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We consider different Linear Combination of Unitaries (LCU) decompositions for molecular electronic structure Hamiltonians. Using these LCU decompositions for Hamiltonian simulation on a quantum computer, the main figure of merit is the…

Quantum Physics · Physics 2023-06-13 Ignacio Loaiza , Alireza Marefat Khah , Nathan Wiebe , Artur F. Izmaylov

One of the most used approaches in simulating materials is the tight-binding approximation. When using this method in a material simulation, it is necessary to compute the eigenvalues and eigenvectors of the Hamiltonian describing the…

Numerical Analysis · Computer Science 2009-10-29 Matthias Petschow , Edoardo Di Napoli , Paolo Bientinesi

We obtain tight upper and lower bounds to the eigenvalues of an anharmonic oscillator with a rational potential. We compare our bounds with results given by other approaches.

Mathematical Physics · Physics 2008-04-18 Francisco M. Fernandez

The aim of the paper is to introduce a new systematic method that can produce lower bounds for eigenvalues. The main idea is to use nonconforming finite element methods. The general conclusion herein is that if local approximation…

Numerical Analysis · Mathematics 2013-04-22 Jun Hu , Yunqing Huang , Qun Lin

We calculate the exceptional points of the eigenvalues of several parameter-dependent Hamiltonian operators of mathematical and physical interest. We show that the calculation is greatly facilitated by the application of the discriminant to…

Quantum Physics · Physics 2019-11-26 Paolo Amore , Francisco M. Fernández

We prove upper and lower bounds for the number of eigenvalues of semi-bounded Schr\"odinger operators in all spatial dimensions. As a corollary, we obtain two-sided estimates for the sum of the negative eigenvalues of atomic Hamiltonians…

Mathematical Physics · Physics 2024-09-16 Sven Bachmann , Richard Froese , Severin Schraven

We introduce variational methods for finding approximate eigenfunctions and eigenvalues of quantum Hamiltonians by constructing a set of orthogonal wave functions which approximately solve the eigenvalue equation.

Mathematical Physics · Physics 2013-07-16 Farrokh Atai , Jens Hoppe , Mariusz Hynek , Edwin Langmann

The so-called equation of motion method is useful to obtain the explicit form of the eigenvectors and eigenvalues of certain non self-adjoint bosonic Hamiltonians with real eigenvalues. These operators can be diagonalized when they are…

Quantum Physics · Physics 2015-09-03 Natalia Bebiano , Joao da Providencia , Joao P. da Providencia

The convergence of the so-called quadratic method for computing eigenvalue enclosures of general self-adjoint operators is examined. Explicit asymptotic bounds for convergence to isolated eigenvalues are found. These bounds turn out to…

Numerical Analysis · Mathematics 2016-11-26 Lyonell Boulton , Aatef Hobiny

We apply the notion of asymptotic iteration method (AIM) to determine eigenvalues of the bosonic Hamiltonians that include a wide class of quantum optical models. We consider solutions of the Hamiltonians, which are even polynomials of the…

Mathematical Physics · Physics 2010-09-02 Ramazan Koc , Hayriye Tutunculer , Eser Olgar

We develop a method to determine the eigenvalues and eigenfunctions of two-boson Hamiltonians include a wide class of quantum optical models. The quantum Hamiltonians have been transformed in the form of the one variable differential…

Quantum Physics · Physics 2007-05-23 Ramazan Koc , Hayriye Tutunculer , Eser Olgar

Some monotone increasing sequences of the lower bounds for the minimum eigenvalue of $M$-matrices are given. It is proved that these sequences are convergent and improve some existing results. Numerical examples show that these sequences…

Numerical Analysis · Mathematics 2017-04-19 Jianxing Zhao , Caili Sang

In this paper, we prove that the Morley element eigenvalues approximate the exact ones from below on regular meshes, including adaptive local refined meshes, for the fourth-order elliptic eigenvalue problems with the clamped boundary…

Numerical Analysis · Mathematics 2015-09-03 Yidu Yang , Hao Li , Hai Bi

In this paper, we give some lower bounds for several eigenvalues. Firstly, we investigate the eigenvalues $\lambda_i$ of the Laplace operator and prove a sharp lower bound. Moreover, we extent this estimate of the eigenvalues to general…

Differential Geometry · Mathematics 2020-11-26 Zhengchao Ji , Hongwei Xu

In this paper, we study eigenvalues of a clamped plate problem. We obtain a lower bound for eigenvalues, which gives an important improvement of results due to Levine and Protter.

Differential Geometry · Mathematics 2009-08-27 Qing-Ming Cheng , Guoxin Wei

This article is devoted to the spectral analysis of the electro-magnetic Schr\"odinger operator on the Euclidean plane. In the semiclassical limit, we derive a pseudo-differential effective operator that allows us to describe the spectrum…

Spectral Theory · Mathematics 2022-01-26 Léo Morin , Nicolas Raymond , San Vu Ngoc

We consider the task of approximating the ground state energy of two-local quantum Hamiltonians on bounded-degree graphs. Most existing algorithms optimize the energy over the set of product states. Here we describe a family of shallow…

Quantum Physics · Physics 2022-01-05 Anurag Anshu , David Gosset , Karen J. Morenz Korol , Mehdi Soleimanifar

The expectation value of the Hamiltonian using a model wave function is widely used to estimate the eigenvalues of electronic Hamiltonians. We explore here a modified formula for models based on long-range interaction. It scales differently…

Chemical Physics · Physics 2024-06-13 Anthony Scemama , Andreas Savin

We use Salem's method to prove that there is a lower bound for partial sums of series of bi-orthogonal vectors in a Hilbert space, or the dual vectors. This is applied to some lower bounds on $L^{1}$ norms for orthogonal expansions. There…

Classical Analysis and ODEs · Mathematics 2009-03-02 Christopher Meaney

An analytical approximation for the eigenvalues of $\mathcal{PT}$ symmetric Hamiltonian $\mathsf{H} = -d^{2}/dx^{2} - (\mathrm{i}x)^{\epsilon+2}$, $\epsilon > -1$ is developed via simple basis sets of harmonic-oscillator wave functions with…

Quantum Physics · Physics 2017-11-08 O. D. Skoromnik , I. D. Feranchuk