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Over the past decades, there has been significant interest in new cooling technology based on the electrocaloric effect. The large electrocaloric effect observed in polymeric and inorganic ferroelectric materials made possible development…

Materials Science · Physics 2020-12-14 B. Asbani , J. -L. Dellis , A. Lahmar , M. Amjoud , Y. Gagou , D. Mezzane , Z. Kutnjak , R. Pirc , M. El Marssi , B. Rožič

The electrocaloric (EC) effect and energy storage properties of eco-friendly ferroelectric Ba0.9Sr0.1Ti1-xSnxO3 (BSTS-x) ceramics prepared by the conventional solid-state reaction method were studied. Significant energy efficiency exceeding…

Atomistic effective Hamiltonian simulations are used to investigate electrocaloric (EC) effects in the lead-free Ba(Zr$_{0.5}$Ti$_{0.5}$)O$_{3}$ (BZT) relaxor ferroelectric. We find that the EC coefficient varies non-monotonically with the…

Materials Science · Physics 2017-07-25 Zhijun Jiang , Sergei Prokhorenko , Sergey Prosandeev , Y. Nahas , D. Wang , J. Íñiguez , E. Defay , L. Bellaiche

Perovskite-type Ba0.9Sr0.1Ti0.9Sn0.1O3(BSTSn) ceramic was synthesized by the sol gel method. The P E hysteresis loops were recorded at different temperatures to investigate the ferroelectric and energy storage properties of BSTSn ceramic.…

Materials Science · Physics 2023-06-13 S. Khardazi , H. Zaitouni , S. Belkhadir , D. Mezzane , M. Amjoud , Y. Gagou , B. Asbani , I. Lukyanchuk , S. Terenchuk

A material with reversible temperature change capability under an external electric field, known as the electrocaloric effect (ECE), has long been considered as a promising solid-state cooling solution. However, electrocaloric (EC)…

The electrocaloric effect (ECE) of BaZr$_{x}$Ti$_{1-x}$O$_3$ (BZT) is closely related to the relaxor state transition of the materials. This work presents a systematic study on the ECE and the state transition of the BZT, using a combined…

The electrocaloric (EC) effect offers a promising energy-efficient and clean cooling technology. We present the first direct measurements of EC temperature change in a new family of EC fluids, ferroelectric nematic liquid crystals (FNLCs),…

The present letter explores the electrocaloric effect (ECE) in the lead free oxide Ba0.8Ca0.2Ti0.95Ge0.05O3 ceramics (BCTG). The electrocaloric responsivity (dT/dE) was determined by two different methods using the Maxwell relationship…

Materials Science · Physics 2015-10-28 B. Asbani , J. -L. Dellis , Y. Gagou , H. Kaddoussi , A. Lahmar , M. Amjoud , D. Mezzane , Z. Kutnjak , M. El Marssi

The coexistence of multiple structural phases and field induced short-range to long-range order transition in ferroelectric materials, leads to a strong electrocaloric effect (ECE) and electrical energy storage density (Wrec) in the…

Giant electrocaloric (EC) effect is observed in BaTiO3 multilayer thick film structure. The temperature change is as high as 4.0 oC under an applied electric field of 352 kV/cm. Most importantly, the EC effect is found to depend on the…

Materials Science · Physics 2015-05-18 Yang Bai , Guang-Ping Zheng , San-Qiang Shi

A-site deficient Ba$_{0.975}$La$_{0.017}$(ZrxTi$_{0.95-x}$)Sn$_{0.05}$O$_3$ (x = 0.05; 0.20) ceramics (BLaZ100xTS) were synthesized using the solid-state reaction. The microstructural study revealed a high density and low porosity in the…

Materials Science · Physics 2020-12-09 Sihem Smail , Manal Benyoussef , Kamel Taïbi , Bouchai Manoun , Mimoun El Marssi , Abdelilah Lahmar

Lead-free BaTi0.89Sn0.11O3 (BTSn) ceramic was elaborated via a solid-state reaction method and its dielectric, ferroelectric, energy storage, electromechanical as well as electrocaloric properties were investigated at 25 kV/cm. Pure…

An atomistic effective Hamiltonian is used to investigate electrocaloric (EC) effects of Pb(Mg$_{1/3}$Nb$_{2/3}$)O$_{3}$ (PMN) relaxor ferroelectrics in its ergodic regime, and subject to electric fields applied along the pseudocubic [111]…

Materials Science · Physics 2018-04-03 Zhijun Jiang , Y. Nahas , S. Prokhorenko , S. Prosandeev , D. Wang , Jorge Íñiguez , L. Bellaiche

Lead-free Ba0.85Ca0.15Zr0.10Ti0.90O3 (BCZT) ceramic exhibits excellent dielectric, ferroelectric and piezoelectric properties at the Morphotropic Phase Boundary (MPB). Previously, we demonstrated that the use of the anionic surfactant…

Lead-free ba0.85ca0.15zr0.1ti0.9o3 (bczt) ceramic powders were synthesized using the sol-gel method. to achieve high-energy storage and large electrocaloric effect in bulk ceramics the ceramics thickness was reduced. dielectric,…

Structural, dielectric, ferroelectric, energy storage properties, and electrocaloric effect were studied in lead-free ceramic Ba$_{0.95}$Ca$_{0.05}$Ti$_{0.89}$Sn$_{0.11}$O$_3$ (BCTSn) elaborated by sol-gel method. Phase purity structure was…

The electrocaloric (EC) effect is calculated for Gd-substituted PMN (x = 0 to 0.1) relaxors from temperature dependent heat capacity and polarization measurements, using a thermodynamic Maxwell equation. Polarization change with temperature…

Materials Science · Physics 2018-11-01 Adityanarayan H. Pandey , A. M. Awasthi , Surya Mohan Gupta

Many ferroelectric devices are based on doped lead zirconate titanate (PZT) ceramics with compositions near the morphotropic phase boundary (MPB), at which the relevant material's properties approach their maximum. Based on a synchrotron…

Electrocaloric (EC) materials show promise in eco-friendly solid-state refrigeration and integrable on-chip thermal management. While direct measurement of EC thin-films still remains challenging, a generic theoretical framework for…

Materials Science · Physics 2021-04-21 Yuping Shi , Limin Huang , Ai Kah Soh , George J. Weng , Shuangyi Liu , Simon A. T. Redfern

Solid-state cooling applications based on the electrocaloric (EC) effect are particularly promising from a technological point of view due to their downsize scalability and natural implementation in circuitry. However, EC effects typically…

Materials Science · Physics 2023-07-19 César Menéndez , Claudio Cazorla
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