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We present for the first time an efficient iterative method to directly solve the four-component Dirac-Kohn-Sham (DKS) density functional theory. Due to the existence of the negative energy continuum in the DKS operator, the existing…

Computational Physics · Physics 2013-05-03 Lin Lin , Sihong Shao , Weinan E

Chemical accuracy serves as an important metric for assessing the effectiveness of the numerical method in Kohn--Sham density functional theory. It is found that to achieve chemical accuracy, not only the Kohn--Sham wavefunctions but also…

Computational Physics · Physics 2023-10-25 Yang Kuang , Yedan Shen , Guanghui Hu

Quantum mechanical calculations for material modelling using Kohn-Sham density functional theory (DFT) involve the solution of a nonlinear eigenvalue problem for $N$ smallest eigenvector-eigenvalue pairs with $N$ proportional to the number…

Computational Physics · Physics 2023-09-26 Sameer Khadatkar , Phani Motamarri

The density functional theory (DFT) in electronic structure calculations can be formulated as either a nonlinear eigenvalue or direct minimization problem. The most widely used approach for solving the former is the so-called…

Computational Physics · Physics 2013-08-14 Xin Zhang , Jinwei Zhu , Zaiwen Wen , Aihui Zhou

Guessing Random Additive Noise Decoding (GRAND) and its variants, known for their near-maximum likelihood performance, have been introduced in recent years. One such variant, Segmented GRAND, reduces decoding complexity by generating only…

Information Theory · Computer Science 2025-12-19 Lukas Rapp , Jiewei Feng , Muriel Médard , Ken R. Duffy

We describe how to apply the recently developed pole expansion and selected inversion (PEXSI) technique to Kohn-Sham density function theory (DFT) electronic structure calculations that are based on atomic orbital discretization. We give…

Computational Physics · Physics 2015-06-04 Lin Lin , Mohan Chen , Chao Yang , Lixin He

The tree code for the approximate evaluation of gravitational forces is extended and substantially accelerated by including mutual cell-cell interactions. These are computed by a Taylor series in Cartesian coordinates and in a completely…

Astrophysics · Physics 2009-10-31 Walter Dehnen

With the development of low order scaling methods for performing Kohn-Sham Density Functional Theory, it is now possible to perform fully quantum mechanical calculations of systems containing tens of thousands of atoms. However, with an…

Chemical Physics · Physics 2020-04-03 William Dawson , Stephan Mohr , Laura E. Ratcliff , Takahito Nakajima , Luigi Genovese

This study presents a novel mixed-precision iterative refinement algorithm, GADI-IR, within the general alternating-direction implicit (GADI) framework, designed for efficiently solving large-scale sparse linear systems. By employing…

Numerical Analysis · Mathematics 2025-03-24 Jifeng Ge , Juan Zhang

The single particle energies obtained in a Kohn--Sham density functional theory (DFT) calculation are generally known to be poor approximations to electron excitation energies that are measured in transport, tunneling and spectroscopic…

Numerical Analysis · Mathematics 2017-12-29 Meiyue Shao , Lin Lin , Chao Yang , Fang Liu , Felipe H. da Jornada , Jack Deslippe , Steven G. Louie

Tensor permutation is a fundamental operation widely applied in AI, tensor networks, and related fields. However, it is extremely complex, and different shapes and permutation maps can make a huge difference. SIMD permutation began to be…

Data Structures and Algorithms · Computer Science 2025-06-05 Yaojian Chen , Tianyu Ma , An Yang , Lin Gan , Wenlai Zhao , Guangwen Yang

We present a spectrally accurate method for the rapid evaluation of free-space Stokes potentials, i.e. sums involving a large number of free space Green's functions. We consider sums involving stokeslets, stresslets and rotlets that appear…

Numerical Analysis · Mathematics 2018-01-18 Ludvig af Klinteberg , Davoud Saffar Shamshirgar , Anna-Karin Tornberg

The Kohn-Sham orbital kinetic energy density $\tau_\sigma(\vec{r}) = \sum_{i} w_{i\sigma} \big|\nabla \psi_{i\sigma}(\vec{r}) \big|^2$ is one fundamental quantity for constructing meta-generalized gradient approximations (meta-GGA) for use…

Materials Science · Physics 2015-06-23 Lin-Hui Ye

We describe a set of techniques for performing large scale ab initio calculations using multigrid accelerations and a real-space grid as a basis. The multigrid methods provide effective convergence acceleration and preconditioning on all…

mtrl-th · Physics 2008-02-03 E. L. Briggs , D. J. Sullivan , J. Bernholc

We describe an OctTree algorithm for the MPI-parallel, adaptive mesh-refinement code {\sc FLASH}, which can be used to calculate the gas self-gravity, and also the angle-averaged local optical depth, for treating ambient diffuse radiation.…

Instrumentation and Methods for Astrophysics · Physics 2018-01-24 Richard Wünsch , Stefanie Walch , František Dinnbier , Anthony P. Whitworth

We propose a novel adaptive damping algorithm for the self-consistent field (SCF) iterations of Kohn-Sham density-functional theory, using a backtracking line search to automatically adjust the damping in each SCF step. This line search is…

Materials Science · Physics 2022-03-14 Michael F. Herbst , Antoine Levitt

We present and review an efficient method to calculate the retarded Green's function in multi-terminal nanostructures; which is needed in order to calculate the conductance through the system and the local particle densities within it. The…

Mesoscale and Nanoscale Physics · Physics 2015-06-16 G. Thorgilsson , G. Viktorsson , S. I. Erlingsson

We present an efficient implemention of a non-equilibrium Green function (NEGF) method for self-consistent calculations of electron transport and forces in nanostructured materials. The electronic structure is described at the level of…

Mesoscale and Nanoscale Physics · Physics 2015-06-04 Jingzhe Chen , Kristian S. Thygesen , Karsten W. Jacobsen

Efficient hybrid DFT simulations of solid state materials would be extremely beneficial for computational chemistry and materials science, but is presently bottlenecked by difficulties in computing Hartree-Fock (HF) exchange with plane wave…

Chemical Physics · Physics 2024-10-30 Yuanheng Wang , Diptarka Hait , Pablo A. Unzueta , Juncheng Harry Zhang , Todd J. Martínez

The quantum mechanical ground state of electrons is described by Density Functional Theory, which leads to large minimization problems. An efficient minimization method uses a selfconsistent field (SCF) solution of large eigenvalue…

Materials Science · Physics 2007-05-23 Claus Bendtsen , Ole H. Nielsen , Lars B. Hansen