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Hot carriers produced from the decay of localized surface plasmons in metallic nanoparticles are intensely studied because of their optoelectronic, photovoltaic and photocatalytic applications. From a classical perspective, plasmons are…

Mesoscale and Nanoscale Physics · Physics 2019-04-09 Lara Román Castellanos , Ortwin Hess , Johannes Lischner

Evolution of the nonequilibrium carriers excited in the process of decay of surface plasmon polaritons in metal is described for each step, from the carrier generation to their extraction from the metal. The relative importance of various…

Optics · Physics 2020-10-22 Jacob B Khurgin

Recent experiments claimed that the enhancement of catalytic reaction rates occurs via the reduction of activation barriers driven by non-equilibrium (``hot'') electrons in plasmonic metal nanoparticles. These experiments place plasmonic…

Chemical Physics · Physics 2020-04-22 Yonatan Sivan , Ieng Wai Un , Yonatan Dubi

Metal nanoparticles are attractive for plasmon-enhanced generation of hot carriers, which may be harnessed in photochemical reactions. In this work, we analyze the coherent femtosecond dynamics of photon absorption, plasmon formation, and…

Mesoscale and Nanoscale Physics · Physics 2021-01-14 Tuomas P. Rossi , Paul Erhart , Mikael Kuisma

Light absorption and scattering of plasmonic metal nanoparticles can lead to non-equilibrium charge carriers, intense electromagnetic near-fields, and heat generation, with promising applications in a vast range of fields, from chemical and…

Optics · Physics 2020-08-27 Guillaume Baffou , Ivan Bordacchini , Andrea Baldi , Romain Quidant

It has been known for many years that metallic nanoparticles can catalyse various chemical reactions, both in the dark and under illumination, through different mechanisms. In the last decade or so, many claims of plasmon-assisted "hot"…

Optics · Physics 2020-11-13 Yonatan Sivan , Yonatan Dubi

Understanding the interplay between illumination and the electron distribution in metallic nanostructures is a crucial step towards developing applications such as plasmonic photo-catalysis for green fuels, nano-scale photo-detection and…

Optics · Physics 2019-07-23 Yonatan Dubi , Yonatan Sivan

Metal nanoparticles are excellent light absorbers. The absorption processes create highly excited electron-hole pairs and recently there has been interest in harnessing these hot charge carriers for photocatalysis and solar energy…

Mesoscale and Nanoscale Physics · Physics 2017-06-13 Gregory V. Hartland , Lucas V. Besteiro , Paul Johns , Alexander O. Govorov

Understanding the intricate relation between illumination and temperature in metallic nano-particles is crucial for elucidating the role of illumination in various physical processes which rely on plasmonic enhancement but are also…

Chemical Physics · Physics 2023-03-31 Ieng-Wai Un , Yonatan Dubi , Yonatan Sivan

The use of nanoplasmonics to control light and heat close to the thermodynamic limit enables exciting opportunities in the field of plasmonic catalysis. The decay of plasmonic excitations creates highly nonequilibrium distributions of hot…

Hot electrons generated from the decay of localized surface plasmons in metallic nanostructures have the potential to transform photocatalysis, photodetection and other optoelectronic applications. However, the understanding of hot-carrier…

Hot electrons and holes generated from the decay of localized surface plasmons (LSPs) in aluminum nanostructures have significant potential for applications in photocatalysis, photodetection and other optoelectronic devices. Here, we…

Optics · Physics 2025-11-03 Gengyue Dong , Simão João , Hanwen Jin , Johannes Lischner

The coherent oscillations of mobile charge carriers near the surface of good conductors-surface plasmons-are been exploited in many applications in information technologies, clean energy, high-density data storage, photovoltaics, chemistry,…

Mesoscale and Nanoscale Physics · Physics 2023-12-20 Jacob Khurgin , Anton Yu. Bykov , Anatoly V. Zayats

The damping of surface plasmons generates hot carriers, which holds promise for photoelectric conversion and photocatalysis. Recent studies have revealed the nonequilibrium characters of the plasmonic hot carriers and their nonadiabatic…

Materials Science · Physics 2025-07-10 Yu Chen , Shengxiang Wu , Shiwu Gao

Recently, there has been significant interest in harnessing hot carriers generated from the decay of localized surface plasmons in metallic nanoparticles for applications in photocatalysis, photovoltaics and sensing. In this work, we…

Materials Science · Physics 2023-08-09 S. M. João , Hanwen Jin , Johannes Lischner

While direct hot-carrier transfer can increase photo-catalytic activity, it is difficult to discern experimentally and competes with several other mechanisms. To shed light on these aspects, here, we model from first principles hot-carrier…

Mesoscale and Nanoscale Physics · Physics 2023-11-20 Jakub Fojt , Tuomas P Rossi , Paul Erhart

Our Comment [Sivan et al., Science 2019] (as well as its longer version [Dubi, Un, & Sivan, ArXiv 2019], and the supporting theoretical studies [Dubi and Sivan, ArXiv 2018]) on recent attempts to distinguish thermal and non-thermal ("hot…

Chemical Physics · Physics 2019-07-11 Yonatan Sivan , Joshua Baraban , Yonatan Dubi

Understanding and controlling properties of plasmon-induced hot carriers is a key step towards next-generation photovoltaic and photocatalytic devices. Here, we uncover a route to engineering hot-carrier generation rates of silver…

Materials Science · Physics 2021-01-26 Lara Román Castellanos , Ortwin Hess , Johannes Lischner

Metallic nanoparticles have been used as catalysts for various reactions, and the huge literature on the subject is hard to overlook. In many applications, the nanoparticles must be affixed to a colloidal carrier for easy handling during…

In this letter, we address the thermal processes occurring in plasmonic nanoparticles. We determine constrains imposed upon the plasmonic excitation in such nanoparticle by the resulting heat generation. Taking into account temperature…

Mesoscale and Nanoscale Physics · Physics 2013-08-06 I. A. Fyodorov , V. M. Parfenyev , G. T. Tartakovsky , S. S. Vergeles , A. K. Sarychev
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