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Essential to various practical applications of lithium-ion batteries is the availability of accurate equivalent circuit models. This paper presents a new coupled electro-thermal model for batteries and studies how to extract it from data.…

Systems and Control · Electrical Eng. & Systems 2024-08-21 Hao Tu , Xinfan Lin , Yebin Wang , Huazhen Fang

This paper investigates the identifiability and estimation of the parameters of the single particle model (SPM) for lithium-ion battery simulation. Identifiability is addressed both in principle and in practice. The approach begins by…

Systems and Control · Computer Science 2018-10-03 Adrien M. Bizeray , Jin-Ho Kim , Stephen R. Duncan , David A. Howey

Efficient parameter identification of electrochemical models is crucial for accurate monitoring and control of lithium-ion cells. This process becomes challenging when applied to complex models that rely on a considerable number of…

Systems and Control · Electrical Eng. & Systems 2024-05-20 Jianzong Pi , Samuel Filgueira da Silva , Mehmet Fatih Ozkan , Abhishek Gupta , Marcello Canova

Growing demand for fast charging and optimised battery designs is fuelling significant interest in electrochemical models of Li-ion batteries. However, estimating parameter values for these models remains a major challenge. In this paper, a…

Systems and Control · Electrical Eng. & Systems 2020-12-04 Ross Drummond , Stephen R. Duncan

In this work we analyse the local nonlinear electrochemical impedance spectroscopy (NLEIS) response of a lithium-ion battery and estimate model parameters from measured NLEIS data. The analysis assumes a single-particle model including…

Chemical Physics · Physics 2023-04-24 T. L. Kirk , A. Lewis-Douglas , D. A. Howey , C. P. Please , S. J. Chapman

The standard continuum model of a lithium-ion battery, the Doyle-Fuller-Newman (DFN) model, is computationally expensive to solve. Typically simpler models, such as the single particle model (SPM), are used to provide insight for control…

Chemical Physics · Physics 2019-11-07 Scott G. Marquis , Valentin Sulzer , Robert Timms , Colin P. Please , S. Jon Chapman

We consider the problem of parameterizing Newman-type models of Li-ion batteries focusing on quantifying the inherent uncertainty of this process and its dependence on the discharge rate. In order to rule out genuine experimental error and…

Computational Physics · Physics 2021-04-14 Jose Morales Escalante , Smita Sahu , Jamie M. Foster , Bartosz Protas

Battery degradation, which is the reduction of performance over time, is one of the main roadblocks to the wide deployment of lithium-ion batteries. Physics-based models, such as those based on the Doyle-Fuller-Newman model, are invaluable…

Chemical Physics · Physics 2023-06-06 Ferran Brosa Planella , W. Dhammika Widanage

The Doyle-Fuller-Newman framework is the most popular physics-based continuum-level description of the chemical and dynamical internal processes within operating lithium-ion-battery cells. With sufficient flexibility to model a wide range…

Battery management systems may rely on mathematical models to provide higher performance than standard charging protocols. Electrochemical models allow us to capture the phenomena occurring inside a lithium-ion cell and therefore, could be…

Computational Engineering, Finance, and Science · Computer Science 2020-05-12 Andrea Pozzi , Xiangzhong Xie , Davide M Raimondo , René Schenkendorf

The Doyle-Fuller-Newman model is arguably the most ubiquitous electrochemical model in lithium-ion battery research. Since it is a highly nonlinear model, its input-output relations are still poorly understood. Researchers therefore often…

Electrochemical hybrid battery models have major potential to enable advanced physics-based control, diagnostic, and prognostic features for next-generation lithium-ion battery management systems. This is due to the physical significance of…

Systems and Control · Electrical Eng. & Systems 2025-05-13 Jackson Fogelquist , Xinfan Lin

Non-invasive parametrisation of physics-based battery models can be performed by fitting the model to electrochemical impedance spectroscopy (EIS) data containing features related to the different physical processes. However, this requires…

Systems and Control · Electrical Eng. & Systems 2025-06-11 Noël Hallemans , Nicola E. Courtier , Colin P. Please , Brady Planden , Rishit Dhoot , Robert Timms , S. Jon chapman , David Howey , Stephen R. Duncan

This contribution presents a parameter identification methodology for the accurate and fast estimation of model parameters in a pseudo-two-dimensional (P2D) battery model. The methodology consists of three key elements. First, the data for…

Systems and Control · Electrical Eng. & Systems 2025-07-21 L. D. Couto , K. Haghverdi , F. Guo , K. Trad , G. Mulder

Physics-based electrochemical battery models derived from porous electrode theory are a very powerful tool for understanding lithium-ion batteries, as well as for improving their design and management. Different model fidelity, and thus…

Physico-chemical continuum battery models are typically parameterized by manual fits, relying on the individual expertise of researchers. In this article, we introduce a computer algorithm that directly utilizes the experience of battery…

Data Analysis, Statistics and Probability · Physics 2023-02-08 Yannick Kuhn , Hannes Wolf , Arnulf Latz , Birger Horstmann

This paper proposes a hierarchical Bayesian model for probabilistic estimation of the electric vehicle battery capacity fade. Since the battery aging factors such as temperature, current, and state of charge are not fixed, and they change…

Systems and Control · Electrical Eng. & Systems 2019-11-05 Mehdi Jafari , Laura E. Brown , Lucia Gauchia

The Doyle-Fuller-Newman (DFN) model is a common mechanistic model for lithium-ion batteries. The reaction rate constant and diffusivity within the DFN model are key parameters that directly affect the movement of lithium ions, thereby…

Systems and Control · Electrical Eng. & Systems 2025-04-15 Marc D. Berliner , Minsu Kim , Xiao Cui , Vivek N. Lam , Patrick A. Asinger , Martin Z. Bazant , William C. Chueh , Richard D. Braatz

Parameter estimation is of foundational importance for various model-based battery management tasks, including charging control, state-of-charge estimation and aging assessment. However, it remains a challenging issue as the existing…

Systems and Control · Electrical Eng. & Systems 2022-07-13 Ning Tian , Yebin Wang , Jian Chen , Huazhen Fang

A model of a lithium-ion battery containing a cosolvent electrolyte is developed and implemented within the open-source PyBaMM platform. Lithium-ion electrolytes are essential to battery operation and normally contain at least two solvents…

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