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We present two methods for efficient detection of chiral molecules based on sequences of single pulses and Raman pulse pairs. The chiral molecules are modelled by a closed-loop three-state system with different signs in one of the couplings…

Quantum Physics · Physics 2020-11-18 Boyan T. Torosov , Michael Drewsen , Nikolay V. Vitanov

Chiral molecules with broken parity symmetries can be modeled as quantum systems with cyclic-transition structures. By using these novel properties, we design two-step laser pulses to distinguish left- and right-handed molecules from the…

Quantum Physics · Physics 2015-05-19 W. Z. Jia , L. F. Wei

We propose to discriminate chiral molecules by combining one- and two-photon processes in a closed-loop configuration. The one-photon-coupling intrinsic {\pi}-phase difference between two enantiomers leads to their different superposition…

Quantum Physics · Physics 2020-02-20 Jin-Lei Wu , Yan Wang , Jie Song , Yan Xia , Shi-Lei Su , Yong-Yuan Jiang

We theoretically introduce a scheme to perform Ramsey spectroscopy on a racemic mixture of chiral molecules, simultaneously extracting the transition frequencies of the left- and right-handed molecules, known as enantiomers. By taking the…

Atomic Physics · Physics 2023-11-07 Itay Erez , Eliana Ruth Wallach , Yuval Shagam

Composite pulses --- sequences of pulses with well defined relative phases --- are an efficient, robust and flexible technique for coherent control of quantum systems. Composite sequences can compensate a variety of experimental errors in…

Quantum Physics · Physics 2019-08-21 Boyan T. Torosov , Nikolay V. Vitanov

We propose an accurate and convenient method to achieve 100\% discrimination of chiral molecules with Lewis-Riesenfeld invariant. By reversely designing the pulse scheme of handed resolution, we obtain the parameters of the three-level…

Quantum Physics · Physics 2023-05-24 Hang Xu , Xue-Ke Song , Dong Wang , Liu Ye

A highly-efficient method for optical detection and separation of left- and right-handed chiral molecules is presented. The method utilizes a closed-loop three-state system in which the population dynamics depends on the phases of the three…

Quantum Physics · Physics 2019-05-08 Nikolay V. Vitanov , Michael Drewsen

A new scheme for enantiomer differentiation of chiral molecules using a pair of linearly polarized intense ultrashort laser pulses with skewed mutual polarization is presented. The technique relies on the fact that the off-diagonal…

Chemical Physics · Physics 2017-05-04 Andrey Yachmenev , Sergei N. Yurchenko

A novel optical method for distinguishing chiral molecules is proposed and validated within a quantum simulator employing a trapped-ion qudit. This approach correlates the sign disparity of the dipole moment of chiral molecules with…

Quantum Physics · Physics 2024-03-11 Teng Liu , Fa Zhao , Pengfei Lu , Qifeng Lao , Min Ding , Ji Bian , Feng Zhu , Le Luo

Developing effective methods to measure the enantiomeric excess of the chiral mixture is one of the major topics in chiral molecular researches, yet remains challenging. Enantiodetection method via two-dimensional (2D) spectroscopy based on…

Chemical Physics · Physics 2023-05-05 Mao-Rui Cai , Chong Ye , Yong Li , Hui Dong

Enantiodetection of chiral molecules is important to pharmaceutical drug production, chemical reaction control, and biological function designs. Traditional optical methods of enantiodetection rely on the weak magnetic-dipole or…

Chemical Physics · Physics 2022-09-14 Mao-Rui Cai , Chong Ye , Hui Dong , Yong Li

We study the excitation of asymmetric-top (including chiral) molecules by two-color femtosecond laser pulses. In the cases of non-chiral asymmetric-top molecules excited by an orthogonally polarized two-color pulse, we demonstrate,…

Optics · Physics 2021-09-16 Long Xu , Ilia Tutunnikov , Yehiam Prior , Ilya Sh. Averbukh

We investigate the application of amplitude-shaped control pulses for enhancing the time and frequency resolution of multipulse quantum sensing sequences. Using the electronic spin of a single nitrogen vacancy center in diamond and up to…

Quantum Physics · Physics 2018-01-03 J. Zopes , K. Sasaki , K. S. Cujia , J. M. Boss , K. Chang , T. F. Segawa , K. M. Itoh , C. L. Degen

We derive composite pulse sequences that achieve high-fidelity excitation of two-state systems in an optically dense, inhomogeneously broadened ensemble. The composite pulses are resistant to distortions due to the back-action of the medium…

Quantum Physics · Physics 2016-02-24 Gabor Demeter

Systematic errors in quantum operations can be the dominating source of imperfection in achieving control over quantum systems. This problem, which has been well studied in nuclear magnetic resonance, can be addressed by replacing single…

Quantum Physics · Physics 2007-05-23 Kenneth Brown , Aram Harrow , Isaac Chuang

Microwave three-wave mixing allows for enantiomer-selective excitation of randomly oriented chiral molecules into rotational states with different energy. The random orientation of molecules is reflected in the degeneracy of the rotational…

Quantum Physics · Physics 2022-08-02 Monika Leibscher , Jonas Kalveram , Christiane P. Koch

Enantioselective orientation of chiral molecules excited by a shaped picosecond laser pulse and a delayed femtosecond pulse is considered. Using quantum mechanical simulations, we demonstrate a strong field-free enantioselective orientation…

Optics · Physics 2022-03-31 Long Xu

Three-wave mixing spectroscopy of chiral molecules, which exist in left-handed and right-handed conformations, allows for enantio-selective population transfer despite random orientation of the molecules. This is based on constructive…

Quantum Physics · Physics 2019-07-09 Monika Leibscher , Thomas F. Giesen , Christiane P. Koch

Enantiodetection is an important and challenging task across natural science. Nowadays, some chiroptical methods of enantiodetection based on decoherence-free cyclic three-level models of chiral molecules can reach the ultimate limit of the…

Quantum Physics · Physics 2022-11-29 Chong Ye , Xiaowei Mu , Yifan Sun , Libin Fu , Xiangdong Zhang

We propose a method to realize enantiodiscrimination of chiral molecules based on quantum correlation function in a driven cavity-molecule system, where the chiral molecule is coupled with a quantized cavity field and two classical light…

Quantum Physics · Physics 2022-08-12 Fen Zou , Yu-Yuan Chen , Bo Liu , Yong Li
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