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We investigate the persistent orientation of asymmetric-top molecules induced by time-delayed THz pulses that are either collinearly or cross polarized. Our theoretical and numerical results demonstrate that the orthogonal configuration…

Chemical Physics · Physics 2023-12-05 Long Xu , Ilia Tutunnikov , Yehiam Prior , Ilya Sh. Averbukh

Impulsive orientation of symmetric-top molecules excited by two-color femtosecond pulses is considered. In addition to the well-known transient orientation appearing immediately after the pulse and then reemerging periodically due to…

Optics · Physics 2021-07-22 Long Xu , Ilia Tutunnikov , Yehiam Prior , Ilya Sh. Averbukh

We theoretically consider the phenomenon of field-free long-lasting orientation of symmetric-top molecules ionized by two-color laser pulses. The anisotropic ionization produces a significant long-lasting orientation of the surviving…

Chemical Physics · Physics 2023-03-08 Long Xu , Ilia Tutunnikov , Yehiam Prior , Ilya Sh. Averbukh

We investigate to which extend a THz laser pulse can be used to produce field-free molecular orientation at high temperature. We consider laser pulses that can be implemented with the state of the art technology and we show that the…

Quantum Physics · Physics 2015-06-05 M. Lapert , D. Sugny

Significant molecular orientation can be achieved by time-symmetric single-cycle pulses of zero area, in the THz region. We show that in spite of the existence of a combined time-space symmetry operation, not only large peak instantaneous…

Chemical Physics · Physics 2012-10-22 Juan Ortigoso

Chirality and chiral molecules are key elements in modern chemical and biochemical industries. Individual addressing, and the eventual separation of chiral enantiomers has been and still is an important elusive task in molecular physics and…

We review on the theoretical status of intense laser orientation and alignment. The evolution of the rotational wave packet and its dynamics leading to orientation and alignment is the topic of the present discussion. The major part of the…

Atomic Physics · Physics 2021-04-14 Vijit V. Nautiyal , Sumana Devi , Ashish Tyagi , Bhawna Vidhani , Anjali Maan , Vinod Prasad

Intense single-cycle THz pulses resonantly interacting with molecular rotations are shown to induce significant field-free orientation under ambient conditions. We calculate and measure the angular distribution associated with THz-driven…

Chemical Physics · Physics 2015-05-28 Sharly Fleischer , Yan Zhou , Robert W. Field , Keith A. Nelson

We study interaction of generic asymmetric molecules with a pair of strong time-delayed short laser pulses with crossed linear polarizations. We show that such an excitation not only provides unidirectional rotation of the most polarizable…

Chemical Physics · Physics 2018-02-28 E. Gershnabel , I. Sh. Averbukh

We show, both classically and quantum mechanically, enantioselective orientation of gas phase chiral molecules excited by laser fields with twisted polarization. Counterintuitively, the induced orientation, whose direction is laser…

Chemical Physics · Physics 2019-10-16 Ilia Tutunnikov , Johannes Floß , Erez Gershnabel , Paul Brumer , Ilya Sh. Averbukh

Ultrashort laser pulses are widely used for transient field-free molecular orientation -- a phenomenon important in chemical reaction dynamics, ultrafast molecular imaging, high harmonics generation, and attosecond science. However,…

Chemical Physics · Physics 2022-12-21 Ilia Tutunnikov , Long Xu , Yehiam Prior , Ilya Sh. Averbukh

We study the excitation of asymmetric-top (including chiral) molecules by two-color femtosecond laser pulses. In the cases of non-chiral asymmetric-top molecules excited by an orthogonally polarized two-color pulse, we demonstrate,…

Optics · Physics 2021-09-16 Long Xu , Ilia Tutunnikov , Yehiam Prior , Ilya Sh. Averbukh

We investigate experimentally and numerically the field-free orientation of the symmetric top molecule of methyl-iodide at high temperature using a terahertz radiation generated by a plasma induced by a two-color laser beam. The degree of…

Quantum Physics · Physics 2016-11-03 P. Babilotte , K. Hamraoui , F. Billard , E. Hertz , B. Lavorel , O. Faucher , D. Sugny

This study shows the unexpected and counter-intuitive possibility of simultaneously orienting a molecule while delocalizing its molecular axis in a plane in field-free conditions. The corresponding quantum states are characterized and…

Quantum Physics · Physics 2022-10-26 D. Sugny

Orientation states of two coupled polar molecules controlled by laser pulses are studied theoretically. By varying the period of a series of periodically applied laser pulse, transition from regular to chaotic behavior may occur. Schmidt…

Quantum Physics · Physics 2007-05-23 Ying-Yen Liao , Yueh-Nan Chen , Der-San Chuu

We present a theoretical study of the shaping of the time-evolution of field-free orientation of linear molecules. We show the extend to which the degree of orientation can be steered along a desired periodic time-dependent signal. The…

Quantum Physics · Physics 2019-05-15 R. Tehini , K. Hamraoui , D. Sugny

Alignment and orientation of molecules by intense, ultrashort laser fields are crucial for a variety of applications in physics and chemistry. These include control of high harmonics generation, molecular orbitals tomography, control of…

The mixed-field orientation of an asymmetric-rotor molecule with its permanent dipole moment non-parallel to the principal axes of polarizability is investigated experimentally and theoretically. We find that for the typical case of a…

Microscopic understanding of low-frequency molecular motions in liquids has been a longstanding goal in soft-matter science. So far, such low-frequency motions have mostly been accessed indirectly by off-resonant optical pulses. A more…

Soft Condensed Matter · Physics 2017-04-26 Mohsen Sajadi , Martin Wolf , Tobias Kampfrath

Sub-cycle electromagnetic pulses in the Terahertz region are considered to be one of the best ways to orient molecules. The simplest option corresponds to half-cycles pulses in the sudden regime, for which the pulse duration is much shorter…

Chemical Physics · Physics 2012-05-14 Juan Ortigoso
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