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The hybrid form is a combination of the Rydberg potential and the London inverse-sixth-power energy. It is accurate at all relevant distance scales and simple enough for use in all-atom simulations of biomolecules. One may compute the…

Biomolecules · Quantitative Biology 2009-11-13 Kevin Cahill

We studied the van der Waals interactions of two finite, solid, cylindrical rods at arbitrary angle and position with respect to each other. An analytic interpolative formula for the interaction potential energy is constructed, based on…

Soft Condensed Matter · Physics 2018-10-03 Jack A. Logan , Alexei V. Tkachenko

The Lifshitz theory of the van der Waals force is extended for the case of an atom (molecule) interacting with a plane surface of an uniaxial crystal or with a long solid cylinder or cylindrical shell made of isotropic material or uniaxial…

Quantum Physics · Physics 2009-11-11 E. V. Blagov , G. L. Klimchitskaya , V. M. Mostepanenko

On the basis of a general formula obtained earlier via fourth-order erturbation theory within the framework of macroscopic quantum electrodynamics, the van der Waals potential between two neutral, unpolarized, ground-state atoms in the…

Quantum Physics · Physics 2008-08-14 Hassan Safari , Dirk-Gunnar Welsch , Ho Trung Dung , Stefan Yoshi Buhmann

Within the frame of macroscopic quantum electrodynamics in causal media, the van der Waals interaction between an atomic system and an arbitrary arrangement of dispersing and absorbing dielectric bodies including metals is studied. It is…

Quantum Physics · Physics 2007-05-23 Stefan Yoshi Buhmann , Ho Trung Dung , Dirk-Gunnar Welsch

We compute the interaction energies of a two-atom system placed in the middle of a perfectly reflecting planar cavity, in the perturbative regime. Explicit expressions are provided for the van der Waals potentials of two polarisable atomic…

Quantum Physics · Physics 2017-11-01 M. Donaire , J. M. Muñoz-Castañeda , L. M. Nieto

Graphene is a carbon molecule with the structure of a honeycomb lattice. We show how this structure can arise in two dimensions as the minimizer of an interaction energy with two-body and three-body terms. In the engineering literature, the…

Materials Science · Physics 2016-08-25 Brittan Farmer , Selim Esedoglu , Peter Smereka

The Fourier component of the potential energy of interaction of an atom with an atom is represented as a polynomial of the fourth degree from the atomic form factor. A numerical calculation was performed for the atomic form factor in the…

Atomic Physics · Physics 2020-04-28 Vladimir. P. Koshcheev , Dmitry. A. Morgun , Yuriy. N. Shtanov

The Lifshitz-type formulas describing the free energy and the force of the van der Waals interaction between an atom (molecule) and a single-wall carbon nanotube are obtained. The single-wall nanotube is considered as a cylindrical sheet…

Materials Science · Physics 2009-11-13 E. V. Blagov , G. L. Klimchitskaya , V. M. Mostepanenko

We consider a multiatomic system where the nuclei are assumed to be point charges at fixed positions. Particles interact via Coulomb potential and electrons have pseudo-relativistic kinetic energy. We prove the van der Waals-London law,…

Mathematical Physics · Physics 2022-11-16 Jean-Marie Barbaroux , Michael Hartig , Dirk Hundertmark , Semjon Vugalter

Atoms deposited on two-dimensional (2D) electronic materials, such as graphene, can exhibit unconventional many-body correlations, not accessible in other settings. All of these are driven by van der Waals forces: between the atoms…

Mesoscale and Nanoscale Physics · Physics 2022-01-13 Adrian Del Maestro , Carlos Wexler , Juan M. Vanegas , Taras Lakoba , Valeri N. Kotov

This is a follow-up of our recently proposed work on pseudopotential calculation (Ref. [21]) of atoms and molecules within DFT framework, using cartesian coordinate grid. Detailed results are presented to demonstrate the usefulness,…

Chemical Physics · Physics 2015-05-18 Amlan K. Roy

Evaluation of internal energy and the inter-atomic or ionic interactions in a crystal lattice usually requires precise calculation of lattice sums. This in the case of small nano-particles (as space-limited domains) presents several…

Mesoscale and Nanoscale Physics · Physics 2014-02-25 Yevgen Bilotsky

We consider the van der Waals energy of an atom near the infinitely thin sphere with finite conductivity which model the fullerene. We put the sphere into spherical cavity inside the infinite dielectric media, then calculate the energy of…

Quantum Physics · Physics 2011-03-30 Nail R. Khusnutdinov

We examine the dipole approximated Pauli-Fierz Hamiltonians of the nonrelativistic QED. We assume that the Coulomb potential of the nuclei together with the Coulomb interaction between the electrons can be approximated by harmonic…

Mathematical Physics · Physics 2020-04-28 Tadahiro Miyao

The Harper equation arising out of a tight-binding model of electrons on a honeycomb lattice subject to a uniform magnetic field perpendicular to the plane is studied. Contrasting and complementary approaches involving von Neumann entropy,…

Strongly Correlated Electrons · Physics 2018-09-26 Geo Jose , Rajesh Malla , Varadharajan Srinivasan , Auditya Sharma , Suhas Gangadharaiah

We study single- and two-atom van der Waals interactions of ground-state atoms which are both polarizable and paramagnetizable in the presence of magneto-electric bodies within the framework of macroscopic quantum electrodynamics. Starting…

Quantum Physics · Physics 2010-01-04 Hassan Safari , Dirk-Gunnar Welsch , Stefan Yoshi Buhmann , Stefan Scheel

The all-order correlation potential method of accurate atomic structure calculations for atoms with one external electron is extended to include one more class of correlation diagrams to all orders. These are the so-called ladder diagrams…

Atomic Physics · Physics 2010-09-20 V. A. Dzuba

We derive solutions of the Schr\"{o}dinger equation for the isotropic van der Waals interaction in a symmetric harmonic trap, with the recent approach [arXiv:2207.09377 (2022)] to handle the multi-scale long-range potential. Asymptotic…

Atomic Physics · Physics 2024-11-11 Ruijie Du

We demonstrate that the model of zero-range potentials can be successfully employed for the description of attached electrons in atomic and molecular anions, for example, negatively charged carbon clusters. To illustrate the capability of…

Atomic and Molecular Clusters · Physics 2023-01-13 Arkadiy S. Baltenkov , Igor Woiciechowski
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