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Giant electroviscous effects in a ferroelectric nematic liquid crystal

Soft Condensed Matter 2023-03-21 v3

Abstract

The electroviscous effect deals with the change in the viscosity of fluids due to an external electric field. Here, we report experimental studies on the electroviscous effects in a ferroelectric nematic liquid crystal. It was synthesised accomplishing a new synthetic route which provides higher yield than conventional one. We measure electric field-dependent viscosity under a steady shear at different temperatures. In the low field range, the increase in viscosity (Δη=η(E)η0\Delta\eta=\eta(E)-\eta_0) is proportional to E2E^2 and the corresponding viscoelectric coefficient (f109f\approx10^{-9}m\textsuperscript{2}/V\textsuperscript{2}) of the ferroelectric nematic is 2 orders of magnitude larger than the apolar nematic liquid crystals and largest ever measured for a fluid. The apparent viscosity measured under a high electric field shows a power-law divergence η(TTc)0.7±0.05\eta\sim(T-T_c)^{-0.7\pm0.05}, followed by nearly an order of magnitude drop below the N-N\textsubscript{F} phase transition. Experimental results within the dynamical scaling approximation demonstrate rapid growth of polar domains under a strong electric field as the N-N\textsubscript{F} phase transition is approached. The gigantic electroviscous effects demonstrated here are important for emerging applications and understanding striking electrohydromechanical effects in ferroelectric nematic liquid crystals.

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Cite

@article{arxiv.2209.11154,
  title  = {Giant electroviscous effects in a ferroelectric nematic liquid crystal},
  author = {M. Praveen Kumar and Jakub Karcz and Przemyslaw Kula and Smarajit Karmakar and Surajit Dhara},
  journal= {arXiv preprint arXiv:2209.11154},
  year   = {2023}
}

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