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Related papers: Formation of COMs through CO hydrogenation on inte…

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Methanol and its precursor formaldehyde are among the most studied organic molecules in the interstellar medium and are abundant in the gaseous and solid phases. We recently developed a model to simulate CO hydrogenation via H atoms on…

Astrophysics of Galaxies · Physics 2015-05-14 H. M. Cuppen , E. F. van Dishoeck , E. Herbst , A. G. G. M. Tielens

This study focuses on the formation of two molecules of astrobiological importance - glycolaldehyde (HC(O)CH2OH) and ethylene glycol (H2C(OH)CH2OH) - by surface hydrogenation of CO molecules. Our experiments aim at simulating the CO…

Astrophysics of Galaxies · Physics 2017-05-26 Gleb Fedoseev , Herma M. Cuppen , Sergio Ioppolo , Thanja Lamberts , Harold Linnartz

Observational studies reveal that complex organic molecules (COMs) can be found in various objects associated with different star formation stages. The identification of COMs in prestellar cores, i.e., cold environments in which thermally…

Solar and Stellar Astrophysics · Physics 2017-06-28 Gleb Fedoseev , Ko-Ju Chuang , Sergio Ioppolo , Danna Qasim , Ewine F. van Dishoeck , Harold Linnartz

Complex organic molecules (COMs) have been observed in comets, hot cores and cold dense regions of the interstellar medium. It is generally accepted that these COMs form on icy dust grain through the recombination reaction of radicals…

Solar and Stellar Astrophysics · Physics 2018-09-12 K. -J. Chuang

A prevailing theory for the interstellar production of complex organic molecules (COMs) involves formation on warm dust-grain surfaces, via the diffusion and reaction of radicals produced through grain-surface photodissociation of stable…

Astrophysics of Galaxies · Physics 2020-08-19 Mihwa Jin , Robin T. Garrod

Hydrogenation reactions of CO in inter- and circumstellar ices are regarded as an important starting point in the formation of more complex species. Previous laboratory measurements by two groups on the hydrogenation of CO ices resulted in…

Solar and Stellar Astrophysics · Physics 2009-06-15 G. W. Fuchs , H. M. Cuppen , S. Ioppolo , C. Romanzin , S. E. Bisschop , S. Andersson , E. F. van Dishoeck , H. Linnartz

Complex organic molecules (COMs) have been observed not only in the hot cores surrounding low- and high- mass protostars, but also in cold dark clouds. Therefore, it is interesting to understand how such species can be formed without the…

Astrophysics of Galaxies · Physics 2016-06-06 K. -J. Chuang , G. Fedoseev , S. Ioppolo , E. F. van Dishoeck , H. Linnartz

Icy interstellar dust grains are a source of complex organic molecule (COM) production, although their formation mechanisms are debated. Laboratory experiments show that atomic C deposited onto interstellar ice analogs can react with…

Astrophysics of Galaxies · Physics 2025-10-27 Sydney A. Willis , Serge A. Krasnokutski , Nathaniel J. Morin , Robin T. Garrod

Simple and complex organic molecules (COMs) are observed along different phases of star and planet formation and have been successfully identified in prestellar environments such as dark and translucent clouds. Yet the picture of organic…

We investigate the formation and evolution of interstellar dust-grain ices under dark-cloud conditions, with a particular emphasis on CO2. We use a three-phase model (gas/surface/mantle) to simulate the coupled gas--grain chemistry,…

Astrophysics of Galaxies · Physics 2015-05-28 Robin T. Garrod , Tyler Pauly

Complex organic molecules (COMs) have been identified in different environments in star- forming regions. Laboratory studies show that COMs form in the solid state, on icy grains, typically following a non-energetic (atom-addition) or…

Astrophysics of Galaxies · Physics 2017-05-23 K. -J. Chuang , G. Fedoseev , D. Qasim , S. Ioppolo , E. F. van Dishoeck , H. Linnartz

Ice chemistry in the dense, cold interstellar medium (ISM) is probably responsible for the formation of interstellar complex organic molecules (COMs). Recent laboratory experiments performed at T=4 K have shown that irradiation of CO:N2 ice…

Astrophysics of Galaxies · Physics 2024-01-09 Rafael Martín-Doménech , Alexander DelFranco , Karin I. Öberg , Mahesh Rajappan

Interstellar complex organic molecules (iCOMs) are assumed to be mainly formed on dust-grain surfaces. However, neutral gas-phase reactions in the interstellar medium (ISM) can play an important role. In this paper, by investigating the…

Astrophysics of Galaxies · Physics 2020-09-09 F. Tonolo , J. Lupi , C. Puzzarini , V. Barone

Complex organic molecules (COMs) have been identified toward high- and low-mass protostars as well as molecular clouds, suggesting that these interstellar species originate from the early stage(s) of starformation. The reaction pathways…

Solar and Stellar Astrophysics · Physics 2020-04-08 K. -J. Chuang , G. Fedoseev , D. Qasim , S. Ioppolo , C. Jäger , Th. Henning , M. E. Palumbo , E. F. van Dishoeck , H. Linnartz

Complex Organic Molecules (COMs) have been detected in the interstellar medium (ISM). However, it is not clear whether their synthesis occurs on the icy surfaces of interstellar grains or via a series of gas-phase reactions. As a test case…

Earth and Planetary Astrophysics · Physics 2016-03-31 Joan Enrique-Romero , Albert Rimola , Cecilia Ceccarelli , Nadia Balucani

Context. In dense clouds, hydrogenation reactions on icy dust grains are key in the formation of molecules, like formaldehyde, methanol, and complex organic molecules (COMs). These species form through the sequential hydrogenation of CO…

Solar and Stellar Astrophysics · Physics 2018-09-28 K. -J. Chuang , G. Fedoseev , D. Qasim , S. Ioppolo , E. F. van Dishoeck , H. Linnartz

In regions where stars form, variations in density and temperature can cause gas to freeze-out onto dust grains forming ice mantles, which influences the chemical composition of a cloud. The aim of this paper is to understand in detail the…

Solar and Stellar Astrophysics · Physics 2017-11-08 S. Cazaux , R. Martin-Domenech , Y. J. Chen , G. M. Munoz Caro , C. Gonzalez Diaz

Interstellar grains are known to be important actors in the formation of interstellar molecules such as H$_2$, water, ammonia, and methanol. It has been suggested that the so-called interstellar complex organic molecules (iCOMs) are also…

AIM: We have recently developed a microscopic Monte Carlo approach to study surface chemistry on interstellar grains and the morphology of ice mantles. The method is designed to eliminate the problems inherent in the rate-equation formalism…

Astrophysics · Physics 2009-11-13 Q. Chang , H. M. Cuppen , E. Herbst

A new, more comprehensive model of gas-grain chemistry in hot molecular cores is presented, in which nondiffusive reaction processes on dust-grain surfaces and in ice mantles are implemented alongside traditional diffusive surface/bulk-ice…

Astrophysics of Galaxies · Physics 2022-02-23 Robin T. Garrod , Mihwa Jin , Kayla A. Matis , Dylan Jones , Eric R. Willis , Eric Herbst
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