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In this work we introduce the use of TiN/Ti2 N layers as a back contact for lifted-off membranes of anodic Ta3N5 nanotube layers. In photoelectrochemical H2 generation experiments under simulated AM 1.5G light, shift of the onset potential…

Materials Science · Physics 2016-10-14 Lei Wang , Anca Mazare , Imgon Hwang , Patrik Schmuki

We report in situ characterized TiO2 thin-films deposited on optical fiber, having thicknesses in the 20-100nm range, and having enhanced conductivity values of 700S/cm upon interacting with hydrogen. This conductivity was achieved in pure…

Materials Science · Physics 2020-10-01 Jacob L. Poole , Paul R. Ohodnicki , Yang Yu , Jian Liu , Bret Howard , Sittichai Natesakhawat

Titan's organic aerosols are formed in the ionosphere, a layer ionized by solar VUV photons and energetic particles from the magnetosphere of Saturn, forming a natural N2-CH4-H2 plasma. Previous works showed some chemical evolution…

Earth and Planetary Astrophysics · Physics 2023-09-06 Audrey Chatain , Nathalie Carrasco , Ludovic Vettier , Olivier Guaitella

Effective co-catalysts are of key importance for photocatalytic H2 generation from aqueous environments. An attractive co-catalyst candidate are AuPt (metastable) alloys due to the synergistic electronic and chemical interaction of the…

Applied Physics · Physics 2020-05-05 Nhat Truong Nguyen , Selda Ozkan , Ondrej Tomanec , Xuemei Zhou , Radek Zboril , Patrik Schmuki

We report the synthesis of bell-shaped Bi/Bi13S18Br2 metal/semiconductor heterostructures as a photocatalyst based on non-toxic and Earth-abundant elements. Their unique morphology arises from a multi-step growth process, involving 1) the…

Kinetic understanding of hydrogen co-reduction of multinary and multi-phase oxides is of interest for enhancing sustainability of alloy production and transition to a hydrogen-based economy. Benefits include decrease in energy consumption,…

Materials Science · Physics 2026-03-17 Emmanuel Uwayezu , Shaolou Wei , Yujiao Li , Johannes D. Bartl , Dierk Raabe , Alfred Ludwig

Ti-O nanoparticles have been synthesized via hollow cathode sputtering in an Ar-O2 atmosphere using high power pulsing. It is shown that the stoichiometry and the size of the nanoparticles can be varied independently, the former through…

Mesoscale and Nanoscale Physics · Physics 2018-10-09 Rickard Gunnarsson , Ulf Helmersson , Iris Pilch

Metallic monolayered [or two - dimensional (2D)] MoS2 nanosheets show tremendous promise for energy storage and catalysis applications. However, state-of-the-art chemical exfoliation methods require > 48 hours to produce milligrams of…

Laser annealing offers a promising route to back end of the line fabrication of ferroelectric thin film transistors based on hafnium-zirconium oxide (HZO). Due to the wide band gap of this material, previous reports have studied the…

Controlling electronic population through chemical doping is one way to tip the balance between competing phases in materials with strong electronic correlations. Vanadium dioxide exhibits a first-order phase transition at around 338 K…

We have found a remarkably large response of the transition temperature of CaFe2As2 single crystals grown out of excess FeAs to annealing / quenching temperature. Whereas crystals that are annealed at 400 C exhibit a first order phase…

Photocatalytic $H_2$ evolution reactions on pristine TiO$_2$ is characterized by low efficiencies due to trapping and recombination of charge carriers, and due to a sluggish kinetics of electron transfer. Noble metal (mainly Pt, Pd, Au)…

Titanium dioxide is a photocatalytic substance of great practical importance. However, with its bandgap in the ultraviolet (UV) regime, native forms (undoped) of TiO2 generally exhibits poor photocatalytic activities under visible light.…

Chemical Physics · Physics 2013-12-04 Mingzheng Wang , Ka-Kit Yee , Biao Nie , Hua Cheng , Jian Lu , Linbao Luo , Zhengtao Xu , Yang Yang Li

The interplay between magnetism and crystal structures in three CaFe$_{2}$As$_{2}$ samples is studied. For the nonmagnetic quenched crystals, different crystalline domains with varying lattice parameters are found, and three phases…

Substantial enhancement of nonlinear high-order harmonics generation based on Fano-resonant nanostructures has received growing interest due to their promising potential for developing integrated and advanced next-generation nanophotonic…

Optics · Physics 2018-08-01 Arash Ahmadivand , Burak Gerislioglu , Nezih Pala

Nonlinear optics at the nanoscale has emerged as a sought-after platform for sensing and imaging applications. The development of these materials is having an impact on fields that include advanced information technology, signal processing…

Optics · Physics 2024-12-24 Rana Faryad Ali , Byron D. Gates

Self-standing TiO$_2$ nanotube layers in the form of membranes are fabricated by self-organizing anodization of Ti metal and a potential shock technique. The membranes were then decorated by sputtering different Pt amounts i) only at the…

Applied Physics · Physics 2020-06-02 Gihoon Cha , Marco Altomare , Nhat Truong Nguyen , Nicola Taccardi , Kiyoung Lee , Patrik Schmuki

High-pressure torsion (HPT) can facilitate phase transformations in titanium dioxide (TiO2) and stabilize its high-pressure columbite phase, as an active photocatalyst, by shear straining under high pressure. This study aims to understand…

Materials Science · Physics 2024-06-03 Jacqueline Hidalgo-Jimenez , Taner Akbay , Yuji Ikeda , Tatsumi Ishihara , Kaveh Edalati

Recent rapid progress in efficiencies for solar water splitting by photoelectrochemical devices has enhanced its prospects to enable storable renewable energy. Efficient solar fuel generators all use tandem photoelectrode structures, and…

Tailoring the magnetic properties of iron oxide nanosystems is essential to expand their biomedical applications. In this study, the 34 nm iron oxide nanocubes with two phases consisting of Fe3O4 and alpha-Fe2O3 were annealed for 2 hours in…

Materials Science · Physics 2024-02-01 Supun B. Attanayake , Amit Chanda , Raja Das , Manh-Huong Phan , Hariharan Srikanth
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