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We show how to construct non-equilibrium thermodynamics for systems too small to be considered thermodynamically in a traditional sense. Through the use of a non-equilibrium ensemble of many replicas of the system which can be viewed as a…

Statistical Mechanics · Physics 2007-05-23 J. M. Rubi , D. Bedeaux , S. Kjelstrup

Implicit rate-type constitutive relations utilizing discontinuous functions provide a novel approach to the purely phenomenological description of the inelastic response of solids undergoing finite deformation. However, this type of…

Soft Condensed Matter · Physics 2020-07-02 David Cichra , Vít Průša

Starting from microscopic mechanics, we derive thermodynamic relations for heat conducting nonequilibrium steady states. The extended Clausius relation enables one to experimentally determine nonequilibrium entropy to the second order in…

Statistical Mechanics · Physics 2009-11-13 Teruhisa S. Komatsu , Naoko Nakagawa , Shin-ichi Sasa , Hal Tasaki

As an extension to strain-gradient models of size-dependent plastic behaviour, this work proposes a model for a stress-gradient theory. The model is distinguished from earlier works on the topic by its being embedded in a thermodynamically…

Materials Science · Physics 2020-12-30 B. D. Reddy , P. Steinmann , A. Kergassner

Reformulating constitutive relation in terms of gradient dynamics (being derivative of a dissipation potential) brings additional information on stability, metastability and instability of the dynamics with respect to perturbations of the…

Fluid Dynamics · Physics 2018-05-09 Adam Janečka , Michal Pavelka

Recently a number of approaches has been developed to connect the microscopic dynamics of particle systems to the macroscopic properties of systems in nonequilibrium stationary states, via the theory of dynamical systems. This way a direct…

Statistical Mechanics · Physics 2009-10-31 L. Rondoni , E. G. D. Cohen

Thermodynamic relations are derived from first principles of mechanics for non-equilibrium processes. Since the key role herein is played by the law of increase of entropy, the latter is analyzed at first. It is shown that its derivation…

chao-dyn · Physics 2008-02-03 J. Kumicak , X. de Hemptinne

Statistical thermodynamics is valuable as a conceptual structure that shapes our thinking about equilibrium thermodynamic states. A cloud of unresolved questions surrounding the foundations of the theory could lead an impartial observer to…

Statistical Mechanics · Physics 2025-10-31 O. B. Ericok , J. K. Mason

Reciprocal relations correlate fairly accurately a great variety of experimental results. Nevertheless, the concepts of statistical fluctuations, and microscopic reversibility - the bases of the accepted proof of the relations by Onsager -…

Chemical Physics · Physics 2007-05-23 Elias P. Gyftopoulos

The use of statistical methods to model gravitational systems is crucial to physics practice, but the extent to which thermodynamics and statistical mechanics genuinely apply to these systems is a contentious issue. This paper provides new…

History and Philosophy of Physics · Physics 2025-02-04 Lorenzo Lorenzetti

We assume that markovian dynamics on a finite graph enjoys a gauge symmetry under local scalings of the probability density, derive the transformation law for the transition rates and interpret the thermodynamic force as a gauge potential.…

Statistical Mechanics · Physics 2015-05-30 Matteo Polettini

Stochastic Thermodynamics (ST) extends the notions of classical thermodynamics to trajectories taken from a nonequilibrium ensemble. This extension yields a simple approach to fluctuation relations in small systems. Multiple time- and…

Statistical Mechanics · Physics 2012-10-19 Bernhard Altaner

We present a physics-based neural network framework for the discovery of constitutive models in fully coupled thermomechanics. In contrast to classical formulations based on the Helmholtz energy, we adopt the internal energy and a…

Computational Engineering, Finance, and Science · Computer Science 2026-05-25 Hagen Holthusen , Paul Steinmann , Ellen Kuhl

The generalized Gibbs free energy and enthalpy is derived in the framework of nonextensive thermodynamics by using the so-called physical temperature and the physical pressure. Some thermodynamical relations are studied by considering the…

Statistical Mechanics · Physics 2015-08-10 Lina Gu , Jiulin Du

We explore the consequences of a deterministic microscopic thermostat-reservoir contact mechanism. With different temperature reservoirs at each end of a two-dimensional system, a heat current is produced and the system has an anomalous…

Statistical Mechanics · Physics 2015-06-15 Gary P. Morriss , Daniel P. Truant

A simple and effective approach to thermodynamics is suggested, which solves the major difficulties in the traditional presentation of the subject. The internal energy is introduced from the behavior of deformable bodies, whereas the…

General Physics · Physics 2012-03-13 Rodrigo de Abreu , Vasco Guerra

In the mechanics of inviscid conservative fluids, it is classical to generate the equations of dynamics by formulating with adequate variables, that the pressure integral calculated in the time-space domain corresponding to the motion of…

Classical Physics · Physics 2008-07-23 Henri Gouin , Jean-François Debieve

A thermodynamically consistent model of non-classical coupled non-linear thermoelasticity capable of accounting for thermal wave propagation is proposed. The heat flux is assumed to consist of both additive energetic and dissipative…

Statistical Mechanics · Physics 2015-07-20 Mebratu F. Wakeni , B. D. Reddy , A. T. McBride

An irreversible thermodynamical theory of solids is presented where the kinematic quantities are defined in an automatically objective way. Namely, auxiliary elements like reference frame, reference time and reference configuration are…

Classical Physics · Physics 2015-12-22 Tamás Fülöp

In this article, we study a thermodynamically consistent thermo-visco-elastic model describing the balance of internal energy in a heat-conducting inelastic body. In the considered problem, the temperature dependence appears in both the…

Analysis of PDEs · Mathematics 2025-11-13 Tomasz Cieślak , Sebastian Owczarek , Karolina Wielgos
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