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We present spectra of the 3.3 $\mu$m and 11.2 $\mu$m PAH features of a large number of (extra-) galactic sources, obtained with ISO-SWS. Clear variations are present in the profiles of these features. The sources are classified…

Aims. We aim to elucidate the spectral changes in the 3 micron region that result from chemical changes in the molecular periphery of polycyclic aromatic hydrocarbons (PAHs) with extra hydrogens (H-PAHs) and methyl groups (Me-PAHs).…

Astrophysics of Galaxies · Physics 2018-04-04 E. Maltseva , C. J. Mackie , A. Candian , A. Petrignani , X. Huang , T. J. Lee , A. G. G. M. Tielens , J. Oomens , WJ Buma

Using the AKARI, Wide-field Infrared Survey Explorer (WISE), Infrared Astronomical Satellite (IRAS), Sloan Digital Sky Survey (SDSS) and Hubble Space Telescope (HST) data, we investigated the relation of polycyclic aromatic hydrocarbon…

We use archival COBE/DIRBE data to construct a map of polycyclic aromatic hydrocarbon (PAH) emission in the $\lambda$-Orionis region. The presence of the 3.3 $\mu$m PAH feature within the DIRBE 3.5 $\mu$m band and the corresponding lack of…

Astrophysics of Galaxies · Physics 2022-11-30 David T. Chuss , Brandon S. Hensley , Alan J. Kogut , Jordan A. Guerra , Hayley C. Nofi , Javad Siah

We examine the dependence of polycyclic aromatic hydrocarbon (PAH) band intensity ratios as a function of the average number of carbon atoms and assess their effectiveness as tracers for PAH size, utilising the data, models, and tools…

Astrophysics of Galaxies · Physics 2023-07-19 A. Maragkoudakis , E. Peeters , A. Ricca , C. Boersma

Polycyclic Aromatic Hydrocarbons (PAHs) are organic molecules which comprise the smallest particles of dust in the interstellar medium (ISM). Due to their broad/complex emission profiles, obtaining kinematics is a challenge with traditional…

Astrophysics of Galaxies · Physics 2024-05-24 Fergus R. Donnan , Dimitra Rigopoulou , Ismael García-Bernete

We present a comprehensive mid-infrared spectroscopic survey of 124 Herbig Ae/Be stars using newly processed Spitzer/IRS spectra from the newly released CASSISjuice database. Based on prominent dust and molecular signatures (polycyclic…

Solar and Stellar Astrophysics · Physics 2025-06-18 R. Arun , Blesson Mathew , B. Shridharan , K. Ujjwal , Akhil Krishna R , G. Maheswar , Sreeja S. Kartha

The formation of polycyclic aromatic hydrocarbons (PAHs) and their methyl derivatives occurs mainly in the dust shells of asymptotic giant branch (AGB) stars. The bands at 3.3 and 3.4 $\mu$m, observed in infrared emission spectra of several…

Solar and Stellar Astrophysics · Physics 2016-04-20 T. Monfredini , F. Fantuzzi , M. A. C. Nascimento , W. Wolff , H. M. Boechat-Roberty

We report on an experimental and theoretical investigation of the importance of anharmonicity in the 3 micron CH stretching region of Polycyclic Aromatic Hydrocarbon (PAH) molecules. We present mass-resolved, high-resolution spectra of the…

Polycyclic aromatic hydrocarbons (PAHs) are key dust components in galaxies and play a fundamental role in the physics of the interstellar medium (ISM), yet their response to AGN feedback remains debated. We present a spatially resolved…

It is very important to identify carrier molecules of astronomical interstellar infrared spectrum (IR) to understand chemical evolution step of polycyclic aromatic hydrocarbon (PAH) in the universe. In our previous study, it was suggested…

Astrophysics of Galaxies · Physics 2018-01-22 Norio Ota

Novel low-band-gap copolymer oligomers are proposed on the basis of density functional theory (DFT) quantum chemical calculations of photophysical properties. These molecules have an electron donor-accepter (D-A) architecture involving…

Chemical Physics · Physics 2017-08-18 Tarek Mestiri , Ala Aldin M. H. M. Darghouth , Mark E. Casida , Kamel Alimi

Infrared spectra of carbon-rich objects which have evolved off the asymptotic giant branch reveal a range of dust properties, including fullerenes, polycyclic aromatic hydrocarbons (PAHs), aliphatic hydrocarbons, and several unidentified…

We extend the prediction of vibrational spectra to large sized polycyclic aromatic hydrocarbon (PAH) molecules comprising up to \sim 1500 carbon atoms by evaluating the efficiency of several computational chemistry methodologies. We employ…

Polycyclic aromatic hydrocarbon (PAH) molecules have long been suggested to be present in the interstellar medium (ISM). Nevertheless, despite their expected ubiquity and sustained searching efforts, identifying specific interstellar PAH…

Astrophysics of Galaxies · Physics 2024-03-12 Kaijun Li , Aigen Li , Xuejuan Yang , Taotao Fang

We have used the Infrared Spectrograph (IRS) on the Spitzer Space Telescope to obtain spectra of HD 100764, an apparently single carbon star with a circumstellar disk. The spectrum shows emission features from polycyclic aromatic…

Mid-infrared (IR) observations of polycyclic aromatic hydrocarbons (PAHs) and molecular hydrogen emission are a potentially powerful tool to derive physical properties of dense environments irradiated by intense UV fields. We present new,…

Astrophysics of Galaxies · Physics 2014-11-20 O. Berne , A. Fuente , J. R. Goicoechea , P. Pilleri , M. Gonzalez-Garcia , C. Joblin

Planet-forming disks of gas and dust around young stars contain polycyclic aromatic hydrocarbons (PAHs). We aim to characterize how the charge state of PAHs can be used as a probe of flows of gas through protoplanetary gaps. In this…

Solar and Stellar Astrophysics · Physics 2015-06-18 K. M. Maaskant , M. Min , L. B. F. M. Waters , A. G. G. M. Tielens

Interstellar infrared observation shows featured spectrum due to polycyclic aromatic hydrocarbon (PAH)at wavelength 3.3,6.2,7.6,7.8,8.6,and 11.3 micrometer,which are ubiquitously observed in many astronomical dust clouds and galaxies. Our…

Astrophysics of Galaxies · Physics 2018-08-06 Norio Ota