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Molecular dynamics simulations of water, liquid beryllium fluoride and silica melt are used to study the accuracy with which the entropy of ionic and molecular liquids can be estimated from atom-atom radial distribution function data. All…

Soft Condensed Matter · Physics 2009-11-13 Ruchi Sharma , Manish Agarwal , Charusita Chakravarty

We study nonequilibrium thermodynamic properties of a driven one-dimensional quantum fluid by combining nonlinear Luttinger liquid theory with the quantum kinetic equation. In particular, we derive an entropy production consistent with the…

Mesoscale and Nanoscale Physics · Physics 2019-10-09 Edvin G. Idrisov , Thomas L. Schmidt

Computer simulations have been employed in recent years to evaluate the configurational entropy changes in model glass-forming liquids. We consider two methods, both of which involve the calculation of the `intra-basin' entropy as a means…

Statistical Mechanics · Physics 2009-10-31 Srikanth Sastry

Analysis of three-particle correlations is performed on the basis of simulation data of atomic dynamics in liquid and amorphous aluminium. A three-particle correlation function is introduced to characterize the relative positions of various…

Statistical Mechanics · Physics 2017-04-05 Bulat N. Galimzyanov , Anatolii V. Mokshin

Many theoretical expressions of dissipation along non-equilibrium processes have been proposed. However, they have not been fully verified by experiments. Especially for systems strongly interacting with environments the connection between…

Statistical Mechanics · Physics 2019-12-03 Ketan Goyal , Xian He , Ryoichi Kawai

The length-scale dependence of the dynamic entropy is studied in a molecular dynamics simulation of a binary Lennard-Jones liquid above the mode-coupling critical temperature $T_c$. A number of methods exist for estimating the entropy of…

Soft Condensed Matter · Physics 2009-10-31 Paolo Allegrini , Jack F. Douglas , Sharon C. Glotzer

We build a comprehensive methodology for the fast computation of entropy across both solid and liquid phases. The proposed method utilizes a single trajectory of molecular dynamics (MD) to facilitate the calculation of entropy, which is…

Computational Physics · Physics 2024-04-05 Qi-Jun Hong , Zi-Kui Liu

The diffusion coefficient--a measure of dissipation, and the entropy--a measure of fluctuation are found to be intimately correlated in many physical systems. Unlike the fluctuation dissipation theorem in linear response theory, the…

Statistical Mechanics · Physics 2021-03-25 Yi Liao , Xiao-Bo Gong

We obtain the large scale limit of the fluctuations around its hydrodynamic limit of the density of particles of a weakly asymmetric exclusion process in dimension up to three. The proof is based upon a sharp estimate on the relative…

Probability · Mathematics 2018-10-24 Milton Jara , Otávio Menezes

Multi-particle collision dynamics is an appealing numerical technique aiming at simulating fluids at the mesoscopic scale. It considers molecular details in a coarse-grained fashion and reproduces hydrodynamic phenomena. Here, the…

Soft Condensed Matter · Physics 2019-03-28 H. Híjar

We use discontinuous molecular dynamics and grand-canonical transition-matrix Monte Carlo simulations to explore how confinement between parallel hard walls modifies the relationships between packing fraction, self-diffusivity, partial…

Soft Condensed Matter · Physics 2009-11-13 Jeetain Mittal , Vincent K. Shen , Jeffrey R. Errington , Thomas M. Truskett

The stochastic entropy generated during the evolution of a system interacting with an environment may be separated into three components, but only two of these have a non-negative mean. The third component of entropy production is…

Statistical Mechanics · Physics 2013-05-30 Ian J. Ford , Richard E. Spinney

Microscopic formula to describe the entropy of biomolecular solutions are derived based on the Gibbs formula of entropy, and the generalized Langevin theory combined with the RISM/3D-RISM theory. Two formula are derived: one is concerned…

Statistical Mechanics · Physics 2023-03-02 Fumio Hirata

Liquid state entropy formulas based on configurational probability distributions are examined for Lennard-Jones fluids across a range temperatures and densities. These formulas are based on expansions of the entropy in series of $n$-body…

Statistical Mechanics · Physics 2023-12-19 Yang Huang , Michael Widom

An algorithm for measurement of entropy in multiparticle systems, based on recently published proposal of the present authors, is given. Dependence on discretization of the system and effects of multiparticle correlations are discussed in…

High Energy Physics - Phenomenology · Physics 2007-05-23 A. Bialas , W. Czyz

We use video microscopy to follow the phase-space trajectory of a two-dimensional colloidal model liquid and calculate three-point correlation functions from the measured particle configurations. Approaching the fluid-solid transition by…

Soft Condensed Matter · Physics 2009-11-10 Klaus Zahn , Georg Maret , Carsten Russ , Hans Hennig von Grunberg

We derive a new formulation to calculate the excess chemical potential of a fraction of $N_1$ particles interacting with $N_2$ particles of a different species. The excess chemical potential is calculated numerically from first principles…

Astrophysics · Physics 2008-11-26 Christophe Winisdoerffer , Gilles Chabrier , Gilles Zérah

Liquid-state theory, computer simulation, and numerical optimization are used to investigate the extent to which positional correlations of a hard-sphere fluid--as characterized by the radial distribution function and the two-particle…

Soft Condensed Matter · Physics 2016-03-23 Ryan B. Jadrich , Beth A. Lindquist , Jonathan A. Bollinger , Thomas M. Truskett

In this paper we consider the three-particle density correlation function for a fractional quantum Hall liquid. The study of this object is motivated by recent experimental studies of fractional quantum Hall systems using inelastic light…

Mesoscale and Nanoscale Physics · Physics 2009-10-31 M. Brownlie , Keith A. Benedict

Understanding active matter has led to new perspectives on biophysics and non-equilibrium dynamics. However, the development of numerical tools for simulating active fluids capable of incorporating non-trivial boundaries or inclusions has…

Soft Condensed Matter · Physics 2024-02-01 Timofey Kozhukhov , Benjamin Loewe , Tyler N. Shendruk
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