Related papers: Efficient and robust chiral resolution by composit…
We present an optical "enantio-selective switch", that, in two steps, turns a ("racemic") mixture of left-handed and right-handed chiral molecules into the enantiomerically pure state of interest. The optical switch is composed of an…
A number of composite pulse (CP) sequences for four basic quantum phase gates -- the Z, S, T and general phase gates -- are presented. The CP sequences contain up to 18 pulses and can compensate up to eight orders of experimental errors in…
We propose an approach to sensitively probe the chirality of molecules by measuring their coherent optical absorption spectra. It is shown that quantum dynamics of the cyclic three-level chiral molecules driven by appropriately-designed…
We study quantum systems with broken symmetry that can be modelled as cyclic three-level atoms with coexisting one- and two-photon transitions. They can be selectively optically excited to any state. As an example, we show that left- and…
Recently, two related three wave mixing experiments have been demonstrated that use allowed rotational transitions to produce a free induction decay signal with an amplitude linearly proportional to the enantiomeric excess of a chiral…
We derive a pulse-area theorem for a cyclic three-level system, an archetypal model for exploring enantioselective state transfer (ESST) in chiral molecules driven by three linearly polarized microwave pulses. By dividing the closed-loop…
Systematic errors hinder precise quantum control. Pulse length errors (PLEs) and off-resonance errors (OREs) are typical systematic errors that are encountered during one-qubit control. A composite pulse (CP) can help compensate for the…
Chiral four-wave-mixing signals are calculated using the irreducible tensor formalism. Different polarization and crossing angle configurations allow to single out the magnetic dipole and the electric quadrupole interactions. Other…
Trains of ultrashort laser pulses separated by the time of rotational revival (typically, tens of picoseconds) have been exploited for creating ensembles of aligned molecules. In this work we introduce a chiral pulse train - a sequence of…
Strong light-matter coupling in chiral cavities has been proposed as an effective way to selectively interact with an enantiomer that shares the same handedness as the cavity's chiral mode. We show that surface plasmons supported by a…
Electrostatic hexapoles are revealed as a powerful tool in the rotational state-selection and alignment of molecules to be utilized in beam experiments on collisional and photoinitiated processes. In the paper, we report results on the…
Photoelectron circular dichroism (PECD) is a highly sensitive enantiospecific spectroscopy for studying chiral molecules in the gas phase using either single-photon ionization or multiphoton ionization. In the short pulse limit investigated…
We prove complete controllability for rotational states of an asymmetric top molecule belonging to degenerate values of the orientational quantum number M. Based on this insight, we construct a pulse sequence that energetically separates…
The measurement of circular dichroism (CD) has widely been exploited to distinguish the different enantiomers of chiral structures. It has been applied to natural materials (e.g. molecules) as well as to artificial materials (e.g.…
Chiral systems exhibit unique properties traditionally linked to their asymmetric spatial arrangement. Recently, multiple laser pulses were shown to induce purely electronic chiral states without altering the nuclear configuration. Here, we…
We introduce a novel control method for robust quantum information processing suited for quantum integrated photonics. We utilize off-resonant detunings as control parameters to derive a new family of composite pulses for high-fidelity…
We develop theoretically and demonstrate experimentally a universal dynamical decoupling method for robust quantum sensing with unambiguous signal identification. Our method uses randomisation of control pulses to suppress simultaneously…
In liquid-state NMR quantum computation, a selective entanglement operator between qubits 2 and 3 of a three-qubit molecule is conventionally realized by applying a pair of short $\pi$-pulses to qubit 1. This method, called refocusing, is…
The error-robust and short composite operations named ConCatenated Composite Pulses (CCCPs), developed as high-precision unitary operations in quantum information processing (QIP), are derived from composite pulses widely employed in…
An interesting class of molecules is that in which the molecules do not possess a stereogenic center but can become chiral due to their spatial arrangement. These molecules can be seen as chiral conformers, whose two non-superimposable…