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Here we report two-dimensional (2D) single-crystalline holey-graphyne (HGY) created an interfacial two-solvent system through a Castro-Stephens coupling reaction from 1,3,5-tribromo-2,4,6-triethynylbenzene. HGY is a new type of 2D carbon…

Materials Science · Physics 2019-07-09 Xinghui Liu1 , Soo Min Cho , Shiru Lin , Eunbhin Yun , Eun Hee Baek , Zhongfang Chen , Do Hyun Ryu , Hyoyoung Lee

Using first-principles calculations, we show that the formation of carbohydrate directly from carbon and water is energetically favored when graphene membrane is subjected to aqueous environment with difference in chemical potential across…

Mesoscale and Nanoscale Physics · Physics 2010-03-17 Wei L. Wang , Efthimios Kaxiras

The use of a novel three-dimensional graphene structure allows circumventing the limitations of the two-dimensional nature of graphene and its application in hydrogen absorption. Here we investigate hydrogen-bonding on monolayer graphene…

Man-made artificial graphene has attracted significant attention in the past few years due to the possibilities to construct designer Dirac fermions with unexpected topological properties and applications in nanoelectronics. Here we use a…

Materials Science · Physics 2014-12-10 Matti Ropo , Sami Paavilainen , Jaakko Akola , Esa Räsänen

Reverse electrodialysis is a promising method to harvest the osmotic energy stored between seawater and freshwater, but it has been a long-standing challenge to fabricate permselective membranes with the power density surpassing the…

Applied Physics · Physics 2019-12-09 Zhenkun Zhang , Wenhao Shen , Lingxin Lin , Mao Wang , Ning Li , Zhifeng Zheng , Feng Liu , Liuxuan Cao

Graphene-based 2D heterostructures exhibit excellent mechanical and electrical properties, which are expected to exhibit better performances than graphene for nanoelectromechanical pressure sensors. Here, we built the pressure sensor models…

Mesoscale and Nanoscale Physics · Physics 2024-10-14 Quan Liu , Chang He , Jie Ding , Wendong Zhang , Xuge Fan

Graphdiyne and graphyne are carbon-based two-dimensional (2D) porous atomic lattices, with outstanding physics and excellent application prospects for advanced technologies, like nanoelectronics and energy storage systems. During the last…

Computational Physics · Physics 2019-02-07 B. Mortazavi , M. Shahrokhi , M. E. Madjet , T. Hussain , X. Zhuang , T. Rabczuk

CO$_2$ capture using carbon-based materials, particularly graphene and graphene-like materials, is a promising strategy to deal with CO$_2$ emissions. However, significant gaps remain in our understanding of the molecular-level interaction…

Ubiquitous graphene is a stricly 2D material representing an ideal adsorbing platform due to its large specific surface area as well as its mechanical strength and resistance to both thermal and chemical stresses. However, graphene as a…

Materials Science · Physics 2016-10-06 Massimiliano Bartolomei , Giacomo Giorgi

In this paper is calculated and analyzed the dielectric behavior of carbon dioxide - methanol mixture and evaluate how the correct reproduction of the electrical properties of this molecules influences in the mixture of these two…

Soft Condensed Matter · Physics 2022-03-11 Raúl Fuentes-Azcatl , Hector Dominguez

Energy barrier of oxygen molecule dissociation on carbon nanotube or graphene with different types of nitrogen doping is investigated using density functional theory. The results show that the energy barriers can be reduced efficiently by…

Materials Science · Physics 2015-06-03 Shuang Ni , Zhenyu Li , Jinlong Yang

Most recently, boron-graphdiyne, a {\pi}-conjugated two-dimensional (2D) structure made from merely sp carbon skeleton connected with boron atoms was successfully experimentally realized through a bottom-to-up synthetic strategy. Motivated…

Computational Physics · Physics 2018-05-14 Bohayra Mortazavi , Masoud Shahrokhi , Xiaoying Zhuang , Timon Rabczuk

Microscopic-level understanding of the separation mechanism for two-dimensional (2D) membranes is an active area of research due to potential implications of this class of membranes for various technological processes. Helium (He)…

Mesoscale and Nanoscale Physics · Physics 2021-09-15 Somnath Bhowmick , Marta I. Hernández , José Campos-Martínez , Yury V. Suleimanov

Graphene-based membranes have been investigated as promising candidates for water filtration and gas separation applications. Experimental evidences have shown that graphene oxide can be impermeable to liquids, vapors and gases, while…

Materials Science · Physics 2017-02-02 Daiane D. Borges , Cristiano F. Woellner , Pedro A. S. Autreto , Douglas S. Galvao

The penetration of atomic hydrogen through defect-free graphene was generally predicted to have a barrier of at least several eV, which is much higher than the 1 eV barrier measured for hydrogen-gas permeation through pristine graphene…

Materials Science · Physics 2023-07-26 Wenqi Xiong , Weiqing Zhou , Pengzhan Sun , Shengjun Yuan

Ultrahigh water permeance, together with a high rejection rate through nanofiltration and separation membranes1,2, is crucial but still challenging for multivalent ion sieving in water treatment processes of desalination, separation, and…

Adsorption is one important way applied to water decontamination, where carbon is commonly used as highly effective absorbent. Carbon of different morphologies and structures normally demonstrate distinct capabilities to adsorption-typed…

Materials Science · Physics 2017-05-02 Sun Ling

It is commonly believed that it is unfavourable for adsorbed H atoms on carbonaceous surfaces to form H$_2$ without the help of incident H atoms. Using ring-polymer instanton theory to describe multidimensional tunnelling effects, combined…

Chemical Physics · Physics 2022-04-05 Erxun Han , Wei Fang , Michail Stamatakis , Jeremy O. Richardson , Ji Chen

The advent of graphene created a revolution in materials science. Because of this there is a renewed interest in other carbon-based structures. Graphene is the ultimate (just one atom thick) membrane. It has been proposed that graphene can…

Mesoscale and Nanoscale Physics · Physics 2017-01-24 Vinicius Splugues , Pedro Alves da Silva Autreto , Douglas S. Galvao

The possibility to control the commensurability and distance between graphene layers separated by a dielectric spacer is considered by the example of a heterostructure consisting of double-layer graphene separated by atomic layers of argon.…

Mesoscale and Nanoscale Physics · Physics 2013-09-24 Andrey M. Popov , Irina V. Lebedeva , Andrey A. Knizhnik , Yurii E. Lozovik , Boris V. Potapkin