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The mobility of lighter species on the surface of interstellar dust grains plays a crucial role in forming simple through complex molecules. Carbon monoxide is one of the most abundant molecules, its surface diffusion on the grain surface…

Astrophysics of Galaxies · Physics 2022-03-30 Kinsuk Acharyya

Water is the main component of interstellar ice mantles, is abundant in the solar system and is a crucial ingredient for life. The formation of this molecule in the interstellar medium cannot be explained by gas-phase chemistry only and its…

Solar and Stellar Astrophysics · Physics 2017-08-23 S. Ioppolo , H. M. Cuppen , C. Romanzin , E. F. van Dishoeck , H. Linnartz

Astrochemistry is a well-established multidisciplinary field devoted to study molecules in space. While most astrochemists are oriented to observe molecules in the gas phase and reproduce their abundances by modeling the physical conditions…

Astrophysics of Galaxies · Physics 2025-12-10 Guillermo M. Muñoz Caro , Héctor Carrascosa de Lucas , Rafael Martín-Doménech

In the interstellar medium (ISM), the formation of complex organic molecules (COMs) is largely facilitated by surface reactions. However, in cold dark clouds, thermal desorption of COMs is inefficient because of the lack of thermal energy…

Astrophysics of Galaxies · Physics 2022-09-07 Alec Paulive , Joshua T. Carder , Eric Herbst

Networks of reactions on dust grain surfaces play a crucial role in the chemistry of interstellar clouds, leading to the formation of molecular hydrogen in diffuse clouds as well as various organic molecules in dense molecular clouds. Due…

Astrophysics · Physics 2010-11-05 B. Barzel , O. Biham

We model the intensity of emission lines from the CO molecule, based on hydrodynamic simulations of spirals, mergers, and high-redshift galaxies with very high resolutions (3pc and 10^3 Msun) and detailed models for the phase-space…

Astrophysics of Galaxies · Physics 2015-02-25 F. Bournaud , E. Daddi , A. Weiss , F. Renaud , C. Mastropietro , R. Teyssier

Carbon ($^3$P) atom is a reactive species that, according to laboratory experiments and theoretical calculations, condensates with interstellar ice components. This fact is of uttermost importance for the chemistry in the interstellar…

Astrophysics of Galaxies · Physics 2023-07-19 Stefano Ferrero , Cecilia Ceccarelli , Piero Ugliengo , Mariona Sodupe , Albert Rimola

To correctly model the abundances of interstellar complex organic molecules (iCOMS) in different environments, both formation and destruction routes should be appropriately accounted for. While several scenarios have been explored for the…

Solar and Stellar Astrophysics · Physics 2019-05-15 Daniela Ascenzi , Andrea Cernuto , Nadia Balucani , Paolo Tosi , Cecilia Ceccarelli , Luca Matteo Martini , Fernando Pirani

Despite its potential reactivity due to ring strain, ethylene oxide (c-C2H4O) is a complex molecule that seems to be stable under the physical conditions of an interstellar dense core; indeed it has been detected towards several high-mass…

Astrophysics of Galaxies · Physics 2015-06-11 A. Occhiogrosso , S. Viti , M. D. Ward , S. D. Price

Freeze-out of the gas phase elements onto cold grains in dense interstellar and circumstellar media builds up ice mantles consisting of molecules that are mostly formed in situ (H2O, NH3, CO2, CO, CH3OH, and more). This review summarizes…

Astrophysics of Galaxies · Physics 2015-09-23 Adwin Boogert , Perry Gerakines , Douglas Whittet

In order to understand how molecular clouds form in the Galactic interstellar medium, we would like to be able to map the structure and kinematics of the gas flows responsible for forming them. However, doing so is observationally…

Astrophysics of Galaxies · Physics 2016-06-01 Simon C. O. Glover , Paul C. Clark

We present simulations of star forming filaments incorporating on of the largest chemical network used to date on-the-fly in a 3D-MHD simulation. The network contains 37 chemical species and about 300 selected reaction rates. For this we…

Astrophysics of Galaxies · Physics 2016-03-23 D. Seifried , S. Walch

In the Milky Way and other main-sequence galaxies, stars form exclusively in molecular gas, which is traced by CO emission. However, low metallicity dwarf galaxies are often `CO-dark' in the sense that CO emission is not observable even at…

On galactic scales, the surface density of star formation appears to be well correlated with the surface density of molecular gas. This has lead many authors to suggest that there exists a causal relationship between the chemical state of…

Astrophysics of Galaxies · Physics 2015-05-28 S. C. O. Glover , P. C. Clark

Nearby dwarf irregular galaxies are ideal laboratories for studying the interstellar medium (ISM) at low metallicity, which is expected to be common for galaxies at very high redshift being observed by the James Webb Space Telescope. We…

Astrophysics of Galaxies · Physics 2023-08-02 Chia-Yu Hu , Amiel Sternberg , Ewine F. van Dishoeck

This review paper summarizes the state-of-the-art in laboratory based interstellar ice chemistry. The focus is on atom addition reactions, illustrating how water, carbon dioxide and methanol can form in the solid state at astronomically…

Astrophysics of Galaxies · Physics 2015-07-13 Harold Linnartz , Sergio Ioppolo , Gleb Fedoseev

Massive young stellar objects in the Magellanic Clouds show infrared absorption features corresponding to significant abundances of CO, CO$_2$ and H$_2$O ice along the line of sight, with the relative abundances of these ices differing…

Astrophysics of Galaxies · Physics 2018-02-21 Tyler Pauly , R. T. Garrod

Recent astronomical observations have shown that interstellar complex organic molecules (COMs) exist even in cold environments ($\sim$10 K), while various interstellar COMs have conventionally been detected in the hot gas ($\gtrsim$ 100 K)…

Astrophysics of Galaxies · Physics 2023-08-11 Yu Komatsu , Kenji Furuya

Syn-glycolamide, a glycine isomer, has recently been detected in the G+0.693-0.027 molecular cloud. Investigations on its formation in the interstellar medium could offer insights into synthetic routes leading to glycine in prebiotic…

Astrophysics of Galaxies · Physics 2025-04-25 Jessica Perrero , Silvia Alessandrini , Hexu Ye , Cristina Puzzarini , Albert Rimola

We have performed experimental investigations of methanol formation via the reactions of low energy $CH_{3}^{+}$ ions with an amorphous solid water (ASW) surface around 10 K. A newly developed experimental apparatus enabled irradiation of…

Astrophysics of Galaxies · Physics 2023-04-27 Y. Nakai , W. M. C. Sameera , K. Furuya , H. Hidaka , A. Ishibashi , N. Watanabe