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Using Localized Surface Plasmon Resonance (LSPR) as an optical probe we demonstrate the presence of free carriers in phosphorus doped silicon nanocrystals (SiNCs) embedded in a silica matrix. In small SiNCs, with radius ranging from 2.6 to…

We introduce a combined Restrained MD/Parallel Tempering approach to study the difference in free energy as a function of a set of collective variables between two states in presence of unknown slow degrees of freedom. We applied this…

Statistical Mechanics · Physics 2015-03-19 Simone Meloni , Sergio Orlandini , Giovanni Ciccotti

A multi-reference configuration mixing scheme is used to describe the ground state, characterized by well defined spin and space group symmetry quantum numbers as well as doping fractions $N_{e}/N_{sites}$, of one dimensional Hubbard…

Strongly Correlated Electrons · Physics 2015-06-18 R. Rodríguez-Guzmán , Carlos A. Jiménez-Hoyos , Gustavo E. Scuseria

The following article presents a multi-length-scale characterization approach for investigating doping chemistry and spatial distributions within semiconductors, as demonstrated using a state-of-the-art CMOS image sensor. With an intricate…

We designed a high-entropy doped NASICON cathode, Na$_3$V$_{1.9}$(CrMoAlZrNi)$_{0.1}$(PO$_4$)$_3$ and investigate its electrochemical performance for sodium-ion batteries (SIBs) to understand the diffusion mechanism including distribution…

Materials Science · Physics 2026-02-05 Manish Kr. Singh , Rajendra S. Dhaka

We consider a Landau-de Gennes model for a suspension of small colloidal inclusions in a nematic host. We impose suitable anchoring conditions at the boundary of the inclusions, and we work in the dilute regime - i.e., the size of the…

Analysis of PDEs · Mathematics 2019-01-14 Giacomo Canevari , Arghir Zarnescu

Density-functional theory based global geometry optimization is used to scrutinize the possibility of endohedral doping of hydrogenated Si fullerenes as a route to Si nanostructures with high magnetic moments. In contrast to previous…

Materials Science · Physics 2013-07-26 Dennis Palagin , Karsten Reuter

Stabilization of grain structure is important for nanocrystalline alloys, and grain boundary segregation is a common approach to restrict coarsening. Doping can alter grain boundary structure, with high temperature states such as amorphous…

Materials Science · Physics 2023-09-15 Tianjiao Lei , Esther C. Hessong , Daniel S. Gianola , Timothy J. Rupert

In this communication, we represent a self-consistent systematic optimization procedure for the development of optimally tuned (OT) range-separated hybrid (RSH) functionals from \emph{first principles}. This is an offshoot of our recent…

Chemical Physics · Physics 2022-05-24 Abhisek Ghosal , Amlan K. Roy

The determining factor of the bulk properties of doped Si is the column rather than the row in the periodic table from which the dopants are drawn. It is unknown whether the basic properties of dopants at surfaces and interfaces, steadily…

Rare-earth doped crystals have numerous applications ranging from frequency metrology to quantum information processing. To fully benefit from their exceptional coherence properties, the effect of mechanical strain on the energy levels of…

Materials Science · Physics 2020-04-15 N. Galland , N. Lucic , B. Fang , S. Zhang , R. Letargat , A. Ferrier , P. Goldner , S. Seidelin , Y. Le Coq

We introduce an orbital-optimized double-hybrid (DH) scheme using the optimized-effective-potential (OEP) method. The orbitals are optimized using a local potential corresponding to the complete exchange-correlation energy expression…

In the present paper, we investigate the structural, thermodynamic, dynamic, elastic, and electronic properties of doped 2D diamond C$_4$X$_2$ (X = B or N) nanosheets in both AA$'$A$''$ and ABC stacking configurations, by first-principles…

Materials Science · Physics 2024-01-10 Bruno Ipaves , João F. Justo , Biplab Sanyal , Lucy V. C. Assali

Systems of elongated molecules, doped with small amounts of molecules lacking mirror symmetry can form macroscopically twisted cholesteric liquid crystal phases. The aim of this work is to rigorously derive the Oseen-Frank model of…

Analysis of PDEs · Mathematics 2020-06-24 Jamie M. Taylor

Theory of electronic and optical properties of exciton and bi-exciton complexes confined in CdSe spherical nanocrystals is presented. The electron and hole states are computed using atomistic $sp^3d^5s^*$ tight binding Hamiltonian including…

Mesoscale and Nanoscale Physics · Physics 2015-05-20 Marek Korkusinski , Oleksandr Voznyy , Pawel Hawrylak

We investigate the electronic and magnetic properties of Mn-doped CdTe nanocrystals (NCs) with 2 nm in diameter which can be experimentally synthesized with Mn atoms inside. Using the density-functional theory, we consider two doping cases:…

Mesoscale and Nanoscale Physics · Physics 2015-05-18 C. Echeverría-Arrondo , J. Pérez-Conde , A. Ayuela

Ab-initio calculations based on density functional theory (DFT) have been performed to study the optical properties of pure graphene and have been compared to that of individual boron (B), nitrogen (N) and BN co-doped graphene sheet. The…

Mesoscale and Nanoscale Physics · Physics 2020-05-22 Pooja Rani , Girija S Dubey , V. K. Jindal

The simulation of stochastic reaction-diffusion systems using fine-grained representations can become computationally prohibitive when particle numbers become large. If particle numbers are sufficiently high then it may be possible to…

Quantitative Methods · Quantitative Biology 2020-10-02 Christian A. Yates , Adam George , Armand Jordana , Cameron A. Smith , Andrew B. Duncan , Konstantinos C. Zygalakis

The stochastic density functional theory (DFT) [Phys. Rev. Lett. 111, 106402 (2013)] is a valuable linear scaling approach to Kohn-Sham DFT that does not rely on the sparsity of the density matrix. Linear (and often sub-linear) scaling is…

Chemical Physics · Physics 2019-02-20 Ming Chen , Roi Baer , Daniel Neuhauser , Eran Rabani

We investigate the topological plasmon polaritons (TPPs) in one-dimensional dimerized doped silicon nanoparticle chains, as an analogy of the topological edge states in the Su-Schrieffer-Heeger (SSH) model. The photonic band structures are…

Optics · Physics 2020-03-18 B. X. Wang , C. Y. Zhao
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