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It is proven that the sum rules for X-ray magnetic dichroism (XMCD) spectra that are used to separate spin and orbital contributions to the magnetic moment are formally correct for an arbitrary strength of electron-electron interactions.…

Strongly Correlated Electrons · Physics 2007-05-23 V. Yu. Irkhin , M. I. Katsnelson

X-ray magnetic circular dichroism (XMCD) and X-ray magnetic linear dichroism (XMLD) are powerful spectroscopic techniques for probing magnetic properties in solids. In this study, we revisit the XMCD and XMLD sum rules within a complete…

Materials Science · Physics 2025-07-03 Y. Yamasaki , Y. Ishii , N. Sasabe

We argue that the magnetic circular dichroism (MCD) of the hard x-ray Raman scattering (XRS) could be used as an element selective probe of local spin polarization. The magnitude of the XRS-MCD signal is directly proportional to the local…

Materials Science · Physics 2019-10-01 Manabu Takahashi , Nozomu Hiraoka

We consider the magnetic circular dichroism spectrum of a crystal with broken time-reversal symmetry in the electric-dipole approximation. Using the Kubo-Greenwood formula for the absorptive part of the antisymmetric optical conductivity,…

Materials Science · Physics 2009-11-13 Ivo Souza , David Vanderbilt

The X-ray magnetic circular dichroism (XMCD) has been measured at the Co K edge in Co-hcp and R-Co compounds (R=La, Tb, Dy). The structure of the experimental XMCD spectra in the near-edge region has been observed to be highly sensitive to…

Materials Science · Physics 2009-10-31 J. P. Rueff , R. M. Galera , Ch. Giorgetti , E. Dartyge , Ch. Brouder , M. Alouani

Magnetic Circular Dichroism (MCD) is a standard technique for the study of magnetic properties of materials in synchrotron beamlines. We present here a new scattering geometry in the Transmission Electron Microscope through which MCD can be…

Corrections to the atomic orbital sum rule for circular magnetic x-ray dichroism in solids are derived using orthonormal LMTOs as a single-particle basis for electron band states.

Materials Science · Physics 2009-10-31 R. Benoist , P. Carra , O. K. Andersen

X-ray magnetic circular dichroism provides a means to identify ferromagnetic, chiral, and altermagnetic orders via their time-reversal-symmetry ($\mathcal{T}$) breaking. However, differentiating magnetic domains related by crystallographic…

We present the x-ray magnetic circular dichroism (XMCD) at the Ni $L_{2,3}$-edge as an evidence of the $d$-wave altermagnetism in rutile-structure NiF$_2$. Sizable XMCD signal is observed in excellent agreement with theoretical simulations.…

In this work we derive sum rules for orbital angular momentum(OAM) resolved electron magnetic chiral dichroism (EMCD) which enable the evaluation of the strength of spin and orbital components of the atomic magnetic moments in a crystalline…

X-ray magnetic circular dichroism (XMCD) has become an important and powerful tool because it allows the study of material properties in combination with elemental specificity, chemical state specificity, and magnetic specificity. A new…

Instrumentation and Detectors · Physics 2015-06-19 Zhi-Ying Guo , Cai-Hao Hong , Hai-Ying Xing , Kun Tang , Wei Xui , Dong-liang Chen , Ming-Qi Cui , YI-Dong Zhao

We investigate the microscopic origin and spectral features of X-ray magnetic circular dichroism (XMCD) in collinear antiferromagnets with trigonal crystal fields, using $\alpha$-MnTe as a prototypical example. Although such systems exhibit…

Materials Science · Physics 2026-04-14 Norimasa Sasabe , Yuta Ishii , Yuichi Yamasaki

An efficient first principles approach to calculate X-ray magnetic circular dichroism (XMCD) and X-ray natural circular dichroism (XNCD) is developed and applied in the near edge region at the K-and L1-edges in solids. Computation of…

Altermagnetism is a recently identified magnetic symmetry class combining characteristics of conventional collinear ferromagnets and antiferromagnets, that were regarded as mutually exclusive, and enabling phenomena and functionalities…

A systematic ab-initio study within the framework of the local-spin-density approximation including spin-orbit coupling and an orbital-polarization term is performed for the spin and orbital moments and for the X-ray magnetic circular…

Materials Science · Physics 2009-11-07 Matej Komelj , Claude Ederer , James W. Davenport , Manfred Faehnle

We theoretically investigate the origin of the x-ray magnetic circular dichroism (XMCD) spectra at the K edges of Mn and Ga in the ferromagnetic phase of Mn3GaC on the basis of an ab initio calculation. Taking account of the spin-orbit…

Materials Science · Physics 2009-11-10 Manabu Takahashi , Jun-ichi Igarashi

X-ray circular dichroism, arising from the contrast in X-ray absorption between opposite photon helicities, serves as a spectroscopic tool to measure the magnetization of ferromagnetic materials and identify the handedness of chiral…

The orbital and spin magnetic moments, and the X-ray-magnetic circular-dichroism (XMCD) spectra at the $M_{4,5}$ edges of the U atoms in a UAs/Co multilayer and in an $\alpha$-U film are calculated within the framework of the…

Strongly Correlated Electrons · Physics 2009-11-10 Matej Komelj , Natasa Stojic

We analyze circular dichroism (CD) in resonant inelastic x-ray scattering (RIXS) in magnetic materials. We define RIXS-CD as the difference between scattering amplitudes for the right- and left-circularly polarized incoming photons and…

Materials Science · Physics 2025-08-07 M. Furo , A. Hariki , J. Kuneš

X-ray magnetic circular dichroism (XMCD) and resonant inelastic X-ray scattering with magnetic circular dichroism (RIXS-MCD) provide unparalleled insights into the electronic and magnetic dynamics of complex materials. Yet, their spectra…

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