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We derive analytical expressions for chemical potentials within the random phase approximation (RPA), equivalently the $GW$ energy functional evaluated using non interacting Green's functions ($G_s$). The chemical potential is obtained…

Chemical Physics · Physics 2026-03-20 Jiachen Li , Weitao Yang

GW calculations with fully self-consistent G and W -- based on the iterative solution of the Dyson equation -- provide an approach for consistently describing ground and excited states on the same quantum mechanical level. We show that for…

Materials Science · Physics 2012-09-27 Fabio Caruso , Patrick Rinke , Xinguo Ren , Matthias Scheffler , Angel Rubio

We present a diagrammatic approach to construct self-energy approximations within many-body perturbation theory with positive spectral properties. The method cures the problem of negative spectral functions which arises from a…

Other Condensed Matter · Physics 2015-06-22 G. Stefanucci , Y. Pavlyukh , A. -M. Uimonen , R. van Leeuwen

The GW method is a many-body electronic structure technique capable of generating accurate quasiparticle properties for realistic systems spanning physics, chemistry, and materials science. Despite its power, GW is not routinely applied to…

Computational Physics · Physics 2020-02-19 Minjung Kim , Glenn J. Martyna , Sohrab Ismail-Beigi

Finite-temperature quantum field theories are formulated in terms of Green's functions and self-energies on the Matsubara axis. In multi-orbital systems, these quantities are related to positive semidefinite matrix-valued functions of the…

Strongly Correlated Electrons · Physics 2021-10-13 Jiani Fei , Chia-Nan Yeh , Dominika Zgid , Emanuel Gull

Analytical continuation is a central step in the simulation of finite-temperature field theories in which numerically obtained Matsubara data is continued to the real frequency axis for physical interpretation. Numerical analytic…

Strongly Correlated Electrons · Physics 2024-10-21 Lei Zhang , Emanuel Gull

We present a numerical integration scheme for evaluating the convolution of a Green's function with a screened Coulomb potential on the real axis in the GW approximation of the self energy. Our scheme takes the zero broadening limit in…

We present a new algorithm to analytically continue the self-energy of quantum many-body systems from Matsubara frequencies to the real axis. The method allows straightforward, unambiguous computation of electronic spectra for lattice…

Strongly Correlated Electrons · Physics 2015-06-18 Peter Staar , Bart Ydens , Anton Kozhevnikov , Jean-Pierre Locquet , Thomas Schulthess

We derive formulas for the Coulomb matrix within the full-potential linearized augmented-plane-wave (FLAPW) method. The Coulomb matrix is a central ingredient in implementations of many-body perturbation theory, such as the Hartree-Fock and…

Materials Science · Physics 2010-03-01 Christoph Friedrich , Arno Schindlmayr , Stefan Bluegel

We explore the combination of the extended dynamical mean field theory (EDMFT) with the GW approximation (GWA); the former sums the local contributions to the self-energies to infinite order in closed form and the latter handles the…

Strongly Correlated Electrons · Physics 2009-11-10 Ping Sun , Gabriel Kotliar

In the probabilistic approach to quantum many-body systems, the ground-state energy is the solution of a nonlinear scalar equation written either as a cumulant expansion or as an expectation with respect to a probability distribution of the…

Statistical Mechanics · Physics 2013-04-04 Andrea Di Stefano , Massimo Ostilli , Carlo Presilla

In many-body perturbation theory (MBPT) the self-energy \Sigma=iGW\Gamma plays the key role since it contains all the many body effects of the system. The exact self-energy is not known; as first approximation one can set the vertex…

Strongly Correlated Electrons · Physics 2012-04-23 Pina Romaniello , Friedhelm Bechstedt , Lucia Reining

We propose an approach for the ab initio calculation of materials with strong electronic correlations which is based on all local (fully irreducible) vertex corrections beyond the bare Coulomb interaction. It includes the so-called GW and…

Strongly Correlated Electrons · Physics 2015-03-19 A. Toschi , G. Rohringer , A. A. Katanin , K. Held

The GW approximation represents the state-of-the-art ab-initio method for computing excited-state properties. Its execution requires control over a larger number of (often interdependent) parameters, and therefore its application in…

Calculations of excited states in Green's function formalism often invoke the diagonal approximation, in which the quasiparticle states are taken from a mean-field calculation. Here, we extend the stochastic approaches applied in the…

Computational Physics · Physics 2023-09-28 Annabelle Canestraight , Xiaohe Lei , Khaled Ibrahim , Vojtech Vlcek

The accuracy of the many-body perturbation theory GW formalism to calculate electron-phonon coupling matrix elements has been recently demonstrated in the case of a few important systems. However, the related computational costs are high…

Computational Physics · Physics 2015-06-23 C. Faber , P. Boulanger , C. Attaccalite , E. Cannuccia , I. Duchemin , T. Deutsch , X. Blase

In this work we study qualitative properties of real analytic bounded maps. The main tool is approximation of real valued functions analytic in rectangular domains of the complex plane by continued g-fractions of Wall. As an application,…

Dynamical Systems · Mathematics 2018-08-21 Alexei Tsygvintsev

The many-body $GW$ formalism, for the calculation of ionization potentials or electronic affinities, relies on the frequency-dependent dielectric function built from the electronic degrees of freedom. Considering the case of water as a…

Materials Science · Physics 2024-09-04 Ivan Duchemin , David Amblard , Xavier Blase

Holomorphic functions are amazing because their values in an ever so small disk in the complex plane completely determine the function values at arbitrary points in their maximum possible domain. The process of extending such a function…

Complex Variables · Mathematics 2015-05-15 Stefan Kranich

Over the years, Hedin's $GW$ self-energy has been proven to be a rather accurate and simple approximation to evaluate electronic quasiparticle energies in solids and in molecules. Attempts to improve over the simple $GW$ approximation, the…

Computational Physics · Physics 2024-01-24 Fabien Bruneval , Arno Förster