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Several chemical reactions catalyzed by plasmonic nanoparticles show enhanced rates under visible-light-excitation of the localized surface plasmon resonance of the nanoparticles. But it has been argued that there is an associated…

Chemical Physics · Physics 2019-10-11 Prashant K. Jain

Recently, there has been a growing interest in the usage of mm-scale composites of plasmonic nanoparticles for enhancing the rates of chemical reactions; the effect was shown recently to be predominantly associated with the elevated…

Applied Physics · Physics 2023-03-31 Ieng-Wai Un , Yonatan Sivan

Nanoscale localization of electromagnetic fields near metallic nanostructures underpins the fundamentals and applications of plasmonics. The unavoidable energy loss from plasmon decay, initially seen as a detriment, has now expanded the…

Generation of energetic (hot) electrons is an intrinsic property of any plasmonic nanostructure under illumination. Simultaneously, a striking advantage of metal nanocrystals over semiconductors lies in their very large absorption cross…

Mesoscale and Nanoscale Physics · Physics 2017-08-31 Lucas V. Besteiro , Xiang-Tian Kong , Zhiming Wang , Gregory V. Hartland , Alexander O. Govorov

Harnessing hot electrons and holes resulting from the decay of localized surface plasmons in nanomaterials has recently led to new devices for photovoltaics, photocatalysis and optoelectronics. Properties of hot carriers are highly tunable…

Materials Science · Physics 2018-02-15 Stefano Dal Forno , Luigi Ranno , Johannes Lischner

When plasmonic nanoparticles are coupled with semiconductors, highly energetic hot carriers can be extracted from the metal-semiconductor interface for various applications in light energy conversion. Hot charge-carrier extraction upon…

We report a numerical investigation on the heat transfer through one dimensional arrays of metallic nanoparticles closely spaced in a host material. Our simulations show that the multipolar interactions play a crucial role in the heat…

Mesoscale and Nanoscale Physics · Physics 2009-11-13 Philippe Ben-Abdallah , Karl Joulain , Jérémie Drevillon , Clément Le Goff

Localized plasmons formed in ultrathin metallic nanogaps can lead to robust absorption of incident light. Plasmonic metasurfaces based on this effect can efficiently generate energetic charge carriers, also known as hot electrons, owing to…

Optics · Physics 2022-09-28 Larousse Khosravi Khorashad , Christos Argyropoulos

Plasmonic absorption of light can lead to significant local heating in metallic nanostructures, an effect that defines the sub-field of thermoplasmonics and has been leveraged in diverse applications from biomedical technology to…

Mesoscale and Nanoscale Physics · Physics 2014-02-21 Joseph B. Herzog , Mark W. Knight , Douglas Natelson

Above-threshold light emission from plasmonic tunnel junctions, when emitted photons have energies significantly higher than the energy scale of the incident electrons, has attracted much recent interest in nano-optics, while the underlying…

Mesoscale and Nanoscale Physics · Physics 2020-12-08 Longji Cui , Yunxuan Zhu , Mahdiyeh Abbasi , Arash Ahmadivand , Burak Gerislioglu , Peter Nordlander , Douglas Natelson

Hot charge carrier extraction from metallic nanostructures is a very promising approach for applications in photo-catalysis, photovoltaics and photodetection. One limitation is that many metallic nanostructures support a single plasmon…

A physically transparent unified theory of optically and plasmon induced hot carrier generation in metals is developed with all the relevant mechanisms included. Analytical expressions that estimate the carrier generation rates, their…

Optics · Physics 2019-06-19 Jacob B Khurgin

The heating of particles by plasma radiation plays a critical role in space science involving dusty plasma as well as in industrial processes such as plasma vapor deposition, microchip production, etching and plasma fusion. Numerical…

Plasma Physics · Physics 2025-09-09 A. Povitsky , M. N. Shneider

Sintering refers to particle coalescence by heat, which has been known as a thermal phenomenon involving all aspects of natural science for centuries. It is particularly important in heterogeneous catalysis because normally sintering…

Alloyed metal nanoparticles are a promising platform for plasmonically enabled hot-carrier generation, which can be used to drive photochemical reactions. Although the non-plasmonic component in these systems has been investigated for its…

Mesoscale and Nanoscale Physics · Physics 2024-08-15 Jakub Fojt , Tuomas P. Rossi , Priyank V. Kumar , Paul Erhart

In numerous applications of energy harvesting via transformation of light into heat the focus recently shifted towards highly absorptive materials featuring nanoplasmons. It is currently established that noble metals-based absorptive…

The transport of energy in heated plasmas requires the knowledge of the radiation coefficients. These coefficients consist of contribution of bremsstrahlung, photoionisation, bound-bound transmissions and scattering. Scattering of photons…

Plasma Physics · Physics 2010-12-20 J. Fiedler

A range of chemical reactions occurring on the surfaces of metal nanoparticles exhibit enhanced rates under plasmonic excitation. Recent analyses based on Arrhenius law fitting have argued in favor of a purely photothermal mechanism of…

Chemical Physics · Physics 2020-06-11 Prashant K. Jain

In plasmonics, and particularly in plasmonic photochemistry, the effect of hot-electron generation is an exciting phenomenon driving new fundamental and applied research. However, obtaining a microscopic description of the hot-electron…

Plasmonic excitations decay within femtoseconds, leaving non-thermal (often referred to as "hot") charge carriers behind that can be injected into molecular structures to trigger chemical reactions that are otherwise out of reach -- a…

Materials Science · Physics 2025-01-28 Jakub Fojt , Paul Erhart , Christian Schäfer