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In this Chapter we provide an overview of the current first-principles perspective on flexoelectric effects in crystalline solids. We base our theoretical formalism on the long-wave expansion of the electrical response of a crystal to an…

Materials Science · Physics 2015-07-29 Massimiliano Stengel , David Vanderbilt

Relaxor ferroelectrics exhibit a unique competition between long-range and short-range interactions that can be tuned electrically which prioritizes these materials in a broad range of electro-mechanical energy-conversion technologies,…

Applied Physics · Physics 2024-06-18 Cecile Saguy , Benjamin Kowalski , Alp Sehirlioglu , Yachin Ivry

We report on nanoscale strain gradients in ferroelectric HoMnO3 epitaxial thin films, resulting in a giant flexoelectric effect. Using grazing-incidence in-plane X-ray diffraction, we measured strain gradients in the films, which were 6 or…

Materials Science · Physics 2011-09-12 Daesu Lee , A. Yoon , S. Y. Jang , J. -G. Yoon , J. -S. Chung , M. Kim , J. F. Scott , T. W. Noh

Piezoresponse force-microscopy (PFM) has become the standard tool to investigate ferroelectrics on the micro- and nanoscale. However, reliability of PFM signals is often problematic and their quantification is challenging and thus not…

Instrumentation and Detectors · Physics 2016-01-15 L. F. Henrichs , J. Bennett , A. J. Bell

As a first step to meet the challenge to calculate the electronic structure and total energy of charged states of atoms and molecules adsorbed on ultrathin-insulating films supported by a metallic substrate using density functional theory…

Materials Science · Physics 2013-11-01 Iván Scivetti , Mats Persson

Hysteresis is studied for a two-dimensional, spin-1/2, nearest-neighbor, kinetic Ising ferromagnet in an oscillating field, using Monte Carlo simulations and analytical theory. Attention is focused on large systems and strong field…

Statistical Mechanics · Physics 2009-10-31 S. W. Sides , P. A. Rikvold , M. A. Novotny

Low-temperature X-ray photoemission electron microscopy (X-PEEM) is used to measure the electric potential at domain walls in improper ferroelectric Er0.99Ca0.01MnO3. By combining X-PEEM with scanning probe microscopy and theory, we develop…

In the framework of Landau--Ginzburg--Devonshire (LGD) phenomenological theory, the influence of misfit strains, surface energy, and finite-size effects on phase diagrams, polar properties, and hysteresis loops has been calculated for…

Materials Science · Physics 2014-07-01 E. A. Eliseev , M. D. Glinchuk , A. N. Morozovska , Ya. V. Yakovenko

We have proposed the phenomenological description of dielectric hysteresis loops in ferroelectric semiconductors with charged defects and prevailing extrinsic conductivity. Exactly we have modified Landau-Ginsburg approach and shown that…

Materials Science · Physics 2009-11-10 Anna N. Morozovska , Eugene A. Eliseev

Ferroelectric thin films present a powerful platform for next generation computing and memory applications. However, domain morphology and dynamics in buried ferroelectric stacks have remained underexplored, despite the importance for real…

Materials Science · Physics 2025-08-29 Megan O. Hill Landberg , Bixin Yan , Huaiyu Chen , Efe Ipek , Morgan Trassin , Jesper Wallentin

Ferroelectric materials possess spontaneous polarization that can be used for multiple applications. Owing to a long term development for reducing the sizes of devices, the preparation of ferroelectric materials and devices are entering…

We report the first investigation of the piezoelectric response on a nanoscale in the poled ferroelectric crystals with engineered configuration of domains. Piezoresponse force microscopy of tetragonal 0.63PMN-0.37PT relaxor-based…

Materials Science · Physics 2011-08-23 Haiyan Guo , Alexei A. Bokov , Zuo-Guang Ye

Precise control of surface properties including electrical characteristics, wettability, and friction is a prerequisite for manufacturing modern organic electronic devices. The successful combination of bottom up approaches for aligning and…

Materials Science · Physics 2011-07-05 G. Hlawacek , Q. Shen , C. Teichert , A. Lex , G. Trimmel , W. Kern

Resolving growth mechanisms and thickness evolution of functional properties is one of the key tasks in materials discovery and optimization involving thin-film materials, traditionally requiring significant experimental budgets. Here we…

Materials Science · Physics 2026-03-02 Yu Liu , Yi-Xiu Chen , Haotong Liang , Ichiro Takeuchi , Sergei V. Kalinin

A memory window of ferroelectric field-effect transistors (FeFETs), defined as a separation of the HIGH-state and the LOW-state threshold voltages, is an important measure of the FeFET memory characteristics. In this study, we theoretically…

Applied Physics · Physics 2022-11-04 Kasidit Toprasertpong , Mitsuru Takenaka , Shinichi Takagi

Micro-Raman spectroscopy has been used to study lattice dynamics associated with the ferroelectric domains of a BiFeO$_3$ single crystal at low temperature. The phonon assignment shows a large frequency splitting between the transverse and…

Strongly Correlated Electrons · Physics 2009-11-13 M. Cazayous , D. Malka , D. Lebeugle , D. Colson

We study the influence of surface anisotropy on the zero-temperature hysteretic properties of a small single-domain magnetic particle, and give an estimation of the anisotropy constant for which deviations from the Stoner-Wohlfarth model…

Statistical Mechanics · Physics 2009-11-07 H. Kachkachi , M. Dimian

We performed analytical calculations of the current-voltage and strain-voltage response of the heterostructure like "charged SPM tip electrode / gap / ionic-semiconductor film" caused by the local changes of (a) ions concentration…

Materials Science · Physics 2010-08-17 A. N. Morozovska , E. A. Eliseev , S. L. Bravina , S. V. Kalinin

We give detailed analysis of the effect of depolarizing field in nanometer-size ferroelectric capacitors studied by Kim et al. [Phys. Rev. Lett. 95, 237602 (2005)]. We calculate a critical thickness of the homogeneous state and its…

Materials Science · Physics 2015-06-25 A. M. Bratkovsky , A. P. Levanyuk

A nanometric needle sensor mounted in an Atomic Force Microscopy allows systematic picometer-range distance measurements. This force sensing device is used in Piezoresponse Force Microscopy (PFM) as a distance sensor, by employing the…

Materials Science · Physics 2017-12-01 A. Gomez , H. T. T Nong , S. Mercone , T. Puig , X. Obradors