Related papers: Charge-, salt- and flexoelectricity-driven anchori…
In this paper, we study electrostatic properties between two similar or oppositely charged surfaces immersed in an electrolyte solution by using mean-field approach accounting for solvent polarization and non-uniform size effect. Applying a…
Nematic phase is the most fundamental mesophase exhibited by most of the rod shaped anisotropic liquid crystalline molecules. Nematics are orientationally ordered fluids whose average orientation direction can be manipulated on application…
The present study aims to investigate utilizing field-effect for inducing heterogeneous surface charge and consequently changing the fluid flow in a solid-state nanochannel with converging-diverging periodicity. It is shown that the…
Nanofluidic systems show great promises for applications in energy conversion, where their performance can be enhanced by nanoscale liquid-solid slip. However, efficiency is also controlled by surface charge, which is known to reduce slip.…
The isotropic-to-nematic transition in liquid crystals is studied in d=3 spatial dimensions. A simulation method is proposed to measure the angle dependent interfacial tension g(theta), with theta the anchoring angle of the nematic phase at…
We demonstrate the generation of diverse material flow regimes in nematic liquid cells as driven by time-variable active surface anchoring, including no-net flow, oscillatory flow, steady flow, and pulsating flow. Specifically, we…
Bending rigidity of a charged membrane or a charged polyelectrolyte screened by monovalent counterions is known to be enhanced by electrostatic effects. We show that in the case of screening by multivalent counterions the electrostatic…
We examine fluctuation-induced (pseudo-Casimir) interactions in nematic liquid-crystalline films confined between two surfaces, where one of the surfaces imposes a strong homeotropic anchoring (ensuring a uniform mean director profile),…
We consider a thin horizontal layer of a non-magnetic electrolyte containing a bulk solution of salt and carrying an electric current. The layer is bounded by two deformable free surfaces loaded with an insoluble surfactant and is placed in…
We study the interaction between heterogeneously charged surfaces in an electrolyte solution by employing classical Density Functional Theory (cDFT) and Monte Carlo simulations. We observe a consistent behavior between cDFT and Monte Carlo…
Study of electrokinetics of nematic liquid crystals (LCs) with dissolved impurities hold utmost importance in understanding director distribution characteristics and modified flow rheology. However, no concrete theory for the non-uniform…
The study of the electrical double layer lies at the heart of colloidal and interfacial science. The standard mean-field Poisson-Boltzmann (PB) theory is incapable of modeling many phenomena originated from ion correlation. An important…
We derive a mathematical model of a nematic electrolyte based on a variational formulation of nematodynamics. Extending our previous work, we consider a general setup which incorporates dielectric anisotropy of the liquid-crystalline matrix…
The electroviscous effect deals with the change in the viscosity of fluids due to an external electric field. Here, we report experimental studies on the electroviscous effects in a ferroelectric nematic liquid crystal. It was synthesised…
We analytically derive the elastic, dielectric, piezoelectric, and the flexoelectric phenomenological coefficients as functions of microscopic model parameters such as ionic positions and spring constants in the two-dimensional…
Using molecular dynamics simulations we examine the effective interactions between two like-charged rods as a function of angle and separation. In particular, we determine how the competing electrostatic repulsions and…
We examine the influence of bidirectional anchoring on the unwinding of a planar cholesteric liquid crystal induced by the application of a magnetic field. We consider a liquid crystal layer confined between two plates with the helical axis…
We theoretically study the size effect of water molecule clusters not only on electrostatic interaction between two charged surfaces in an aqueous electrolyte but also on electroosmotic transport in a nanofluidic channel. Applying a free…
Electrosprays are a powerful technique to generate charged micro/nanodroplets. In the last century, the technique received extensive study and successful applications, including a Nobel price in Chemistry. However, nowadays its use in…
While fluids near a solid surface are at the core of applications in energy storage/conversion, electrochemistry/electrowetting and adsorption/catalysis, their nanoscale behavior remains only partially deciphered. Beyond conventional…