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The dynamics of one species chemical kinetics is studied. Chemical reactions are modelled by means of continuous time Markov processes whose probability distribution obeys a suitable master equation. A large deviation theory is formally…

Statistical Mechanics · Physics 2015-03-14 Carlos Escudero , Andres M. Rivera , Pedro J. Torres

To study the fluctuations and dynamics in chemical reaction processes, stochastic differential equations based on the rate equation involving chemical concentrations are often adopted. When the number of molecules is very small, however,…

Chemical Physics · Physics 2007-05-23 Yuichi Togashi , Kunihiko Kaneko

Statistical measures of chaos have long been used in the study of chaotic dynamics in the framework of the interacting boson model. The use of large number of bosons renders additional studies of chaos possible, that can provide a direct…

Nuclear Theory · Physics 2015-11-23 S. Karampagia , Dennis Bonatsos , R. F. Casten

Autocatalytic reaction system with a small number of molecules is studied numerically by stochastic particle simulations. A novel state due to fluctuation and discreteness in molecular numbers is found, characterized as extinction of…

Biological Physics · Physics 2007-05-23 Yuichi Togashi , Kunihiko Kaneko

Dynamical systems theory provides powerful methods to extract effective macroscopic dynamics from complex systems with slow modes and fast modes. Here we derive and theoretically support a macroscopic, spatially discrete, model for a class…

Analysis of PDEs · Mathematics 2010-03-12 Wei Wang , A. J. Roberts

A new generic dynamical phenomenon of pseudochaos and its relevance to the statistical physics both modern as well as traditional one are considered and explained in some detail. The pseudochaos is defined as a statistical behavior of the…

chao-dyn · Physics 2016-08-31 Boris Chirikov

It has recently been shown that structural conditions on the reaction network, rather than a 'fine-tuning' of system parameters, often suffice to impart 'absolute concentration robustness' on a wide class of biologically relevant,…

Probability · Mathematics 2014-01-20 David F. Anderson , German Enciso , Matthew Johnston

Chemical, physical and ecological systems passing through a saddle-node bifurcation will, momentarily, find themselves balanced at a semi-stable steady state. If perturbed by noise, such systems will escape from the zero-steady state, with…

Statistical Mechanics · Physics 2020-01-08 Alastair Jamieson-Lane , Eric N. Cytrynbaum

Multistability of mesoscopic, driven biochemical reaction systems has implications to a wide range of cellular processes. Using several simple models, we show that one class of bistable chemical systems has a deterministic counterpart in…

Chemical Physics · Physics 2010-11-12 Yunxin Zhang , Hao Ge , Hong Qian

Heterogeneity in gene expression across isogenic cell populations can give rise to phenotypic diversity, even when cells are in homogenous environments. This diversity arises from the discrete, stochastic nature of biochemical reactions,…

Quantitative Methods · Quantitative Biology 2017-08-31 Zachary Fox , Brian Munsky

In this paper, we introduce a novel method to identify transitions from steady states to chaos in stochastic models, specifically focusing on the logistic and Ricker equations by leveraging the gamma distribution to describe the underlying…

Probability · Mathematics 2025-06-13 Haiyan Wang , Ying Wang

To study the dynamics of chemical processes, we often adopt rate equations to observe the change in chemical concentrations. However, when the number of the molecules is small, the fluctuations cannot be neglected. We often study the…

Chemical Physics · Physics 2007-05-23 Yuichi Togashi , Kunihiko Kaneko

An approach is suggested for treating multiscale fluctuations in macromolecular systems. The emphasis is on the statistical properties of such fluctuations. The approach is illustrated by a macromolecular system with mesoscopic fluctuations…

Chemical Physics · Physics 2012-08-07 V. I. Yukalov , E. P. Yukalova

We propose a method to study the transition to chaos in isolated quantum systems of interacting particles. It is based on the concept of delocalization of eigenstates in the energy shell, controlled by the Gaussian form of the strength…

Quantum Physics · Physics 2012-05-15 L. F. Santos , F. Borgonovi , F. M. Izrailev

A fundamental issue in nonlinear dynamics and statistical physics is how to distinguish chaotic from stochastic fluctuations in short experimental recordings. This dilemma underlies many complex systems models from stochastic gene…

Chaotic Dynamics · Physics 2010-04-12 Chi-Sang Poon , Cheng Li , Guo-Qiang Wu

We study a fractional reaction-diffusion system with two types of variables: activator and inhibitor. The interactions between components are modeled by cubical nonlinearity. Linearization of the system around the homogeneous state provides…

Pattern Formation and Solitons · Physics 2007-05-23 V. Gafiychuk , B. Datsko , V. Meleshko

We investigate the connections between microscopic chaos, defined on a dynamical level and arising from collisions between molecules, and diffusion, characterized by a mean square displacement proportional to the time. We use a number of…

Chaotic Dynamics · Physics 2007-05-23 C. P. Dettmann , E. G. D. Cohen

Stable chaos is a generalization of the chaotic behaviour exhibited by cellular automata to continuous-variable systems and it owes its name to an underlying irregular and yet linearly stable dynamics. In this review we discuss analogies…

Chaotic Dynamics · Physics 2010-10-19 Antonio Politi , Alessandro Torcini

A molecule traveling in a realistic propagation environment can experience stochastic interactions with other molecules and the environment boundary. The statistical behavior of some isolated phenomena, such as dilute unbounded molecular…

Chemical Physics · Physics 2015-05-20 Adam Noel , Karen C. Cheung , Robert Schober

When very small particles are suspended in a fluid in motion, they tend to follow the flow. How such tracer particles are mixed, transported, and dispersed by turbulent flow has been successfully described by statistical models. Heavy…

Fluid Dynamics · Physics 2023-12-21 J. Bec , K. Gustavsson , B. Mehlig
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