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General features of the $\alpha-\beta$ transition of quartz are investigated. Molecular dynamics methods are mainly used, an analytic treatment being deferred to a work in preparation. A basic preliminary observation is that the transition…

Statistical Mechanics · Physics 2023-07-26 Andrea Carati , Fabrizio Gangemi , Roberto Gangemi , Luigi Galgani

We have performed a combined experimental and theoretical study of ethane and methane at high pressures up to 120 GPa at 300 K using x-ray diffraction and Raman spectroscopy and the USPEX ab-initio evolutionary structural search algorithm,…

We present a combined experimental and theoretical study on the quasi-one-dimensional organic conductor (TMTTF)$_2$PF$_6$, and elucidate the variation of its physical properties under pressure. We fully resolve the crystal structure by…

The high-pressure behaviour of PbS was investigated by angular dispersive X-ray powder diffraction up to pressures of 6.8 GPa. Experiments were accompanied by first principles calculations at the density functional theory level. By…

Materials Science · Physics 2009-11-07 K. Knorr , L. Ehm , M. Hytha , B. Winkler , W. Depmeier

The onset of quartetting, i.e. alpha-particle condensation, in symmetric nuclear matter is studied with the help of an in-medium modified four nucleon equation. It is found that at very low density quartetting wins over pairing, because of…

Nuclear Theory · Physics 2008-09-04 Y. Funaki , T. Yamada , H. Horiuchi , G. Röpke , P. Schuck , A. Tohsaki

Cu2OSeO3 is known as a unique example of insulating multiferroic compounds with skyrmion spin texture, which is characterized by the chiral cubic crystal structure at ambient pressure. Recently, it has been reported that this compound shows…

Strongly Correlated Electrons · Physics 2020-11-18 E. Nishibori , S. Karatsu , C. Terakura , N. Takeshita , M. Kinoshita , S. Ishiwata , Y. Tokura , S. Seki

The response to compression of the clathrate type-II structure Ge(cF136) is investigated by means of \textit{ab initio} small-cell metadynamics at different temperatures and pressures. At lower pressure $p$=2.5 GPa the metastable metallic…

Materials Science · Physics 2022-11-23 Daniele Selli , Igor A. Baburin , Roman Martoňák , Stefano Leoni

We report a joint experimental and theoretical study of the structural, vibrational, and electronic properties of layered monoclinic arsenic sulfide (alpha-As2S3), aka mineral orpiment, under compression. X-ray diffraction and Raman…

Layered transition-metal trichalcogenides have become one of the research frontiers as two-dimensional magnets and candidate materials used for phase-change memory devices. Herein we report the high-pressure synchrotron X-ray diffraction…

Strongly Correlated Electrons · Physics 2019-06-03 Zhenhai Yu , Wei Xia , Kailang Xu , Ming Xu , Hongyuan Wang , Xia Wang , Na Yu , Zhiqiang Zou , Jinggeng Zhao , Lin Wang , Xiangshui Miao , Yanfeng Guo

Strongly anisotropic geomaterials undergo fracture under compressive loading. This paper applies a phase-field fracture model to study this fracture process. While phase-field fracture models have several advantages, they provide unphysical…

The phase diagram of oxygen is investigated for pressures from 50 to 130~GPa and temperatures up 1200 K using first principles theory. A metallic molecular structure with the $P6_3/mmc$ symmetry ($\eta^{'}$ phase) is determined to be…

Computational Physics · Physics 2019-02-19 S. F. Elatresh , S. A. Bonev

Experimental studies established that calcium undergoes several counterintuitive transitions under pressure: fcc \rightarrow bcc \rightarrow simple cubic \rightarrow Ca-IV \rightarrow Ca-V, and becomes a good superconductor in the simple…

Materials Science · Physics 2015-05-20 A. R. Oganov , Y. M. Ma , Y. Xu , I. Errea , A. Bergara , A. O. Lyakhov

We report a study of the high-pressure structural behavior of ZnV2O6, Zn2V2O7, and Zn3V2O8, which has been explored by means of synchrotron powder x-ray diffraction. We found that ZnV2O6 and Zn3V2O8 remain in the ambient-pressure structure…

Unprecedented bright and intense synchrotron X-rays have been widely used to unravel numerous compelling electronic and structural properties using a large variety of physical techniques, while the puzzling phenomenon is the uncertainties…

Materials Science · Physics 2017-05-09 Xinguo Hong , Matt Newville , Ho-Kwang Mao , T. Irifune , L. Huang

Li2FeSiO4 is an important alternative cathode for next generation Li-ion batteries due to its high theoretical capacity (330 mA h/g). However, its development has faced significant challenges arising from structural complexity and poor…

Materials Science · Physics 2016-11-15 P. Vajeeston , H. Fjellvåg

Certain alumino-silicates display exotic properties enabled by their framework structure made of corner-sharing tetrahedral rigid units. Using \textit{in situ} diamond-anvil cell x-ray diffraction (XRD), we study the pressure-induced…

The structural evolution of two selected compositions of Yttria-Stabilized Zirconia (YSZ), with 3mol% (3YSZ) and 8mol% (8YSZ) of Y2O3, have been investigated under pressure using in-situ synchrotron X-ray diffraction (XRD) and Raman…

We have performed experimental and theoretical studies of the structural stability of YAsO4 and YCrO4 at high pressures. X-ray diffraction experiments together with ab initio total-energy and lattice-dynamics calculations have allowed us to…

Materials Science · Physics 2012-01-26 D. Errandonea , R. Kumar , J. Lopez-Solano , P. Rodriguez-Hernandez , A. Munoz , M. G. Rabie , R. Saez Puche

We report on the structural properties of ScAlMgO4 studied under quasi-hydrostatic pressure using synchrotron high-pressure x-ray diffraction up to 40 GPa. We also report on single-crystal studies of ScAlMgO4 performed at 300 K and 100 K.…

Materials Science · Physics 2011-05-19 D. Errandonea , R. S. Kumar , J. Ruiz-Fuertes , A. Segura , E. Haussuehl

The process of structural relaxation in disordered solids subjected to repeated tension-compression loading is studied using molecular dynamics simulations. The binary glass is prepared by rapid cooling well below the glass transition…

Soft Condensed Matter · Physics 2020-05-04 Pritam Kumar Jana , Nikolai V. Priezjev