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Related papers: Magneli-Phases in Anatase Strongly Promote Co-Cata…

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The photocatalytic production of hydrogen peroxide (H$_2$O$_2$) from water is a promising strategy for solar-to-chemical energy conversion. Herein, we investigate the effect of metal-free heteroatom doping (B, O, P, and S) on the…

Innovative synthetic approaches can yield new phases containing novel structural and magnetic motifs. In this work, we show the synthesis and magnetic characterization of three new and one previously reported layered phase in the…

Strongly Correlated Electrons · Physics 2024-03-28 Allana G. Iwanicki , Brandon Wilfong , Eli Zoghlin , Wyatt Bunstine , Maxime A. Siegler , Tyrel M. McQueen

Thick anatase films were fabricated on graphite substrates using a method of anodic aqueous electrophoretic-deposition using oxalic acid as a dispersant. Thick films were subsequently fired in air and in nitrogen at a range of temperatures.…

Materials Science · Physics 2013-03-13 D. A. H. Hanaor , M. Michelazzi , J. Chenu , C. Leonelli , C. C. Sorrell

We investigate the complex relationship between the growth conditions and the structural and transport properties of $\mathrm{Ti_xO_y}$ thin films grown by molecular beam epitaxy. Transport properties ranging from metallicity to…

The electronic properties of quasi-one-dimensional anatase TiO2 nanostructures, in the form of thin nanowires having (101) and (001) facets, have been systematically investigated using the standard, hybrid density functional and…

Mesoscale and Nanoscale Physics · Physics 2014-07-08 Hatice Unal , Oguz Gulseren , Sinasi Ellialtioglu , Ersen Mete

Compact solid discharge products enable energy storage devices with high gravimetric and volumetric energy densities, but solid deposits on active surfaces can disturb charge transport and induce mechanical stress. In this Letter we develop…

Chemical Physics · Physics 2013-07-26 B. Horstmann , B. Gallant , R. Mitchell , W. G. Bessler , Y. Shao-Horn , M. Z. Bazant

Au and Pt do not form homogeneous bulk alloys as they are thermodynamically not miscible. However, we show that anodic TiO$_2$ nanotubes (NTs) can in-situ be uniformly decorated with homogeneous AuPt alloy nanoparticles (NPs) during their…

Photocatalytic nitrogen fixation is an important pathway for carbon neutralization and sustainable development. Inspired by nitrogenase, the participation of molybdenum can effectively activate nitrogen. A novel Ti/Mo composites…

Chemistry in Titan's N2-CH4 atmosphere produces complex organic aerosols. The chemical processes and the resulting organic compounds are still far from understood, although extensive observations, laboratory, and theoretical simulations…

Earth and Planetary Astrophysics · Physics 2022-09-26 Chao He , Joseph Serigano , Sarah M. Horst , Michael Radke , Joshua A. Sebree

Titanium dioxide (TiO$_2$) thin films are commonly used as photocatalytic materials. Here, we enhance the photocatalytic activity of devices based on TiO$_2$ by combining nanostructured glass substrates with metallic plasmonic…

Recently, the development of efficient and non-noble metal electrocatalysts with excellent durability for the hydrogen evolution reaction (HER) has attracted increasing attention. The exotic and robust metallic surface states of topological…

Chemical Physics · Physics 2019-09-27 Qing Qu , Bin Liu , Jing Liang , Ding Pan , Iam Keong Sou

The inherent existence of multi phases in iron oxide nanostructures highlights the significance of them being investigated deliberately to understand and possibly control the phases. Here, the effects of annealing at 250 0C with a variable…

The magnetic behavior of $Fe_{3-x}O_4$ nanoparticles synthesized either by high-temperature decomposition of an organic iron precursor or low-temperature co-precipitation in aqueous conditions, is compared. Transmission electron microscopy,…

The local chemistry, structure, and magnetism of (Ga,Fe)N nanocomposites grown by metal organic vapor phase epitaxy is studied by high resolution synchrotron x-ray diffraction and absorption, transmission electron microscopy, and…

Magnesium dihydride ($\mgh$) stores 7.7 weight % hydrogen, but it suffers from a high thermodynamic stability and slow (de)hydrogenation kinetics. Alloying Mg with lightweight transition metals (TM = Sc, Ti, V, Cr) aims at improving the…

Materials Science · Physics 2009-02-04 Suleyman Er , Dhirendra Tiwari , Gilles A. de Wijs , Geert Brocks

To compare the metal-insulator transitions (MITs) of VO2 and V2O3 we analyze the relations between the structural and electronic properties of the vanadium Magneli phases. These materials set up the homologous series VnO(2n-1) (3 <= n <= 9)…

Strongly Correlated Electrons · Physics 2009-11-10 Udo Schwingenschloegl , Volker Eyert

Flexoelectricity is universal in all dielectrics, effective at high temperatures, and a promising transduction technique for nanoelectromechanical systems (NEMS). However, as flexoelectricity is still in its early stages, many aspects…

Materials Science · Physics 2024-10-03 Daniel Moreno-Garcia , Luis Guillermo Villanueva

Atomically flat, epitaxial, and stoichiometric thin films of the electronically phase separated compound (La$_{0.5}$Pr$_{0.5}$)$_{0.67}$Ca$_{0.33}$MnO$_{3}$ were grown on as-received and treated NdGaO$_{3}$ substrates by fine tuning of…

Materials Science · Physics 2011-09-16 Hyoungjeen Jeen , Rafiya Javed , Amlan Biswas

The least is the best. We introduce a technique to strongly reduce Pt use for photocatalytic hydrogen generation from TiO2 nanotubes. By site-selectively depositing thin layers of Pt only at the mouth of the nanotubes and by a subsequent…

Chemical Physics · Physics 2016-10-18 Nhat Truong Nguyen , Marco Altomare , JeongEun Yoo , Nicola Taccardi , Patrik Schmuki

X-ray diffraction, transmission electron microscopy, and magnetization measurements are employed to study the structural and magnetic properties of Mn-rich (Mn,Ga)As nanocrystals embedded in GaAs. These nanocomposites are obtained by…

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