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The Kitaev spin model offers an exact quantum spin liquid in the ground state, which has stimulated exploration of its material realization over the last decade. Thus far, most of the candidates are found in $4d$- and $5d$-electron…

Strongly Correlated Electrons · Physics 2020-11-03 Seong-Hoon Jang , Ryoya Sano , Yasuyuki Kato , Yukitoshi Motome

Finding new materials with antiferromagnetic (AFM) Kitaev interaction is an urgent issue to broaden and enrich the quantum magnetism research significantly. By carrying out inelastic neutron scattering experiments and subsequent analysis,…

Co$^{2+}$ ions in an octahedral crystal field, stabilise a j$_{eff}$ = 1/2 ground state with an orbital degree of freedom and have been recently put forward for realising Kitaev interactions, a prediction we have tested by investigating…

In the Kitaev honeycomb model, spins coupled by strongly-frustrated anisotropic interactions do not order at low temperature but instead form a quantum spin liquid with spin fractionalization into Majorana fermions and static fluxes. The…

Layered honeycomb magnets are of interest as potential realizations of the Kitaev quantum spin liquid (KQSL), a quantum state with long-range spin entanglement and an exactly solvable Hamiltonian. Conventional magnetically ordered states…

Strongly Correlated Electrons · Physics 2020-01-28 Ruidan Zhong , Tong Gao , Nai Phuan Ong , Robert J. Cava

A polycrystalline sample of the hyperhoneycomb iridate $\beta$-ZnIrO$_3$ was synthesized via a topochemical reaction, and its structural, magnetic, and thermodynamic properties were investigated. The magnetization and heat capacity data…

Strongly Correlated Electrons · Physics 2022-02-17 Yuya Haraguchi , Akira Matsuo , Koichi Kindo , Hiroko Aruga Katori

We investigate the ground state properties of the spin S=1 Kitaev honeycomb model under a magnetic field based on the density matrix renormalization group (DMRG) calculation. With the time reversal symmetry breaking due to the magnetic…

Strongly Correlated Electrons · Physics 2020-09-23 Zheng Zhu , Zheng-Yu Weng , D. N. Sheng

The layered honeycomb magnet $\alpha$-Li$_2$IrO$_3$ has been theoretically proposed as a candidate to display novel magnetic behaviour associated with Kitaev interactions between spin-orbit entangled $j_{\rm eff}=1/2$ magnetic moments on a…

Strongly Correlated Electrons · Physics 2017-02-17 S. C. Williams , R. D. Johnson , F. Freund , Sungkyun Choi , A. Jesche , I. Kimchi , S. Manni , A. Bombardi , P. Manuel , P. Gegenwart , R. Coldea

Cobaltates with 3$d$ based layered honeycomb structure were recently proposed as Kitaev magnets and putative candidates to host the long-sought Kitaev spin liquid. Here we present inelastic neutron scattering results down to 50 mK for…

Strongly Correlated Electrons · Physics 2023-01-18 Alaric L. Sanders , Richard A. Mole , Jiatu Liu , Alex J. Brown , Dehong Yu , Chris D. Ling , Stephan Rachel

The 3$d^7$ Co$^{2+}$-based insulating magnet \NCTO{} has recently been reported to have strong Kitaev interactions on a honeycomb lattice, and is thus being considered as a Kitaev quantum spin liquid candidate. However, due to the existence…

We theoretically propose a family of $f$-electron based magnets that realizes Kitaev-type bond-dependent anisotropic interactions. Based on {\it ab initio} calculations, we show that $A_2$PrO$_3$ ($A$: alkali metals) crystalize in a…

Strongly Correlated Electrons · Physics 2020-11-03 Seong-Hoon Jang , Ryoya Sano , Yasuyuki Kato , Yukitoshi Motome

We report the magnetic properties of CaCo$_2$TeO$_6$ as a Kitaev candidate. CaCo$_2$TeO$_6$ was synthesized through a topochemical process, wherein all Na$^+$ ions in Na$_2$Co$_2$TeO$_6$ were replaced with half the amount of Ca$^{2+}$ ions.…

Strongly Correlated Electrons · Physics 2025-04-03 Yuya Haraguchi , Yuto Yoshida , Akira Matsuo , Koichi Kindo , Hiroko Aruga Katori

We have investigated the magnetic properties and mapped out the phase diagram of the honeycomb magnet Na2Co2TeO6 with Co 3d7 in out-of-plane magnetic fields. This material has previously been proposed to show nearest-neighbor Kitaev…

Strongly Correlated Electrons · Physics 2024-06-03 Shengzhi Zhang , Sangyun Lee , Eric Brosha , Qing Huang , Haidong Zhou , Vivien S. Zapf , Minseong Lee

We report the synthesis and properties of (H,Li)$_{6}$Ru$_{2}$O$_{6}$, which is shown to be a $J_{\text{eff}}=\frac{1}{2}$ system made out of Ru$^{3+}$ moments in a honeycomb geometry. Bulk magnetization, heat capacity, nuclear magnetic…

Strongly Correlated Electrons · Physics 2025-02-06 Sanjay Bachhar , M. Baenitz , Hubertus Luetkens , John Wilkinson , Sumiran Pujari , A. V. Mahajan

In the search for quantum spin liquids, candidate materials for the Kitaev model and its extensions have been intensively explored during the past decade, as the models realize the exact quantum spin liquids in the ground state. Thus far,…

Strongly Correlated Electrons · Physics 2018-01-22 Ryoya Sano , Yasuyuki Kato , Yukitoshi Motome

We explore the potential experimental realization of the mixed-spin Kitaev model in materials such as Zr$_{0.5}$Ru$_{0.5}$Cl$_3$, where spin-1/2 and spin-3/2 ions occupy distinct sublattices of a honeycomb lattice. By developing a…

Strongly Correlated Electrons · Physics 2025-05-09 Willian Natori , Yang Yang , Hui-Ke Jin , Johannes Knolle , Natalia B. Perkins

Anderson proposed structural topology in frustrated magnets hosting novel quantum spin liquids (QSLs). The QSL state is indeed exactly derived by fractionalizing the spin excitation into spinless Majorana fermions in a perfect two…

Intensive studies of the interplay between spin-orbit coupling (SOC) and electronic correlations in transition metal compounds have recently been undertaken. In particular, $j_{\rm eff}$ = 1/2 bands on a honeycomb lattice provide a pathway…

Strongly Correlated Electrons · Physics 2015-06-24 Heung-Sik Kim , V. Vijay Shankar , Andrei Catuneanu , Hae-Young Kee

Na$_2$IrO$_3$, a honeycomb 5$d^5$ oxide, has been recently identified as a potential realization of the Kitaev spin lattice. The basic feature of this spin model is that for each of the three metal-metal links emerging out of a metal site,…

Competition and cooperation between electron correlation and relativistic spin-orbit coupling give rise to diverse exotic quantum phenomena in solids. An illustrative example is spin-orbit entangled quantum liquids, which exhibit remarkable…

Strongly Correlated Electrons · Physics 2024-03-15 Yi-Feng Zhao , Seong-Hoon Jang , Yukitoshi Motome
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