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A simple and computationally efficient scheme to calculate approximate imaginary-frequency dependent polarizability, hence asymptotic van der Waals coefficient, within density functional theory is proposed. The dynamical dipolar…

Materials Science · Physics 2009-04-20 Huy-Viet Nguyen , Stefano de Gironcoli

The Lifshitz theory of the van der Waals force is extended for the case of an atom (molecule) interacting with a plane surface of an uniaxial crystal or with a long solid cylinder or cylindrical shell made of isotropic material or uniaxial…

Quantum Physics · Physics 2009-11-11 E. V. Blagov , G. L. Klimchitskaya , V. M. Mostepanenko

We consider the zero-temperature van der Waals interaction between two molecules, each of which has a zero or near-zero electronic gap between a groundstate and the first excited state, using a toy model molecule ( equilateral H3) as an…

Other Condensed Matter · Physics 2016-12-21 John F. Dobson , Andreas Savin , Janos G. Angyan , Ru-Fen Liu

We study the shift of rotational levels of a diatomic polar molecule due to its van der Waals (vdW) interaction with a gently curved dielectric surface at temperature $T$, and submicron separations. The molecule is assumed to be in its…

Quantum Physics · Physics 2016-08-18 Giuseppe Bimonte , Thorsten Emig , Robert L. Jaffe , Mehran Kardar

We consider potential-based interactions between beams (or fibers) and shells (or membranes) using a coarse-grained approach with focus on van der Waals attraction and steric repulsion. The involved 6D integral over volumes of a beam and a…

Numerical Analysis · Mathematics 2026-03-02 Aleksandar Borković , Michael H. Gfrerer , Roger A. Sauer

We calculate the non-retarded dispersion force exerted on an electrically polarizable quantum particle by a perfectly conducting toroid, which is one of the most common objects exhibiting a non-trivial topology. We employ a convenient…

Quantum Physics · Physics 2021-08-26 P. P. Abrantes , Yuri França , Reinaldo de Melo e Souza , F. S. S. da Rosa , C. Farina

Van der Waals forces as interactions between neutral and polarisable particles act at small distances between two objects. Their theoretical origin lies in the electromagnetic interaction between induced dipole moments caused by the vacuum…

Chemical Physics · Physics 2019-06-05 Johannes Fiedler , Clas Persson , Mathias Boström , Stefan Y. Buhmann

We verify that the van der Waals interaction and hence all dispersion interactions for the hydrogen molecule given by: W"= -{A/R^6}-{B/R^8}-{C/R^10}- ..., in which R is the internuclear separation, are exactly soluble. The constants…

Quantum Physics · Physics 2011-08-05 T. C. Choy

We consider a multiatomic system where the nuclei are assumed to be point charges at fixed positions. Particles interact via Coulomb potential and electrons have pseudo-relativistic kinetic energy. We prove the van der Waals-London law,…

Mathematical Physics · Physics 2022-11-16 Jean-Marie Barbaroux , Michael Hartig , Dirk Hundertmark , Semjon Vugalter

We study single- and two-atom van der Waals interactions of ground-state atoms which are both polarizable and paramagnetizable in the presence of magneto-electric bodies within the framework of macroscopic quantum electrodynamics. Starting…

Quantum Physics · Physics 2010-01-04 Hassan Safari , Dirk-Gunnar Welsch , Stefan Yoshi Buhmann , Stefan Scheel

Non-relativistic quantum particles bounded to a curve in R^2 by attractive contact $\delta$-interaction are considered. The interval between the energy of the transversal bound state and zero is shown to belong to the absolutely continuous…

Mathematical Physics · Physics 2020-08-13 J. Dittrich

We develop a formalism suitable for studying Maxwell's equations in the presence of a medium that is axially symmetric, in particular with respect to Casimir-Polder interaction energies. As an application, we derive the Casimir-Polder…

Classical Physics · Physics 2017-12-04 K. V. Shajesh , Prachi Parashar , Iver Brevik

The ground state and excited state resonance dipole-dipole interaction energy between two elongated conducting molecules are explored. We review the current status for ground state interactions. This interaction is found to be of a much…

Chemical Physics · Physics 2025-11-03 Subhojit Pal , Iver Brevik , Mathias Boström

Using a recently obtained (general) formula for the interaction energy between an excited and a ground-state atom (Sherkunov Y 2007 Phys. Rev. A 75 012705), we consider the interaction energy between two such atoms near the interface…

Quantum Physics · Physics 2008-04-10 Marin-Slobodan Tomas

We consider the van der Waals interaction between two ground-state atoms embedded in adjacent semi-infinite magnetodielectric media, with emphasis on medium effects on it. We demonstrate that, in this case, at small atom-atom distances the…

Quantum Physics · Physics 2009-11-13 M. S. Tomas

The paper deals with the analytical integration of interaction potentials between specific geometries such as disks, cylinders, rectangles, and rectangular prisms. Interaction potentials are modeled as inverse-power laws with respect to the…

Computational Physics · Physics 2024-12-02 Aleksandar Borković , Michael H. Gferer , Roger A. Sauer

This article focuses on isomerizations of molecules, i.e. chemical reactions during which a molecule is transformed into another one with the same atoms in a different spatial configuration. We consider the special case in which the system…

Mathematical Physics · Physics 2023-03-15 Ioannis Anapolitanos , Marco Olivieri , Sylvain Zalczer

We extend a method (E. Canc\`es and L.R. Scott, SIAM J. Math. Anal., 50, 2018, 381--410) to compute more terms in the asymptotic expansion of the van der Waals attraction between two hydrogen atoms. These terms are obtained by solving a set…

Mathematical Physics · Physics 2020-07-09 Éric Cancès , Rafaël Coyaud , L. Ridgway Scott

Nanostructures can be bound together at equilibrium by the van der Waals (vdW) effect, a small but ubiquitous many-body attraction that presents challenges to density functional theory. How does the binding energy depend upon the size or…

Chemical Physics · Physics 2018-03-14 Jianmin Tao , John P. Perdew , Hong Tang , Chandra Shahi

We study the dispersion interaction of the van der Waals and Casimir-Polder (vdW-CP) type between a neutral atom and the surface of a metal by allowing for nonlocal electrodynamics, i.e. electron diffusion. We consider two models: (i) bulk…

Atomic Physics · Physics 2014-07-23 Elad Eizner , Baruch Horovitz , Carsten Henkel