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Related papers: Tuning Penta-Graphene Electronic Properties Throug…

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In the present work, first-principles calculations based on the density functional theory (DFT), GW approximation and Bethe-Salpeter equation (BSE) are performed to study the electronic and optical properties of penta-graphene (PG)…

Computational Physics · Physics 2024-01-12 Babak Minaie , Seyed A. Ketabi , José M. De Sousa

Tetra-Penta-Deca-Hexa-graphene (TPDH) is a new 2D carbon allotrope with attractive electronic and mechanical properties. It is composed of tetragonal, pentagonal, and hexagonal carbon rings. When TPDH-graphene is sliced into…

Materials Science · Physics 2024-07-01 Juan Gomez Quispe , Douglas Soares Galvao , Pedro Alves da Silva Autreto

Recently, a new two-dimensional carbon allotrope called pentagraphene (PG) was proposed. PG exhibits mechanical and electronic interesting properties, including typical band gap values of semiconducting materials. PG has a Cairo-tiling-like…

Mesoscale and Nanoscale Physics · Physics 2017-03-13 J. M. de Sousa , A. L. Aguiar , E. C. Girao , Alexandre F. Fonseca , A. G. Souza Filho , Douglas S. Galvao

The shortcomings of mono-component systems, e.g., the gapless nature of graphene, the lack of air-stability in phosphorene, etc. have drawn great attention toward stacked materials expected to show interesting electronic and optical…

Mesoscale and Nanoscale Physics · Physics 2020-12-24 Maryam Mahdavifar , Sima Shekarforoush , Farhad Khoeini

All carbon electronics based on graphene has been an elusive goal. For more than a decade, the inability to produce significant band-gaps in this material has prevented the development of semiconducting graphene. While chemical…

Graphene monolayer is a material with zero band gap, because of which its applications in optoelectronics are limited. The question arises, can we modify the optoelectronic properties of graphene by doping it with other atoms? Synthesis of…

Materials Science · Physics 2026-03-18 Samayita Das , Alok Shukla

The novel carbon allotrope with particular and unique 2D arrangement of carbon atoms similar to a Cairo pentagonal tiling, with interplay of $sp^{3}$ and $sp^{2}$ hybridized carbon atoms is called of Penta-graphene (PG). Previous…

Materials Science · Physics 2021-07-07 W. H. S. Brandão , A. L. Aguiar , J. M. De Sousa

Being a true two-dimensional crystal, graphene has special properties. In particular, a point-like defect in graphene may have effects in the long range. This peculiarity questions the validity of using a supercell geometry in an attempt to…

Materials Science · Physics 2015-06-05 Philippe Lambin , Hakim Amara , François Ducastelle , Luc Henrard

We have investigated the way in which the concentration and distribution of adatoms affect the geometric and electronic properties of graphene. Our calculations were based on the use of first principle under the density functional theory…

Mesoscale and Nanoscale Physics · Physics 2017-03-08 Ngoc Thanh Thuy Tran , Dipendra Dahal , Godfrey Gumbs , Ming-Fa Lin

We investigate electronic transport in the nitrogen-doped graphene containing different configurations of point defects: singly or doubly substituting N atoms and nitrogen-vacancy complexes. The results are numerically obtained using the…

Mesoscale and Nanoscale Physics · Physics 2014-08-06 T. M. Radchenko , V. A. Tatarenko , I. Yu. Sagalianov , Yu. I. Prylutskyy

Nitrogen doping of the carbon is an important method to improve the performance and durability of catalysts for proton exchange membrane fuel cells by platinum-nitrogen and carbon-nitrogen bonds. This study shows that p-phenyl groups and…

Recent experimental findings and theoretical predictions suggest that nitrogen-doped CVD-grown graphene may give rise to electronic band gaps due to impurity distributions which favour segregation on a single sublattice. Here we demonstrate…

Mesoscale and Nanoscale Physics · Physics 2016-02-09 Thomas Aktor , Antti-Pekka Jauho , Stephen R. Power

The doping of graphene to tune its electronic structure is essential for its further use in carbon based electronics. Adapting strategies from classical silicon based semiconductor technology, we use the incorporation of heteroatoms in the…

Graphene is an ideal platform to study many-body effects due to its semimetallic character and the possibility to dope it over a wide range. Here we study the width of graphene's occupied $\pi$-band as a function of doping using…

Strongly Correlated Electrons · Physics 2016-08-10 Søren Ulstrup , Malte Schüler , Marco Bianchi , Felix Fromm , Christian Raidel , Thomas Seyller , Tim Wehling , Philip Hofmann

Graphene, being one-atom thick, is extremely sensitive to the presence of adsorbed atoms and molecules and, more generally, to defects such as vacancies, holes and/or substitutional dopants. This property, apart from being directly usable…

Materials Science · Physics 2011-04-08 Rocco Martinazzo , Simone Casolo , Gian Franco Tantardini

We simulate the optical and electrical responses in gallium-doped graphene. Using density functional theory with a local density approximation, we simlutate the electronic band structure and show the effects of impurity doping (0-3.91\%) in…

Transport measurements have revealed several exotic electronic properties of graphene. The possibility to influence the electronic structure and hence control the conductivity by adsorption or doping with adatoms is crucial in view of…

Polyyne, a sp1-hybridized linear allotrope of carbon, has a tunable quasiparticle energy gap, which depends on the terminated chemical ending groups as well as the chain length. Previously, nitrogen doping was utilized to tailor the…

Materials Science · Physics 2022-11-15 Kan Zhang , Jiling Li , Peitao Liu , Guowei Yang , Lei Shi

We have combined DFT calculations with the Boltzmann semiclassical transport theory to investigate the effect of selective hydrogenation on the thermoelectric properties of tetra-penta-deca-hexagonal graphene (TPDH-gr), a recently proposed…

In monolayer graphene, substitutional doping during growth can be used to alter its electronic properties. We used scanning tunneling microscopy (STM), Raman spectroscopy, x-ray spectroscopy, and first principles calculations to…