao Yang , Eran Rabani

Spectral measures arise in numerous applications such as quantum mechanics, signal processing, resonances, and fluid stability. Similarly, spectral decompositions (pure point, absolutely continuous and singular continuous) often…

Spectral Theory · Mathematics 2021-03-02 Matthew John Colbrook

We present a machine learning algorithm for the prediction of molecule properties inspired by ideas from density functional theory. Using Gaussian-type orbital functions, we create surrogate electronic densities of the molecule from which…

Chemical Physics · Physics 2019-11-27 Michael Eickenberg , Georgios Exarchakis , Matthew Hirn , Stéphane Mallat , Louis Thiry

Within the well-established optical response function formalism, a new strategy with the central idea of employing the forward-backward stochastic Schr\"{o}dinger equations in a segmented way to accurately obtain the two-dimensional (2D)…

Chemical Physics · Physics 2018-08-08 Yaling Ke , Yi Zhao

The main result of this thesis is an efficient protocol to determine the frequencies of a signal $C(t)= \sum_k |a_k|^2 e^{i \omega_k t}$, which is given for a finite time, to a high degree of precision. Specifically, we develop a theorem…

Mathematical Physics · Physics 2024-12-12 Timothy Stroschein

Hard X-ray spectra in solar flares provide knowledge of the electron spectrum that results from acceleration and propagation in the solar atmosphere. However, the inference of the electron spectra from solar X-ray spectra is an ill-posed…

Astrophysics · Physics 2009-11-10 E. P. Kontar , M. Piana , A. M. Massone , A. G. Emslie , J. C. Brown

In this work, we first give some mathematical preliminaries concerning the generalized prolate spheroidal wave function (GPSWFs). These set of special functions have been introduced in [16] and [7] and they are defined as the infinite and…

Classical Analysis and ODEs · Mathematics 2023-01-24 NourElHouda Bourguiba , Souabni Ahmed

We propose a multiscale spectral generalized finite element method (MS-GFEM) for discontinuous Galerkin (DG) discretizations. The method builds local approximations on overlapping subdomains as the sum of a local source solution and a…

Numerical Analysis · Mathematics 2026-01-15 Christian Alber , Lukas Holbach

The first focus of this paper is the characterization of the spectrum and the singular values of the coefficient matrix stemming from the discretization with space-time grid for a parabolic diffusion problem and from the approximation of…

Numerical Analysis · Mathematics 2023-02-17 Matthias Bolten , Sven-Erik Ekström , Isabella Furci , Stefano Serra-Capizzano

We present a real-space formulation and higher-order finite-difference implementation of periodic Orbital-free Density Functional Theory (OF-DFT). Specifically, utilizing a local reformulation of the electrostatic and kernel terms, we…

Computational Physics · Physics 2015-12-23 Swarnava Ghosh , Phanish Suryanarayana

Koopmans spectral functionals aim to describe simultaneously ground state properties and charged excitations of atoms, molecules, nanostructures and periodic crystals. This is achieved by augmenting standard density functionals with simple…

Materials Science · Physics 2022-07-25 Nicola Colonna , Riccardo De Gennaro , Edward Linscott , Nicola Marzari

The application of orthonormal basis functions such as Prolate Spheroidal Wave Functions (PSWF) for accurate source modeling in radio astronomy has been comprehensively studied. They are of great importance for high fidelity, high dynamic…

Instrumentation and Methods for Astrophysics · Physics 2011-11-03 Parisa Noorishad , Sarod Yatawatta

We develop a non-Gaussian variational approach that enables us to study both equilibrium and far-from-equilibrium physics of the two-dimensional Fermi polaron. This method provides an unbiased analysis of the polaron-to-molecule phase…

Quantum Gases · Physics 2026-05-01 Yi-Fan Qu , Pavel E. Dolgirev , Eugene Demler , Tao Shi

Duo is a general, user-friendly program for computing rotational, rovibrational and rovibronic spectra of diatomic molecules. Duo solves the Schr\"{o}dinger equation for the motion of the nuclei not only for the simple case of uncoupled,…

Computational Physics · Physics 2016-07-05 Sergei N. Yurchenko , Lorenzo Lodi , Jonathan Tennyson , Andrey V. Stolyarov

In this work, a Generalized Finite Difference (GFD) scheme is presented for effectively computing the numerical solution of a parabolic-elliptic system modelling a bacterial strain with density-suppressed motility. The GFD method is a…

Numerical Analysis · Mathematics 2024-01-29 Federico Herrero-Hervás

Spectroscopic techniques are very essential tools in studying electronic structures, spectroscopic constants and energetic properties of diatomic molecules. These techniques are also required for parametrization of new method based on…

Chemical Physics · Physics 2015-04-15 Babatunde J. Falaye , Sameer M. Ikhdair , Majid Hamzavi

In this paper, we discuss the application of the Generalized Finite Element Method (GFEM) to approximate the solutions of quasilinear elliptic equations with multiple interfaces in one dimensional space. The problem is characterized by…

Numerical Analysis · Mathematics 2021-02-02 Tilsa Aryeni , Quanling Deng , Victor Ginting