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A new perturbative approach to canonical equation-of-motion coupled-cluster theory is presented using coupled-cluster perturbation theory. A second-order M{\o}ller-Plesset partitioning of the Hamiltonian is used to obtain the well known…

Chemical Physics · Physics 2015-07-09 Jason N. Byrd , Varun Rishi , Ajith Perera , Rodney J. Bartlett

Accurate many-body treatments of condensed-phase systems are challenging because correlated solvers such as full configuration interaction (FCI) and the density matrix renormalization group (DMRG) scale exponentially with system size.…

We propose a general strategy to develop quantum many-body approximations of primitives in linear algebra algorithms. As a practical example, we introduce a coupled-cluster inspired framework to produce approximate Hamiltonian moments, and…

Chemical Physics · Physics 2025-12-30 Yuhang Ai , Huanchen Zhai , Johannes Tölle , Garnet Kin-Lic Chan

Ab initio nuclear many-body frameworks require extensive computational resources, especially when targeting heavier nuclei. Importance-truncation (IT) techniques allow to significantly reduce the dimensionality of the problem by neglecting…

Nuclear Theory · Physics 2022-03-31 J. Hoppe , A. Tichai , M. Heinz , K. Hebeler , A. Schwenk

Most nonrelativistic electron correlation methods can be adapted to account for relativistic effects, as long as the relativistic molecular spinor integrals are available, from either a four-, two-, or one-component mean-field calculation.…

Strongly Correlated Electrons · Physics 2024-07-17 Zijun Zhao , Francesco A. Evangelista

A distorted-wave version of the renormalisation group is applied to scattering by an inverse-square potential and to three-body systems. In attractive three-body systems, the short-distance wave function satisfies a Schroedinger equation…

Nuclear Theory · Physics 2009-11-10 Thomas Barford , Michael C. Birse

We report a spin-free formulation of the multireference (MR) driven similarity renormalization group (DSRG) by employing the ensemble normal ordering of Mukherjee and Kutzelnigg [W. Kutzelnigg and D. Mukherjee, J. Chem. Phys. 107, 432…

Chemical Physics · Physics 2021-10-04 Chenyang Li , Francesco A. Evangelista

We consider renormalization of the three-body scattering problem in low-energy effective field theory of self-interacting scalar particles by applying time-ordered perturbation theory to the manifestly Lorentz-invariant formulation. The…

Nuclear Theory · Physics 2017-06-07 E. Epelbaum , J. Gegelia , Ulf-G. Meißner , De-Liang Yao

The physical properties of a quantum many-body system can, in principle, be determined by diagonalizing the respective Hamiltonian, but the dimensions of its matrix representation scale exponentially with the number of degrees of freedom.…

Strongly Correlated Electrons · Physics 2023-09-13 G. Catarina , Bruno Murta

The study of the three-body problem with short-range attractive two-body forces has a rich history going back to the 1930's. Recent applications of effective field theory methods to atomic and nuclear physics have produced a much improved…

Nuclear Theory · Physics 2009-11-11 R. F. Mohr , R. J. Furnstahl , H. -W. Hammer , R. J. Perry , K. G. Wilson

Many-body perturbation theory (MBPT) based on Green's functions and Feynman diagrams provides a fundamental theoretical framework for various \emph{ab initio} computational approaches in molecular and materials science, including the random…

Quantum Physics · Physics 2025-03-20 Yuqi Wang , Wei-Hai Fang , Zhendong Li

We report an efficient implementation of a second-order multireference perturbation theory based on the driven similarity renormalization group (DSRG-MRPT2) [C. Li and F. A. Evangelista, J. Chem. Theory Comput. 11, 2097 (2015)]. Our…

Chemical Physics · Physics 2016-06-22 Kevin P. Hannon , Chenyang Li , Francesco A. Evangelista

For theories with multiple couplings we construct simple expressions for the four-dimensional (or, in general, integer-dimensional) renormalization constants assuming that all divergences are logarithmical. These expressions allow relating…

High Energy Physics - Theory · Physics 2025-12-17 Gleb Kovyrshin , Nikolai Meshcheriakov , Victoria Shatalova , Konstantin Stepanyantz

It is shown how to adapt the non-perturbative coupled cluster method of many-body theory so that it may be successfully applied to Hamiltonian lattice $SU(N)$ gauge theories. The procedure involves first writing the wavefunctions for the…

High Energy Physics - Lattice · Physics 2009-10-22 C. H. Llewellyn Smith , N. J. Watson

There are three essential problems in computational relativistic chemistry: electrons moving at relativistic speeds, close lying states and dynamical correlation. Currently available quantum-chemical methods are capable of solving systems…

Chemical Physics · Physics 2020-05-08 Jan Brandejs , Jakub Višňák , Libor Veis , Maté Mihály , Örs Legeza , Jiří Pittner

The conceptual framework provided by the functional Renormalization Group (fRG) has become a formidable tool to study correlated electron systems on lattices which, in turn, provided great insights to our understanding of complex many-body…

Computational Engineering, Finance, and Science · Computer Science 2016-11-02 Julian Lichtenstein , Jan Winkelmann , David Sánchez de la Peña , Toni Vidović , Edoardo Di Napoli

We present and analyze results of the relativistic coupled-cluster calculation of energies, hyperfine constants, and dipole matrix elements for the $2s$, $2p_{1/2}$, and $2p_{3/2}$ states of Li atom. The calculations are complete through…

Atomic Physics · Physics 2011-07-13 A. Derevianko , S. G. Porsev , K. Beloy

Basis set convergence of correlation effects on molecular atomization energies beyond the CCSD (coupled cluster with singles and doubles) approximation has been studied near the one-particle basis set limit. Quasiperturbative connected…

Chemical Physics · Physics 2008-08-17 Amir Karton , Peter R. Taylor , Jan M. L. Martin

We present a comprehensive review of the In-Medium Similarity Renormalization Group (IM-SRG), a novel ab inito method for nuclei. The IM-SRG employs a continuous unitary transformation of the many-body Hamiltonian to decouple the ground…

Nuclear Theory · Physics 2016-03-15 H. Hergert , S. K. Bogner , T. D. Morris , A. Schwenk , K. Tsukiyama

The in-medium similarity renormalization group (IMSRG) is a powerful and flexible many-body method to compute the structure of nuclei starting from nuclear forces. Recent developments have extended the IMSRG from its standard truncation at…

Nuclear Theory · Physics 2025-03-12 M. Heinz , T. Miyagi , S. R. Stroberg , A. Tichai , K. Hebeler , A. Schwenk