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We theoretically study the electrokinetic transport properties of nano-fluidic devices under the influence of a pressure, voltage or salinity gradient. On a microscopic level the behaviour of the device is quantified by the Onsager matrix…

Soft Condensed Matter · Physics 2019-12-02 B. L. Werkhoven , R. van Roij

We investigate the complexation of a highly charged sphere with a long flexible polyelectrolyte, \textit{both negatively charged} in salt free environment. Electroneutrality is insured by the presence of divalent counterions. Using…

Soft Condensed Matter · Physics 2007-05-23 Rene Messina , Christian Holm , Kurt Kremer

Despite the ubiquity of aqueous electrolytes, the effect of salt on water organization remains controversial. We introduce a nonlocal and nonlinear field theory for the nanoscale polarization of ions and water and derive the electrolyte…

The electrolyte (comprising of solute ions and solvents) flow-through the porous media is frequently encountered in nature or in many engineering applications, such as the electrochemical systems, manufacturing of composites, oil…

Fluid Dynamics · Physics 2013-09-12 Chengjun Xu , Chin-Tsau Hsu

It is shown that the conductance of a weakly disordered Luttinger-liquid quantum wire connected to non-interacting leads is affected by electron-electron interactions in the wire. This is in contrast to the case of a perfect wire the…

Condensed Matter · Physics 2009-10-28 Dmitrii L. Maslov

The electrical conductivity of disordered insulator-conductor composites have been studied for more than thirty years. In spite of this some properties of dc bulk conductivity of composites still remain incompletely understood. We present a…

Atomic and Molecular Clusters · Physics 2009-03-23 M. Cattani , M. C. Salvadori , M. Cattani

We present a novel theoretical framework for understanding the expressive power of normalizing flows. Despite their prevalence in scientific applications, a comprehensive understanding of flows remains elusive due to their restricted…

Machine Learning · Computer Science 2025-01-30 Felix Draxler , Stefan Wahl , Christoph Schnörr , Ullrich Köthe

The complexation of a polyelectrolyte with an oppositely charged spherical macroion is studied for both salt free and salty solutions. When a polyelectrolyte winds around the macroion, its turns repel each other and form an almost…

Soft Condensed Matter · Physics 2009-10-31 T. T. Nguyen , B. I. Shklovskii

Many-body systems, such as electrons flowing in a superconductor, are among the most difficult theoretical problems to study. A new family of exactly solvable models may offer some answers.

Superconductivity · Physics 2015-06-24 Michel Heritier

The conductivity of ionic solutions is arguably their most important trait, being widely used in electrochemical, biochemical, and environmental applications. The Debye-H\"uckel-Onsager theory successfully predicts the conductivity at very…

Soft Condensed Matter · Physics 2023-01-03 Yael Avni , Ram M. Adar , David Andelman , Henri Orland

Understanding and controlling polyelectrolyte adsorption onto carbon nanotubes is a fundamen- tal challenge in nanotechology. Polyelectrolytes have been shown to stabilise nanotube suspensions through adsorbing onto the nanotube surface,…

Soft Condensed Matter · Physics 2018-01-18 Alpha A. Lee , Sarah V. Kostinski , Michael P. Brenner

Organic electrochemical transistors are extensively studied for applications ranging from bioelectronics to analog and neuromorphic computing. Despite significant advances, the fundamental interactions between the polymer semiconductor…

A general organizing principle is proposed that can be used to derive the equations of motion describing the near-equilibrium dynamics of causal and thermodynamically stable relativistic systems. The latter are found to display some new…

Nuclear Theory · Physics 2024-06-04 Lorenzo Gavassino , Marcelo M. Disconzi , Jorge Noronha

The derivative discontinuity is a key concept in electronic structure theory in general and density functional theory in particular. The electronic energy of a quantum system exhibits derivative discontinuities with respect to different…

Chemical Physics · Physics 2017-09-13 Paula Mori-Sánchez , Aron J. Cohen

We examine the interactions between polyelectrolytes (PEs) and uncharged substrates at conditions corresponding to a dielectric discontinuity between the aqueous solution and the substrate. To this end, we vary the relevant system…

Soft Condensed Matter · Physics 2024-12-03 Hossein Vahid , Alberto Scacchi , Maria Sammalkorpi , Tapio Ala-Nissila

Electrostatic correlations between ions dissolved in water are known to impact their transport properties in numerous ways, from conductivity to ion selectivity. The effects of these correlations on the solvent itself remain, however, much…

Soft Condensed Matter · Physics 2024-01-31 Paul Robin

Describing analytically the transport properties of electrolytes, such as their conductivity or the self-diffusion of the ions, has been a central challenge of chemical physics for almost a century. In recent years, this question has…

Soft Condensed Matter · Physics 2023-09-21 Olivier Bernard , Marie Jardat , Benjamin Rotenberg , Pierre Illien

Inelastic lifetime of an electron quasiparticle in an electron liquid due to electron-electron interaction evaluated in previous work is calculated in an alternative way. Both the contributions of the "direct" and "exchange" processes are…

Strongly Correlated Electrons · Physics 2009-11-11 Zhixin Qian

Percolation theory and the associated conductance networks have provided deep insights into the flow and transport properties of a vast number of heterogeneous materials and media. In practically all cases, however, the conductance of the…

Statistical Mechanics · Physics 2023-07-27 Carl Fredrik Berg , Muhammad Sahimi

We have investigated the charge carrier transport in organic molecular semiconductors. It has been found that mobility is a function of electric field and temperature due to hopping conduction. Several theoretical models for charge…

Materials Science · Physics 2007-05-23 Ajit Kumar Mahapatro , Subhasis Ghosh
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