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We prepare mixtures of ultracold CaF molecules and Rb atoms in a magnetic trap and study their inelastic collisions. When the atoms are prepared in the spin-stretched state and the molecules in the spin-stretched component of the first…

Collisions between ultracold calcium monohydroxide (CaOH) molecules are realized and studied. Inelastic collision rate constants are measured for CaOH prepared in ground and excited vibrational states, and the electric field dependence of…

We study inelastic collisions between CaF molecules and $^{87}$Rb atoms in a dual-species magneto-optical trap. The presence of atoms increases the loss rate of molecules from the trap. By measuring the loss rates and density distributions,…

We study collisions of ultracold CaF molecules in strong static electric fields. These fields allow the creation of long-range barriers in the interaction potential, effectively preventing the molecules from reaching the short-range region…

Ultracold collisions between Cs atoms and Cs2 dimers in the electronic ground state are observed in an optically trapped gas of atoms and molecules. The Cs2 molecules are formed in the triplet ground state by cw-photoassociation through the…

Atomic Physics · Physics 2009-11-11 Peter Staanum , Stephan D. Kraft , Joerg Lange , Roland Wester , Matthias Weidemueller

Collision cross sections and rate constants between two ground- state oxygen molecules are investigated theoretically at translational energies below $\sim 1$K and in zero magnetic field. We present calculations for elastic and spin-…

Atomic Physics · Physics 2009-11-07 Alexandr V. Avdeenkov , John L. Bohn

The collisional stability of ultracold polar molecules in electrostatic traps is considered. Rate constants for collisions that drive molecules from weak-field-seeking to strong-field-seeking states are estimated using a simple model. The…

Atomic Physics · Physics 2009-11-06 John L. Bohn

Exploring inelastic and reactive collisions on the quantum level is a main goal of the developing field of ultracold chemistry. We present first experimental studies of inelastic collisions of metastable ultracold triplet molecules in the…

Ultra-cold RbCs molecules in high-lying vibrational levels of the a$^3\Sigma^+$ ground electronic state are confined in an optical trap. Inelastic collision rates of these molecules with both Rb and Cs atoms are determined for individual…

Universal collision rate constants are calculated for ultracold collisions of two like bosonic or fermionic heteronuclear alkali-metal dimers involving the species Li, Na, K, Rb, or Cs. Universal collisions are those for which the short…

Chemical Physics · Physics 2017-09-13 Paul S. Julienne , Thomas M. Hanna , Zbigniew Idziaszek

Understanding and controlling collisions is crucial to the burgeoning field of ultracold molecules. All experiments so far have observed fast loss of molecules from the trap. However, the dominant mechanism for collisional loss is not well…

The collision of molecules at ultracold temperatures is of great importance for understanding the chemical interactions at the quantum regime. While much theoretical work has been devoted to this, experimental data are only available…

Quantum Gases · Physics 2018-01-30 Xin Ye , Mingyang Guo , Maykel L. González-Martínez , Goulven Quéméner , Dajun Wang

We investigate the role of hyperfine structure in resonant-dipole interactions between two atoms cotrapped in an optical tweezer. Two-body loss rates from light-assisted collisions (LACs) are measured across the $^{87}$Rb hyperfine spectrum…

Atomic Physics · Physics 2025-01-14 Steven K. Pampel , Matteo Marinelli , Mark O. Brown , José P. D'Incao , Cindy A. Regal

Accurate \textit{ab initio} potential energy surfaces are essential to understand and predict collisional outcomes in ultracold molecular systems. In this study, we explore the intermolecular interactions between two laser-cooled CaF…

Atomic Physics · Physics 2025-11-12 Dibyendu Sardar , Marcin Gronowski , Michał Tomza , John L. Bohn

Recent experiments on ultracold non-reactive dipolar molecules have observed high two-body losses, even though these molecules can undergo neither inelastic, nor reactive (as they are in their absolute ground state), nor light-assisted…

Atomic Physics · Physics 2024-06-21 Goulven Quéméner , James F. E. Croft , John L. Bohn

Utilizing single-photon photoassociation, we have achieved ultracold rubidium molecules with a high number density that provides a new efficient approach toward molecular quantum degeneracy. A new detection mechanism for ultracold molecule…

Atomic Physics · Physics 2015-06-12 Jun-Ren Chen , Cheng-Yang Kao , Hung-Bin Chen , Yi-Wei Liu

Understanding ultracold collisions involving molecules is of fundamental importance for current experiments, where inelastic collisions typically limit the lifetime of molecular ensembles in optical traps. Here we present a broad study of…

Ultracold polar molecules are promising for quantum information processing and searches for physics beyond the Standard Model. Laser cooling to ultracold temperatures is an established technique for trapped diatomic and triatomic molecules.…

Collisional complexes, which are formed as intermediate states in molecular collisions, are typically short-lived and decay within picoseconds. However, in ultracold collisions involving bialkali molecules, complexes can live for…

Chemical Physics · Physics 2023-01-13 Roman Bause , Arthur Christianen , Andreas Schindewolf , Immanuel Bloch , Xin-Yu Luo

Harnessing the potential wide-ranging quantum science applications of molecules will require control of their interactions. Here, we use microwave radiation to directly engineer and tune the interaction potentials between ultracold calcium…

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