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We investigate the performance of the GW approximation by comparison to exact results for small model systems. The role of the chemical potentials in Dyson's equation as well as the consequences of numerical resonance broadening are…

Materials Science · Physics 2007-05-23 Thomas J. Pollehn , Arno Schindlmayr , R. W. Godby

We present two new developments for computing excited state energies within the $GW$ approximation. First, calculations of the Green's function and the screened Coulomb interaction are decomposed into two parts: one is deterministic while…

Computational Physics · Physics 2020-10-28 Mariya Romanova , Vojtěch Vlček

We have implemented the so called GW approximation (GWA) based on an all-electron full-potential Projector Augmented Wave (PAW) method. For the screening of the Coulomb interaction W we tested three different plasmon-pole dielectric…

Materials Science · Physics 2007-05-23 B. Arnaud , M. Alouani

We introduce an alternative route to quasiparticle self-consistent $GW$ calculations ($\mathrm{qs}GW$) on the basis of a Joint Approximate Diagonalization of the one-body $GW$ Green's functions $G(\varepsilon_n^{QP})$ taken at the input…

Materials Science · Physics 2024-12-05 Ivan Duchemin , Xavier Blase

We develop a unified spectral-semigroup framework that connects real-time and imaginary-time quantum dynamics through analytic continuation. Within this formulation, evolution is expressed as an exponential reweighting of spectral…

Applied Physics · Physics 2026-05-12 Pengfei Zhu

We propose a novel approach to quasiparticle GW calculations which does not require the computation of unoccupied electronic states. In our approach the screened Coulomb interaction is evaluated by solving self-consistent linear-response…

Materials Science · Physics 2015-05-14 Feliciano Giustino , Marvin L. Cohen , Steven G. Louie

We present GW calculations of molecules, ordered and disordered solids and interfaces, which employ an efficient contour deformation technique for frequency integration, and do not require the explicit evaluation of virtual electronic…

Materials Science · Physics 2015-01-14 Marco Govoni , Giulia Galli

Complex Gaussian basis sets are optimized to accurately represent continuum radial wavefunctions over the whole space. First, attention is put on the technical ability of the optimization method to get more flexible series of Gaussian…

Chemical Physics · Physics 2025-11-04 Stéphanie Laure Egome Nana , Arnaud Leclerc , Lorenzo Ugo Ancarani

We consider thermal $n$-point Green functions in the framework of quantum field theory at finite temperature. We show how analytic continuations from imaginary to real energies relate these functions originally defined in the imaginary-time…

High Energy Physics - Phenomenology · Physics 2014-11-17 R. Baier , A. Niegawa

We report unphysical irregularities and discontinuities in some key experimentally-measurable quantities computed within the GW approximation of many-body perturbation theory applied to molecular systems. In particular, we show that the…

Chemical Physics · Physics 2019-05-06 Mickaël Véril , Pina Romaniello , J. A. Berger , Pierre-François Loos

Quantum many-body theory has witnessed tremendous progress in various fields, ranging from atomic and solid-state physics to quantum chemistry and nuclear structure. Due to the inherent computational burden linked to the ab initio treatment…

The $GW$ approximation is a widely used framework for studying correlated materials, but it struggles with certain limitations, such as its inability to explain pseudogap phenomena. To overcome these problems, we propose a systematic…

Strongly Correlated Electrons · Physics 2024-09-26 Hui Li , Yingze Su , Junnian Xiong , Haiqing Lin , Huaqing Huang , Dingping Li

We provide an in-depth examination of the $GW$ approximation of Green's function many-body perturbation theory by detailing both its theoretical and practical aspects in the realm of quantum chemistry. First, the quasiparticle context is…

Chemical Physics · Physics 2024-03-20 Antoine Marie , Abdallah Ammar , Pierre-François Loos

Various many-body perturbation theory techniques for calculating electron behavior rely on {\it W}, the screened Coulomb interaction. Computing {\it W} requires complete knowledge of the dielectric response of the electronic system, and the…

Materials Science · Physics 2021-06-30 John Vinson , Eric L. Shirley

With the aim of identifying universal trends, we compare fully self-consistent electronic spectra and total energies obtained from the GW approximation with those from an extended GWGamma scheme that includes a nontrivial vertex function…

Materials Science · Physics 2007-05-23 Arno Schindlmayr , Thomas J. Pollehn , R. W. Godby

Complex potential transformations which add imaginary parts to chosen energy levels are given and qualitatively explained. Unexpected shape similarity of potential perturbations for real and imaginary E-shifts of bound states are exhibited.…

Quantum Physics · Physics 2007-05-23 V. M. Chabanov , B. N. Zakhariev

Analytic continuation (AC) from imaginary-time Green's function to spectral function is essential in the numerical analysis of dynamical properties in quantum many-body systems. However, this process faces a fundamental challenge: it is an…

Strongly Correlated Electrons · Physics 2024-09-04 Yuichi Motoyama , Hiroshi Shinaoka , Junya Otsuki , Kazuyoshi Yoshimi

Continuum or discrete polarizable models for the study of optoelectronic processes in embedded subsystems rely mostly on the restriction of the surrounding electronic dielectric response to its low frequency limit. Such a description hinges…

Materials Science · Physics 2024-04-01 David Amblard , Xavier Blase , Ivan Duchemin

The method of analytic continuation from imaginary to real chemical potential is one of the most powerful tools to circumvent the sign problem in lattice QCD. Here we test this method in a theory, 2-color QCD, which is free from the sign…

High Energy Physics - Lattice · Physics 2010-10-27 Paolo Cea , Leonardo Cosmai , Massimo D'Elia , Alessandro Papa

For materials which are incorrectly predicted by density functional theory to be metallic, an iterative procedure must be adopted in order to perform GW calculations. In this paper we test two iterative schemes based on the quasi-particle…

Materials Science · Physics 2007-05-23 V. A. Popa , G. Brocks , P. J. Kelly