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Doping of semiconductors by impurity atoms enabled their widespread technological application in micro and opto-electronics. For colloidal semiconductor nanocrystals, an emerging family of materials where size, composition and shape-control…

Materials Science · Physics 2021-05-25 David Mocatta , Guy Cohen , Jonathan Schattner , Oded Millo , Eran Rabani , Uri Banin

The preferred location of boron and phosphorus in oxidized free-standing Si nanoparticles was investigated using a first-principles density functional approach. The calculated formation energies indicate that P should segregate to the…

Materials Science · Physics 2015-06-05 A. Carvalho , S. Oberg , M. Barroso , M. J. Rayson , P. R. Briddon

We extend the range-separated double-hybrid RSH+MP2 method [J. G. Angyan et al., Phys. Rev. A 72, 012510 (2005)], combining long-range HF exchange and MP2 correlation with a short-range density functional, to a fully self-consistent version…

Chemical Physics · Physics 2019-12-24 Szymon Smiga , Ireneusz Grabowski , Mateusz Witkowski , Bastien Mussard , Julien Toulouse

Single atom manipulation within doped correlated electron systems would be highly beneficial to disentangle the influence of dopants, structural defects and crystallographic characteristics on their local electronic states. Unfortunately,…

Superconductivity · Physics 2020-01-08 F. Massee , Y. K. Huang , M. Aprili

Tuning of the electronic properties of pre-synthesized colloidal semiconductor nanocrystals (NCs) by doping plays a key role in the prospect of implementing them in printed electronics devices such as transistors, and photodetectors. While…

Materials Science · Physics 2021-05-25 Yorai Amit , Yuanyuan Li , Anatoly I. Frenkel , Uri Banin

In this study, the structural, electronic and optical properties of Pb doped rutile SnO$_2$ were investigated using the range separated hybrid exchange-correlation functional method. In the calculations, LDA functional was used instead of…

Materials Science · Physics 2021-07-28 Veysel Çelik

Silicon nanocrystals with diameters between 1 and 3 nm and surfaces passivated by chlorine or a mixture of chlorine and hydrogen were modeled using density functional theory, and their properties compared with those of fully hydrogenated…

Mesoscale and Nanoscale Physics · Physics 2013-11-06 A. Carvalho , S. Öberg , M. J. Rayson , P. R. Briddon

The cuprate material BSCCO-2212 is believed to be doped by a combination of cation switching and excess oxygen. The interstitial oxygen dopants are of particular interest because scanning tunnelling microscopy (STM) experiments have shown…

Superconductivity · Physics 2009-11-11 Y. He , T. S. Nunner , P. J. Hirschfeld , H. -P. Cheng

We analyze enhancements in the magnitude of the self-energy for electrons far away from the Fermi surface in doped Mott insulators using the dynamical cluster approximation to the Hubbard model. For large onsite repulsion, U, and hole…

Strongly Correlated Electrons · Physics 2016-01-11 J. Merino , O. Gunnarsson , G. Kotliar

Using simulations we explore the behaviour of two-dimensional colloidal (poly)crystals doped with active particles. We show that these active dopants can provide an elegant new route to removing grain boundaries in polycrystals.…

Soft Condensed Matter · Physics 2016-03-31 B. van der Meer , L. Filion , M. Dijkstra

In this work, the electronic and optical properties of a Nitrogen (N) or a Boron (B) doped BeO monolayer are investigated in the framework of density functional theory. It is known that the band gap of a BeO monolayer is large leading to…

We present an implementation in a linear-scaling density-functional theory code of an electronic enthalpy method, which has been found to be natural and efficient for the ab initio calculation of finite systems under hydrostatic pressure.…

Mesoscale and Nanoscale Physics · Physics 2015-06-16 Niccolò R. C. Corsini , Andrea Greco , Nicholas D. M. Hine , Carla Molteni , Peter D. Haynes

We have used density functional theory to study the energetics and electronic structure of aluminium dopants in crystalline silicon. We present data regarding the atomic and electronic structure and properties of pairs of substitutional…

Materials Science · Physics 2019-07-09 Jack T. L. Poulton , David R. Bowler

Local fluctuations in the distribution of dopant atoms are a suspected cause of nanoscale electronic disorder or phase separation observed within the pnictide superconductors. Atom probe tomography results present the first direct…

Superconductivity · Physics 2011-06-30 W. K. Yeoh , B. Gault , X. Y. Cui , C. Zhu , M. P. Moody , L. Li , R. K. Zheng , W. X Li , X. L. Wang , S. X. Dou , C. T. Lin , S. P. Ringer

Controlling dopant transport with high spatial precision is crucial for improving the semiconductor functionality, reliability, and scalability. Although prior models of noise-assisted diffusion have been largely confined to idealized one…

Statistical Mechanics · Physics 2025-09-12 Mesfin Taye , Yoseph Abebe , Tibebe Birhanu , Lemi Demeyu , Mulugeta Bekele

We construct range-separated double-hybrid schemes which combine coupled-cluster or random-phase approximations with a density functional based on a two-parameter Coulomb-attenuating-method-like decomposition of the electron-electron…

Chemical Physics · Physics 2020-01-29 Cairedine Kalai , Bastien Mussard , Julien Toulouse

Recently developed fused-ring electron-acceptors such as Y6 (BTP-4F) have strong oscillator strength, good charge-carrier transport and a small bandgap. They therefore have enormous current technical application to organic optoelectronics,…

Materials Science · Physics 2026-05-15 Tom Ward , Isabel Creed , Tim Rein , Jarvist Moore Frost

The kinetics of intrinsic and dopant-enhanced solid phase epitaxy (SPE) are stud- ied in buried amorphous Si (a-Si) layers in which SPE is not retarded by H. As, P, B and Al profiles were formed by multiple energy ion implantation over a…

Materials Science · Physics 2010-08-02 B. C. Johnson , J. C. McCallum

We present a highly efficient molecular dynamics scheme for calculating the concentration depth profile of dopants in ion irradiated materials. The scheme incorporates several methods for reducing the computational overhead, plus a rare…

Computational Physics · Physics 2009-10-31 Keith M. Beardmore , Niels Gronbech-Jensen

Multiconfigurational short-range density functional theory (MC-srDFT) rigorously combines ground state wavefunction theory with DFT. Unlike single-reference range-separated hybrid functionals, MC-srDFT has lacked theoretically grounded…

Chemical Physics · Physics 2026-03-05 Michał Hapka , Katarzyna Pernal , Ewa Pastorczak